储能科学与技术 ›› 2019, Vol. 8 ›› Issue (4): 709-717.doi: 10.12028/j.issn.2095-4239.2019.0018
房满庭, 章学来, 纪珺, 华维三, 刘彪, 王绪哲
收稿日期:
2019-02-25
修回日期:
2019-03-09
出版日期:
2019-07-01
发布日期:
2019-03-19
通讯作者:
章学来,E-mail:xlzhang@shmtu.edu.cn。
作者简介:
房满庭(1995-),男,硕士研究生,研究方向为相变储热技术及其应用。E-mail:fmt0535@163.com
基金资助:
FANG Manting, ZHANG Xuelai, JI Jun, HUA Weisan, LIU Biao, WANG Xuzhe
Received:
2019-02-25
Revised:
2019-03-09
Online:
2019-07-01
Published:
2019-03-19
摘要: 水合盐相变储能材料具有相变温度适中、导热系数大、潜热值高、价格低廉等优点,因而具有广阔的使用前景。然而,过冷、相分离、循环稳定性差等诸多问题限制了水合盐的实际应用。许多学者将水合盐与其它材料结合,构成复合相变材料,成功地解决了以上问题。前人对水合盐复合相变材料的研究以解决水合盐在使用过程中的上述问题居多。然而近年来,有研究者制备复合相变材料以改善水合盐的热物性,如相变温度、导热系数、潜热值等,取得了一定成果,但这一研究思路仍需进行进一步探索。文章将制备水合盐复合相变材料的目的作为线索,总结了水合盐复合相变材料的研究思路,详细介绍了国内外相关的研究工作和研究成果,并指出了今后水合盐复合相变材料的研究重点。
中图分类号:
房满庭, 章学来, 纪珺, 华维三, 刘彪, 王绪哲. 水合盐复合相变材料的研究进展[J]. 储能科学与技术, 2019, 8(4): 709-717.
FANG Manting, ZHANG Xuelai, JI Jun, HUA Weisan, LIU Biao, WANG Xuzhe. Progress in hydrated salt based composite phase change materials[J]. Energy Storage Science and Technology, 2019, 8(4): 709-717.
[1] 张寅平. 相变贮能[M]. 合肥:中国科学技术大学出版社, 1996. [2] POMIANOWSKI M, HEISELBERG P, ZHANG Y. Review of thermal energy storage technologies based on PCM application in buildings[J]. Energy & Buildings, 2013, 67(4):56-69. [3] 孟令然, 郭立江, 李晓禹, 等. 水合盐相变储能材料的研究进展[J]. 储能科学与技术, 2017, 6(4):623-632. MENG Lingran, GUO Lijiang, LI Xiaoyu, et al. Salt hydrate based phase change materials for thermal energy storage-A review[J]. Energy Storage Science and Technology, 2017, 6(4):623-632. [4] TAO W B, XIE R H. Research and development of organic phase change materials for cool thermal energy storage[J]. J. Refrig., 2016, 37(1):52-59. [5] 张仁元. 相变材料与相变储热技术[M]. 北京:科学出版社, 2008. ZHANG Renyuan. Phase change materials and phase change heat storage technology[M]. Beijing:Science Press, 2008. [6] LANE G A. Low temperature heat storage with phase change materials[J]. International Journal of Ambient Energy, 1980, 1(3):155-168. [7] TELKES M. Thermal storage in salt-hydrates[J]. Solar Materials Science, 1980, 1:377-404. [8] DINCER I, ROSEN M. Thermal energy storage:Systems and applications[M]. New York:John Wiley & Sons, 2002. [9] MAVRIGIANNAKI A, AMPATZI E. Latent heat storage in buildingelements:A systematic review on properties and contextual performance factors[J]. Renewable and Sustainable Energy Reviews, 2016, 60:852-866. [10] 张玉文, 陈钟颀, 董志锋. 潜热蓄热系统的热力学分析[J]. 甘肃科学学报, 1993, 5(3):28-32. ZHANG Yuwen, CHEN Zhongqi, DONG Zhifeng. Thermodynamic analysis of latent heat storage system[J]. Journal of Gansu Sciences, 1993, 5(3):28-32. [11] JOLLYR P J. Calcium chloride hexahydrate fusion-solidification behavior[J]. Thermochimica Acta, 1989, 152(2):271-278. [12] GEORGE A L. Phase change materials for storage nucleation to prevent supercooling[J]. Solar Energy Materials and Solar Cells, 1992, 27:135-160. [13] 徐云龙, 刘栋. 