MXenes胶体氧化的调控策略及其对超级电容器性能的影响

doi:10.19799/j.cnki.2095-4239.2021.0480

摘要/Abstract

摘要：

超级电容器作为能量存储器件，因具有较快的充放电速率、较高的功率密度和长的循环寿命等特点被广泛研究。MXenes因具有高电导率、高电化学活性、易成膜和亲水性等特点而被广泛应用在超级电容器领域，并展示了出色的储能性能。然而其面临着环境敏感、易氧化降解等严峻挑战，生成几乎没有电容量贡献的TiO₂等产物，严重阻碍了MXenes基超级电容器的发展。探索MXenes胶体稳定性的优化策略，并实现其稳定性的选择性调控，对提升MXenes在超级电容器及其他不同应用场合的性能具有重要的现实意义。为此本文简要总结了抑制MXenes氧化的策略，提出了稳定性选择性调控的总体方案，探讨了选择性调控对超级电容器性能的影响机制，为制备高性能MXenes基超级电容器提供思路。

关键词: MXenes, 稳定性, 超级电容器, 氧化动力学

Abstract:

Supercapacitors have been extensively studied as an energy storage device due to their faster charging-discharging rates, higher power density, and longer service life. MXenes with high conductivity, high electrochemical activity, ease of fabrication into film, hydrophilicity, and other characteristics, are widely used in the field of supercapacitors and exhibit excellent energy storage performance. However, the environmental sensitivity and ease of oxidation degradation, which results in the formation of TiO₂ and other compounds that contribute essentially nothing to the capacitance, have significantly hampered the development of high-performance supercapacitors. It is critical to investigate the stability optimization strategy of MXenes colloid and realize the selective regulation of its stability for improving the performance of MXenes in supercapacitors and other potential application fields. Therefore, we summarize the strategies for inhibiting MXenes oxidation, propose an overall scheme of selective stability regulation, and discuss the effect of selective regulation on the performance of supercapacitors, as well as provide suggestions for fabricating high-performance MXenes-based supercapacitors.

Key words: MXenes, stability, supercapacitor, oxidation kinetics

中图分类号:

TM 911.14

郭铁柱, 周迪, 张传芳. MXenes胶体氧化的调控策略及其对超级电容器性能的影响[J]. 储能科学与技术, 2022, 11(4): 1165-1174.

Tiezhu GUO, Di ZHOU, Chuanfang ZHANG. Strategies for improving MXene colloidal stability and impact on their supercapacitor performance[J]. Energy Storage Science and Technology, 2022, 11(4): 1165-1174.

