储能科学与技术 ›› 2022, Vol. 11 ›› Issue (9): 3028-3034.doi: 10.19799/j.cnki.2095-4239.2022.0385

• 创刊十周年专刊 • 上一篇    下一篇

碳酸盐/高炉矿渣定型复合相变储热材料的制备与性能

王君雷1,2,3(), 张第玲1, 王昆3, 许东东1,2, 徐祥贵1, 姚华1,2, 刘文巍1,2, 黄云1,2,4()   

  1. 1.中国科学院过程工程研究所多相复杂系统国家重点实验室,北京 100190
    2.中国科学院大学,北京 100049
    3.天津大学内燃机燃烧学国家重点实验室,天津 300072
    4.中国科学院洁净能源创新研究院,辽宁 大连 116023
  • 收稿日期:2022-07-11 修回日期:2022-07-23 出版日期:2022-09-05 发布日期:2022-08-30
  • 通讯作者: 黄云 E-mail:jlwang18@ipe.ac.cn;yunhuang@ipe.ac.cn
  • 作者简介:王君雷(1993—),男,博士研究生,研究方向为储热技术,E-mail:jlwang18@ipe.ac.cn
  • 基金资助:
    国家自然科学基金(21975262);中科院清洁能源先导基金(DNL202017);河南省储能材料与过程重点实验室(202102)

Carbonates/blast furnace slag form-stable phase change materials

Junlei WANG1,2,3(), Diling ZHANG1, Kun WANG3, Dongdong XU1,2, Xianggui XU1, Hua YAO1,2, Wenwei LIU1,2, Yun HUANG1,2,4()   

  1. 1.State Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China
    2.University of Chinese Academy of Sciences, Beijing 100049, China
    3.State Key Laboratory of Engines, Tianjin University, Tianjin 300072, China
    4.Dalian National Laboratory for Clean Energy, Dalian 116023, Liaoning, China
  • Received:2022-07-11 Revised:2022-07-23 Online:2022-09-05 Published:2022-08-30
  • Contact: Yun HUANG E-mail:jlwang18@ipe.ac.cn;yunhuang@ipe.ac.cn

摘要:

碳酸盐(Na2CO3和K2CO3)是极具潜力的高温相变材料,高炉矿渣(blast furnace slag,BS)作为基体材料兼具环境和经济效益,但是碳酸盐在高温熔融状态下通常会与高炉矿渣发生反应。为此,本工作发展两步法制备路线以攻克这一问题。首先,使用碳酸盐对高炉矿渣进行改性,得到化学性质稳定的改性矿渣(modified blast furnace slag,MBS);其次,通过混合烧结法制备碳酸盐/改性矿渣定型复合相变材料(form-stable phase change materials,FSPCMs)。经过冷热循环测试制备的K2CO3/KMBS复合相变材料比Na2CO3/NMBS的定型效果更优。分析发现,K2CO3与KMBS具有良好的化学相容性,随着K2CO3含量增加,K2CO3/KMBS定型相变材料的潜热逐渐增加,且测试结果与计算一致,在质量比4∶6(40K2CO3/60KMBS)时,潜热为94.8 kJ/kg,且热稳定性最好。

关键词: 储热, 碳酸盐, 改性矿渣, 定型复合相变材料

Abstract:

Blast furnace slag (BFS) is a very affordable matrix material, and carbonates (Na2CO3 and K2CO3) are promising phase change materials for high-temperature applications; however, carbonates react with BFS when it is in the molten state. A two-step approach was created as a result to solve this problem. First, carbonate was used to modify BFS so that it can no longer react with carbonate; second, a hybrid sintering method was used to create form-stable phase change materials (FSPCMs). After thermal cycling, the obtained K2CO3/KMBS FSPCMs exhibited better shape preservation than Na2CO3/NMBS FSPCMs. Further tests revealed that K2CO3 and KMBS were chemically compatible. The measurement was consistent with the calculated value, and the latent heat of K2CO3/KMBS FSPCMs gradually increased with the increase in K2CO3 content. At the mass ratio of 4∶6 (40K2CO3/60KMBS), the latent heat is 94.8 kJ/kg, and the thermal stability is the best.

Key words: thermal energy storage, carbonate, modified blast furnace slag, form-stable composite phase change material

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