六水氯化钙相变材料过冷性质的研究[J]. 材料工程, 2006(s1):218-221. XU Yunlong, LIU Dong. Preliminary supercooling research on calcium chloride hexahydrate as phase change material[J]. Material Engineering, 2006(s1):218-221. [14] XU X X, CUI H Z, SHAZIM A M, et al. Development of novel composite PCM for thermal energy storage using CaCl2·6H2O with graphene oxide and SrCl2·6H2O[J]. Energy and Buildings, 2017, 156:163-172. [15] 何媚质, 杨鲁伟, 张振涛. 无机相变材料CaCl2·6H2O的过冷特性[J]. 化工学报, 2017, 68(11):4016-4024. HE Meizhi, YANG Luwei, ZHANG Zhentao. Supercooling characteristics of inorganic phase change material CaCl2·6H2O[J]. CIESC Journal, 2017, 68(11):4016-4024. [16] 丁益民, 阎立诚, 薛俊慧. 水合盐储热材料的成核作用[J]. 化学物理学报, 1996, 9(1):83-86. DING Yimin, YAN Licheng, XUE Junhui. Nucleation of salt-hydrates as the thermal energy storage material[J]. Chinese Journal of Chemical Physics, 1996, 9(1):83-86. [17] FENG G, XU X, LI G, et al. Application of Na2SO4·10H2O thermal storage in air-conditioning cooling water system[J]. Materials Research Innovations, 2015, 19(s5):983-987. [18] 柳馨, 铁健, 铁生年. 纳米粉体对Na2SO4·10H2O过冷及相分层现象的影响[J]. 人工晶体学报, 2015, 44(11):3072-3078. LIU Xin, TIE Jian, TIE Shengnian. Effect of nano powder additionon the subcooling and phase stratifcation of sodium sulfatedecahydrate[J]. Journal of Synthetic Crystals, 2015, 44(11):3074-3080. [19] 冷从斌, 季旭, 罗熙, 等. Na2SO4·10H2O/EG复合相变材料的制备与性能分析[J]. 材料工程, 2017, 45(1):58-64. LENG Congbin, JI Xu, LUO Xi, et al. Preparation and performance analysis of Na2SO4·10H2O/EG composite phase change materials[J]. Journal of Materials Engineering, 2017, 45(1):58-64. [20] 唐志伟, 赵化涛, 陈志峰. 硬脂酸与Na2HPO4·12H2O混合相变材料储热性能[J]. 北京工业大学学报, 2009, 35(6):809-814. TANG Zhiwei, ZHAO Huatao, CHEN Zhifeng. Study on mixtures of stearic acid and Na2HPO4·12H2O as heat storage phase-change materials[J]. Journal of Beijing University of Technology, 2009, 35(6):809-814. [21] 祝盼盼, 黄金. 多孔基体-Na2HPO4·12H2O复合材料体系的相变特性[J]. 广东工业大学学报, 2014, 31(2):128-132. ZHU Panpan, HUANG Jin. The phase transition performance of Na2HPO4·12H2O in porous medium[J]. Journal of Guangdong University of Technology, 2014, 31(2):128-132. [22] 吴苓瑜, 杨华武, 黎艳玲, 等. 新型二元相变材料结晶与储热性能的研究[J]. 华中师范大学学报, 2016, 50(5):737-740. WU Cenyu, YANG Huawu, LI Yanling, et al. Study on crystallization and thermal storage properties of new binary phase change materials[J]. Journal of Central China Normal University, 2016, 50(5):737-740. [23] 邓燕, 丁云飞.不同成核剂对Na2HPO4·12H2O相变过冷性能的影响[J]. 