图/表 2

参考文献 53

1	GUO T Z, ZHOU D, LIU W F, et al. Recent advances in all-in-one flexible supercapacitors[J]. Science China Materials, 2021, 64(1): 27-45.
2	WANG F X, WU X W, YUAN X H, et al. Latest advances in supercapacitors: from new electrode materials to novel device designs[J]. Chemical Society Reviews, 2017, 46(22): 6816-6854.
3	ABDOLHOSSEINZADEH S, HEIER J, ZHANG C F. Coating porous MXene films with tunable porosity for high-performance solid-state supercapacitors[J]. Chemelectrochem, 2021, 8(10): 1911-1917.
4	ABDOLHOSSEINZADEH S, HEIER J, ZHANG C F. Printing and coating MXenes for electrochemical energy storage devices[J]. Journal of Physics-Energy. 2020, 2(3): doi: 10.1088/2515-7655/aba47d.
5	ZHANG C F. Interfacial assembly of two-dimensional MXenes[J]. Journal of Energy Chemistry, 2021, 60: 417-434.
6	Li N, PENG J H, ONG W J, et al. MXenes: An emerging platform for wearable electronics and looking beyond[J]. Matter, 2021, 4(2): 377-407.
7	KARAHAN H E, GOH K, ZHANG C F, et al. MXene materials for designing advanced separation membranes[J]. Advanced Materials, 2020, 32(29): doi: 10.1002/adma.201906697.
8	VAHIDMOHAMMADI A, ROSEN J, GOGOTSI Y. The world of two-dimensional carbides and nitrides (MXenes)‍[J]. Science, 2021, 372(6547): 1165.
9	ABDOLHOSSEINZADEH S, SCHNEIDER R, VERMA A, et al. Turning trash into treasure: additive free MXene sediment inks for screen-printed micro-supercapacitors[J]. Advanced Materials, 2020, 32(17): doi: 10.1002/adma.202000716.
10	DING L, Li L B, LIU Y C, et al. Effective ion sieving with Ti₃C₂Tx MXene membranes for production of drinking water from seawater[J]. Nature Sustainability. 2020, 3(4): 296-302.
11	LUO Y, CHEN G-F, DING L, et al. Efficient electrocatalytic N₂ fixation with MXene under ambient conditions[J]. Joule, 2019, 3(1): 279-289.
12	CHENG Y, MA Y, LI L, et al. Bioinspired microspines for a high-performance spray Ti₃C₂Tx MXene-based piezoresistive sensor[J], ACS Nano, 2020, 14(2): 2145-2155.
13	LIU J, ZHANG H B, SUN R, et al. Hydrophobic, flexible, and lightweight MXene foams for high-performance electromagnetic-interference shielding[J]. Advanced Materials, 2017, 29(38): doi: 10.1002/adma.201702367.
14	HUANG R K, CHEN X, DONG Y Q, et al. MXene composite nanofibers for cell culture and tissue engineering[J]. ACS Applied Bio Materials, 2020, 3(4): 2125-2131.
15	LUKATSKAYA M R, KOTA S, LIN Z F, et al. Ultra-high-rate pseudocapacitive energy storage in two-dimensional transition metal carbides[J]. Nature Energy, 2017, 2(8): 17105.
16	LIN H, WANG X G, YU L D, et al. Two-dimensional ultrathin MXene ceramic nanosheets for photothermal conversion[J]. Nano Letters, 2017, 17(1): 384-391.
17	吕通, 张恩爽, 原因, 等. 大片单层低缺陷MXene的制备及其膜材料的电磁屏蔽性能[J]. 高等学校化学学报, 2019, 40(10): 2059-2066.
	LYU T, ZHANG E S, YUAN Y, et al. Preparation of large-size single layer MXene with low defect and electromagnetic shielding performance of MXene film[J]. Chemical Journal of Chinese Universities, 2019, 40(10): 2059-2066.
18	GUO T Z, FU M S, ZHOU D, et al. Flexible Ti₃C₂Tx/graphene films with large-sized flakes for supercapacitors[J]. Small Structures, 2021, 2(7): doi: 10.1002/sstr.202100015.
19	SHAO H, XU K, WU Y C, et al. Unraveling the charge storage mechanism of Ti₃C₂Tx MXene electrode in acidic electrolyte[J]. ACS Energy Letters, 2020, 5(9): 2873-2880.
20	ABDOLHOSSEINZADEH S, JIANG X T, ZHANG H, et al. Perspectives on solution processing of two-dimensional MXenes[J]. Materials Today, 2021, 48: 214-240.
21	XIA J X, YANG S Z, WANG B, et al. Boosting electrosynthesis of ammonia on surface-engineered MXene Ti₃C₂[J]. Nano Energy, 2020, 72: doi: 10.1016/j.nanoen.2020.104681.
22	JIA G W, ZHENG A, WANG X, et al. Flexible, biocompatible and highly conductive MXene-graphene oxide film for smart actuator and humidity sensor[J]. Sensors and Actuators B: Chemical, 2021, 346: doi: 10.1016/j.snb.2021.130507.
23	IQBAL A, HONG J, KO T Y, et al. Improving oxidation stability of 2D MXenes: synthesis, storage media, and conditions[J]. Nano Convergence, 2021, 8(1): 9.
24	DOO S, CHAE A, KIM D, et al. Mechanism and kinetics of oxidation reaction of aqueous Ti₃C₂Tx suspensions at different pHs and temperatures[J]. ACS applied materials & interfaces, 2021, 13(19): 22855-22865.
25	ZHANG J Z, KONG N, HEGH D, et al. Freezing titanium carbide aqueous dispersions for ultra-long-term storage[J]. ACS Applied Materials & Interfaces, 2020, 12(30): 34032-34040.
26	ZHANG C J, PINILLA S, MCEVOY N, et al. Oxidation stability of colloidal two-dimensional titanium carbides (MXenes)[J]. Chemistry of Materials, 2017, 29(11): 4848-4856.
27	HUANG S H, MOCHALIN V N. Hydrolysis of 2D transition-metal carbides (MXenes) in colloidal solutions[J]. Inorganic Chemistry, 2019, 58(3): 1958-1966.
28	HABIB T, ZHAO X F, SHAH S A, et al. Oxidation stability of Ti₃C₂Tx MXene nanosheets in solvents and composite films[J]. npj 2D Materials and Applications, 2019, 3(1): 8.
