基于超级电容器的MnO2 二元复合材料研究进展

doi:10.19799/j.cnki.2095-4239.2019.0251

摘要/Abstract

摘要：

MnO₂作为典型的超级电容器赝电容材料具有成本低、比电容高等优点，但其导电性能差、工作过程中结构不稳定等缺点严重影响其电化学性能。目前，将MnO₂与其它材料复合制备二元复合材料是改善其电化学性能的有效手段之一。本文综述了基于超级电容器的MnO₂与双电层、MnO₂与赝电容二元复合材料国内外的研究进展，对比分析了MnO₂二元复合材料的电化学性能。综合分析表明，MnO₂与赝电容电极材料复合能够通过协同作用，进一步提高复合材料电化学性能；“核-壳”异质结构可以起到缓冲与支撑作用，增加复合材料的结构稳定性。因此，构建“核-壳”结构的MnO₂与赝电容复合电极材料会成为今后的研究热点。

关键词: 二氧化锰, 复合材料, 超级电容器

Abstract:

As a typical pseudocapacitor material for supercapacitors, MnO₂ has the advantages of low cost and high specific capacitance, but its electrochemical performance is degraded by poor conductivity and structural instability in the working process. At present, the electrochemical performance of MnO₂ is improved by binary composites. This paper reviews the research progress on supercapacitor-based MnO₂ and dual-layered MnO₂, and pseudocapacitor binary composite materials. After analyzing and comparing the electrochemical performances of MnO₂ binary composites, it is proposed that composite MnO₂ and pseudo-capacitive materials, or composites with coreshell heterogeneous structures, are competitive candidates for improving the electrochemical performance.

Key words: manganese dioxide, composite materials, supercapacitor

中图分类号:

TB 34

侯朝霞, 王晓慧, 屈晨滢, 王健. 基于超级电容器的MnO₂ 二元复合材料研究进展[J]. 储能科学与技术, 2020, 9(3): 797-806.

HOU Zhaoxia, WANG Xiaohui, QU Chenying, WANG Jian. Research progress of MnO₂ binary composites based on supercapacitors[J]. Energy Storage Science and Technology, 2020, 9(3): 797-806.

图/表 6

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基于超级电容器的MnO₂ 二元复合材料研究进展

Research progress of MnO₂ binary composites based on supercapacitors

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