应用化工, 2018, 47(3), 534-536+540. DENG Yan, DING Yunfei. Study on the effect of suppercooling properties on different nucleation to Na2HPO4·12H2O[J]. Applied Chemical Industry, 2018, 47(3), 534-536+540. [24] WADA T, YAMAMOTO R.Crystal nucleation of sodium acetate trihydrate catalyzed by tetrasodium pyrophosphate decahydrate[J]. Bull. Chem. Soc. Jpn., 1982, 55:3603. [25] 郎雪梅, 叶菊招. 三水合醋酸钠的相变贮热性能[J]. 材料开发与应用, 2003, 18(1):4-7. LANG Xuemei, YE Juzhao. Phase change property of sodium acetate trihydrate as heat storage material[J]. Development and Application of Materials, 2003, 18(1):4-7. [26] 李晶, 刘中良, 马重芳. 改善三水醋酸钠固液相变性能的实验研究[J]. 工程热物理学报, 2006, 27(5):817-819. LI Jin, LIU Zhongliang, MA Chongfang. Expermental study on improving solid-liquid phase change performance of acetate hydroxide trihydrate[J]. Journal of Engineering Thermpohysics, 2006, 26(5):817-819. [27] 徐建霞, 柯秀芳. CH3COONa·3H2O相变储能性能研究[J]. 材料开发与应用, 2007, 22(6):24-27. XU Jianxia, KE Xiufang. An investigation on phase change property of CH3COONa·3H2O as energy storage material[J]. Development and Application of Materials, 2007, 22(6):24-27. [28] 丁红雨, 李慧星, 冯国会. 基于相变材料三水醋酸钠蓄热性能实验研究[J]. 建筑节能, 2014, 42(10):42-45. DING Hongyu, LI Huixin, FENG Guohui. Experimental researchon thermal storage performance of CH3COONa·3H2O as phase change material[J]. Building Energy Effciency, 2014, (10):42-45. [29] 卢大杰, 胡芃, 赵斌斌, 等. 三水合醋酸钠纳米成核剂的性能研究[J]. 工程热物理学报, 2012, 33(8):1279-1282. LU Dajie, HU Peng, ZHAO Binbin, et al. Study on the performance of nanoparticles as nucleating agents for sodium acetate trihydrate[J]. Journal of Engineering Thermpohysics, 2012, 33(8):1279-1282. [30] 杜晓冬, 章学来, 丁锦宏, 等. 纳米成核剂对三水乙酸钠蓄热性能的影响[J]. 建筑节能, 2017, 45(9):25-28. DU Xiaodong, ZHANG Xuelai, DING Jinhong, et al. Effects of nanoparticles nucleating agents on the performance of sodium acetate trihydrate[J]. Building Energy Effciency, 2017, 45(9):25-28. [31] 盛强, 邢玉明, 王泽. 八水氢氧化钡相变材料的强化传热实验[J]. 航空动力学报, 2013, 28(9):1927-1932. SHENG Qiang, XING Yuming, WANG Ze. Experiment on heat transfer enhancement of barium hydroxide octahydrate phase change material[J]. Journal of Aerospace Power, 2013, 28(9):1927-1932. [32] 冷从斌, 季旭, 罗熙, 等. 膨胀石墨/八水氢氧化钡复合定型相变材料的制备与储热性能研究[J]. 功能材料, 2016, 47(3):3247-3252. LENG Congbin, JI Xu, LUO Xi, et al. Preparation and heat storage performance investigation of expanded graphite/octahydrate composite solidifed phase change material[J]. Journal of Functional Materials, 2016, 47(3):3247-3252. [33] 纪珺, 刘宇飞, 任迎蕾, 等. Ba(OH)2·8H2O复合相变材料及其在太阳能光伏/热集热器上的释热特性[J]. 化工学报, 2017, 68(8):2985-2990. JI Jun, LIU Yufei, REN Yinglei, et al. Ba(OH)2·8H2O composite phase-change material and its heat release characteristics in solar photovoltaic/photo-thermal collectors[J]. CIESC Journal, 2017, 68(8):2985-2990. [34] XIAO Q Q, YUAN W H, Li L, et al. Fabrication and characteristics of composite phase change material based on Ba(OH)2·8H2O for thermal energy storage[J]. Solar Energy Materials and Solar Cells, 2018, 179:339-345. [35] 华维三, 章学来, 刘锋, 等. 