29	唐俊. 二维Ti₃C₂Tx纳米结构调控及其对电化学性能的影响[D]. 北京: 北京大学, 2020.TANG J. Tuning the nanostructure of Ti₃C₂Tx MXene for optimization of the electrochemical performance[D]. Beijing: Peking University, 2020.
30	TANG J, MATHIS T S, KURRA N, et al. Tuning the electrochemical performance of titanium carbide MXene by controllable in situ anodic oxidation[J]. Angewandte Chemie-International Edition, 2019, 58(49): 17849-17855.
31	WU C-W, UNNIKRISHNAN B, CHEN I W P, et al. Excellent oxidation resistive MXene aqueous ink for micro-supercapacitor application[J]. Energy Storage Materials, 2020, 25: 563-571.
32	ZHAO X F, VASHISTH A, BLIVIN J W, et al. pH, nanosheet concentration, and antioxidant affect the oxidation of Ti₃C₂Tx and Ti₂CTx MXene dispersions[J]. Advanced Materials Interfaces, 2020, 7(20): doi: 10.1002/admi.202000845.
33	SHUCK C E, HAN M K, MALESKI K, et al. Effect of Ti₃AlC₂MAX phase on structure and properties of resultant Ti₃C₂Tx MXene[J]. ACS Applied Nano Materials, 2019, 2(6): 3368-3376.
34	MATHIS T S, MALESKI K, GOAD A, et al. Modified MAX phase synthesis for environmentally stable and highly conductive Ti₃C₂ MXene[J]. ACS Nano, 2021, 15(4): 6420-6429.
35	SANG X H, XIE Y, LIN M W, et al. Atomic defects in monolayer titanium carbide (Ti₃C₂Tx) MXene[J]. ACS Nano, 2016, 10(10): 9193-9200.
36	SARYCHEVA A, GOGOTSI Y. Raman spectroscopy analysis of the structure and surface chemistry of Ti₃C₂Tx MXene[J]. Chemistry of Materials, 2020, 32(8): 3480-3488.
37	SHI Y C, LIU Y. Vacancy and N dopants facilitated Ti³⁺ sites activity in 3D Ti_3- xC₂Ty MXene for electrochemical nitrogen fixation[J]. Applied Catalysis B: Environmental, 2021, 297: doi: 10.1016/j.apcatb.2021.120482.
38	LUKATSKAYA M R, BAK S M, YU X Q, et al. Probing the mechanism of high capacitance in 2D titanium carbide using in situ X-ray absorption spectroscopy[J]. Advanced Energy Materials, 2015, 5(15): doi: 10.1002/aenm.201500589.
39	ALHABEB M, MALESKI K, ANASORI B, et al. Guidelines for synthesis and processing of two-dimensional titanium carbide (Ti₃C₂Tx MXene)[J]. Chemistry of Materials, 2017, 29(18): 7633-7644.
40	SHI H H, ZHANG P P, LIU Z C, et al. Ambient-stable two-dimensional titanium carbide (MXene) enabled by iodine etching[J]. Angewandte Chemie-International Edition, 2021, 60(16): 8689-8693.
41	HE P, WANG X X, CAI Y Z, et al. Tailoring Ti₃C₂Tx nanosheets to tune local conductive network as an environmentally friendly material for highly efficient electromagnetic interference shielding[J]. Nanoscale, 2019, 11(13): 6080-6088.
42	李雪松. 二维晶体MXene (Ti₃C₂Tx)环境不稳定性的研究[D]. 济南: 山东大学, 2021.LI X S. Study on environmental instability of two-dimensional crystal MXene (Ti₃C₂Tx) [D]. Ji'nan: Shandong university, 2021.
43	NATU V, HART J L, SOKOL M, et al. Edge capping of 2D-MXene sheets with polyanionic salts to mitigate oxidation in aqueous colloidal suspensions[J]. Angewandte Chemie-International Edition, 2019, 58(36): 12655-12660.
44	ZHAO X F, VASHISTH A, PREHN E, et al. Antioxidants unlock shelf-stable Ti₃C₂Tx (MXene) nanosheet dispersions[J]. Matter, 2019, 1(2): 513-526.
45	LI J B, QIN R Z, YAN L, et al. Plasmonic light illumination creates a channel to achieve fast degradation of Ti₃C₂Tx nanosheets[J]. Inorganic Chemistry, 2019, 58(11): 7285-7294.
46	JI J J, ZHAO L F, SHEN Y F, et al. Covalent stabilization and functionalization of MXene via silylation reactions with improved surface properties[J]. FlatChem, 2019, 17: doi: 10.1016/j.flatc.2019.100128.
47	YANG W Z, HUANG B Y, LI L B, et al. Covalently sandwiching MXene by conjugated microporous polymers with excellent stability for supercapacitors[J]. Small Methods, 2020, 4(10): doi: 10.1002/smtd.202000434.
48	SEYEDIN S, ZHANG J Z, USMAN K A S, et al. Facile solution processing of stable MXene dispersions towards conductive composite fibers[J]. Global Challenges, 2019, 3(10): doi: 10.1002/gchz.201900037.
49	SATO T, HAMADA Y, SUMIKAWA M, et al. Solubility of oxygen in organic solvents and calculation of the Hansen solubility parameters of oxygen[J]. Industrial and Engineering Chemistry Research, 2014, 53(49): 19331-19337.
50	CHAE Y, KIM S J, CHO S Y, et al. An investigation into the factors governing the oxidation of two-dimensional Ti₃C₂ MXene[J]. Nanoscale, 2019, 11(17): 8387-8393.
51	MALESKI K, MOCHALIN V N, GOGOTSI Y. Dispersions of two-dimensional titanium carbide MXene in organic solvents[J]. Chemistry of Materials, 2017, 29(4): 1632-1640.
52	ZHANG Q X, LAI H R, FAN R Z, et al. High concentration of Ti₃C₂Tx MXene in organic solvent[J]. ACS Nano, 2021, 15(3): 5249-5262.
53	LUO Y Y, YANG C H, TIAN Y P, et al. A long cycle life asymmetric supercapacitor based on advanced nickel-sulfide/titanium carbide (MXene) nanohybrid and MXene electrodes[J]. Journal of Power Sources, 2020, 450: doi: 10.1016/j.jpowsour.2019.227694.

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