相变材料复合八水氢氧化钡的制备及热性能[J]. 化工进展, 2018, 37(11):4384-4389. HUA Weisan, ZHANG Xuelai, LIU Feng, et al. Preparation and thermal properties of composite barium hydroxide octahydrate for energy storage[J]. Chemical Industry and Engineering Progress, 2018, 37(11):4384-4389. [36] 宋婧, 曾令可, 税安泽, 等. 钾明矾蓄热性能的研究与改善[J]. 人工晶体学报, 2007, 36(2):358-362. SONG Jing, ZENG Lingke, SHUI Anze, et al. Study on heat storage property and improvement of aluminum potassium sulfate[J]. Journal of Synthetic Crystals, 2007, 36(2):358-362. [37] 任雪潭, 刘艳春, 曾令可. 成核剂对钾明矾储能物性的影响[J]. 山东陶瓷, 2012, 35(6):7-9. REN Xuetan, LIU Yanchun, ZENG Lingke. Influence of nucleating on the energy storage of potassium alum[J]. Shandong Ceramics, 2012, 35(6):7-9. [38] 埃文思.结晶化学导论[M]. 北京:人民教育出版社, 1983. [39] 苑坤杰, 张正国, 方晓明, 等. 水合无机盐及其复合相变储热材料的研究进展[J]. 化工进展, 2016, 35(6):1820-1826. YUAN Kunjie, ZHANG Zhengguo, FANG Xiaoming, et al. Research progress of inorganic hydrated salts and their phase change heat storage composites[J]. Chemical Industry and Engineering Progress, 2016, 35(6):1820-1826. [40] 李玉婷, 周永全, 葛飞, 等. 无机水合盐相变储能材料的过冷及相分离研究进展[J]. 盐湖研究, 2018, 26(1):81-86. LI Yuting, ZHOU Yongquan, GE Fei, et al. Progress in supercooling and phase separation of inorganic hydrated salt phase change energy storage materials[J]. Journal of Salt Lake Research, 2018, 26(1):81-86. [41] 施敏敏, 章学来. 用于储存自然冷能的相变材料制备及蓄冷特性[J]. 化学工程, 2010, 38(9):82-85. SHI Minmin, ZHANG Xuelai.Preparation of phase-change material for natural cool energy storage and its characteristics[J]. Chemical Engineering, 2010, 38(9):82-85. [42] 刘欣, 徐涛, 高学农, 等. 十水硫酸钠的过冷和相分离探究[J]. 化工进展, 2011, 30(s1):755-758. LIU Xin, XU Tao, GAO Xuenong, et al. Study on supercooling and phase separation of Na2SO4·10H2O[J]. Chemical Industrial and Engineering Prograss, 2011, 30(s1):755-758. [43] 李凤艳, 王鹏, 袁亚东. 相变温度为室温的Na2SO4·10H2O相变储热材料的制备研究[J]. 合成材料老化与应用, 2015, 44(1):39-41+46. LI Fengyan, WANG Peng, YUAN Yadong. The preparation of phase change material Na2SO4·10H2O with the phase transition temperature at room temperature[J]. Synthetic Materials Aging and Application, 2015, 44(1):39-41+46. [44] CABEZA L C, SVENSSON G, HIEBLER S, et al. Thermal performance of sodium acetate trihydrate thickened with different materials as phase change energy storage material[J]. Applied Thermal Engineering, 2003, 23(13):1697-1704. [45] RAMIREZ B M L G, CHRIS G E, MARTINEZ S M, et al. Tuning of thermal properties of sodium acetate trihydrate by blending with polymer and silver nanoparticles[J]. Applied Thermal Engineering,2014, 62(2):838-844. [46] 杨宜凡, 顾晓滨, 刘鹏. 添加剂对三水醋酸钠的储热性能影响研究[J]. 广州化工, 2017, 45(19):84-86+92. YANG Yifan, GU Xiaobin, LIU Peng. Influence of additives on supercooling of CH3COONa·3H2O as phase change material[J]. Guangzhou Chemical Industry, 2017, 45(19):84-86+92. [47] 盛强, 邢玉明, 王泽. 成核剂对八水氢氧化钡相变材料过冷度的影响[J]. 化工新型材料, 2015, 43(2):100-102. SHENG Qiang, XING Yuming, WANG Ze. Influence ofnucleating agents on the supercooling of Ba(OH)2·8H2O as phase change material[J]. New Chemical Materials, 2015(2):100-102. [48] WU Y, WANG T. Hydrated salts/expanded graphite composite with high thermal conductivity as a shape-stabilized phase change material for thermal energy storage[J]. Energy Conversion and Management, 2015, 101(1):164-171. [49] KIMURA H, KAI J. Phase change stability of CaCl2·6H2O[J]. Solar Energy, 1984, 33(1):49-55. [50] 刘超. 六水氯化钙重结晶的相分层机理和控制研究[J]. 中国建材科技, 2015, 24(3):52-53. LIU Chao. Study on stratiifcation mechanism and conformity of calcium chloride hexahydrate during recrystallization[J]. China Building Materials Science & Technology, 2015, 24(3):52-53. [51] LI X, ZHOU Y, NIAN H. Phase change behavior of latent heat storage media based on calcium chloride hexahydrate composites containing strontium chloride hexahydrate and oxidation expandable graphite[J]. Applied Thermal Engineering, 2016, 102:38-44. [52] 凡海川, 李玉香, 郑召, 等. 不同粒径膨胀蛭石制备复合相变材料试验研究[J]. 非金属矿, 2018, 41(6):63-66. FAN Haichuan, LI Yuxiang, ZHENG Zhao, et al. Experimental study on preparation of composite phase change materials by expanded vermiculite with different particle sizes[J]. Non-Metallic Mines, 2018, 41(6):63-66. [53] 刘磊, 彭犇, 邱桂博, 等. 不同载体的Na2SO4·10H2O基定形相变材料的制备和热性能研究[J]. 人工晶体学报, 2017, 46(12):2374-2379+2385. LIU Lei, PENG Ben, QIU Guibo, et al. Preparation and thermal properties of shape-stabilized Na2SO4·10H2O composite PCM with different carriers[J]. Journal of Synthetic Crystals, 2017, 46(12):2374-2379+2385. [54] 徐笑锋, 章学来, 李玉洋, 等. 十水硫酸钠低温相变材料的制备及稳定性[J]. 化学工程, 2018, 46(10):11-15+25. XU Xiaofeng, ZHANG Xuelai, LI Yuyang, et al. Preparation and stability properties of sodium sulphate PCMs for thermal energy storage[J]. Chemical Engineering, 2018, 46(10):11-15+25. [55] 鄢瑛, 林小花, 张会平. 十二水磷酸氢二钠相变材料的改性研究[J]. 高校化学工程学报, 2011, 25(6):1068-1072. YAN Ying, LIN Xiaohua, ZHANG Huiping. Modification of disodium hydrogen phosphate dodecahydrate phase change material[J]. Journal of Chemical Engineering of Chinese Universities, 2011, 25(6):1068-1072. [56] 陈跃, 纪珺, 徐笑锋, 等. 十二水磷酸氢二钠纳米复合相变材料的过冷特性[J]. 化工进展, 2018, 37(7):2734-2739. CHEN Yue, JI Jun, XU Xiaofeng, et al. Supercooling characteristics of disodium hydrogen phosphate nano-composites phase change materials[J]. Chemical Industrial and Engineering Progress, 2018, 37(7):2734-2739. [57] 郑涛杰, 陈志莉, 刘强, 等. 水合盐相变储能材料增稠剂优选研究[J]. 太阳能学报, 2018, 39(7):1781-1787. ZHENG Taojie, CHEN Zhili, LIU Qiang, et al. Study on optimum agent of thickness for salt hydrate phase change energy storage material[J]. Acta Energiae Solaris Sinica, 2018, 39(7):1781-1787. [58] DANNEMAND M, KONG W Q, FAN J H, et al. Laboratory test of a prototype heat storage module based on stable supercooling of sodium acetate trihydrate[J]. Energy Procedia, 2015, 70:172-181. [59] 赵亮, 邢玉明, 芮州峰, 等. 空气浴条件下三水醋酸钠相变材料的储热性能实验[J]. 复合材料学报, 2018, 35(8):2208-2215. ZHAO Liang, XING Yuming, RUI Zhoufeng, et al. Experimental study on the thermal energy storage characteristic of sodium acetate trihydrate as phase change material under the air bath condition[J]. Acta Materiae Compositae Sinica, 2018, 35(8):2208-2215. [60] 吴东灵, 李廷贤, 何峰, 等. 三水醋酸钠相变储能复合材料改性制备及储/放热特性[J]. 化工学报, 2018, 69(7):2860-2868. WU Dongling, LI Tingxian, HE Feng, et al. Preparation and performance of modified sodium acetate trihydrate composite phase change material for thermal energy storage[J]. CIESC Journal, 2018, 69(7):2860-2868. [61] 韩兴超, 章学来, 华维三, 等. 成核剂对相变材料Ba(OH)2·8H2O储热特性的影响[J]. 化工进展, 2018, 37(7):2727-2733. HAN Xingchao, ZHANG Xuelai, HUA Weisan, et al. Influence of nucleating agents on the heat storage characteristics of phase change material Ba(OH)2·8H2O[J]. Chemical Industrial and Engineering Progress, 2018, 37(7):2727-2733. [62] LI G, ZHANG B B, LI X, et al. The preparation, characterization and modifcation of a new phase change material:CaCl2·6H2O-MgCl2·6H2O eutectic hydrate salt[J]. Solar Energy Materials and Solar Cells, 2014, 126:51-55. [63] 卢竼漪, 侯峰, 徐贵钰. 碳纳米管-无机盐复合成核剂对MgCl2·6H2OCaCl2·6H2O体系储热性能的影响[J]. 稀有金属材料与工程, 2018, 47(s1):277-281. LU Pengyi, HOU Feng, XU Guiyu. Effect of carbon nanotubeinorganic salt composite nucleating agent on thermal storage performance of MgCl2·6H2O-CaCl2·6H2O system[J]. Rare Metal Materials and Engineering, 2018, 47(s1):277-281. [64] 徐玲玲, 沈艳华, 梁斌斌, 等. Na2SO4·10H2O和Na2HPO4·12H2O体系的相变特性[J]. 南京工业大学学报(自然科学版), 2005, 27(4):27-31. XU Lingling, SHEN Yanhua, LIANG Binbin, et al. Study on phase transfer characteristics of system Na2SO4·10H2O and Na2HPO4·12H2O[J]. Journal of Nangjing University of Technology(Science Edition), 2005, 27(4):27-31. [65] 张勇, 邹志荣, 李建明, 等. 日光温室相变空心砌块的制备及功效[J]. 农业工程学报, 2010, 26(2):263-267. ZHANG Yong, ZOU Zhirong, LI Jianming, et al. Preparation of the small concrete hollow block with PCM and its efficacy in greenhouses[J]. Transactions of the Chinese Society of Agricultural Engineering, 2010, 26(2):263-267. [66] 方玉堂, 金策, 梁向晖, 等. 三水醋酸钠/甲酰胺复合相变材料的制备及性能[J]. 化工学报, 2015, 66(12):5142-5148. FANG Yutang, JIN Ce, LIANG Xianghui, et al. Preparation and performance of sodium acetate trihydrate/formamide composite phase change material[J]. CIESC Journal, 2015, 66(12):5142-5148. [67] LI X, ZHOU Y, NIAN H, et al. Preparation and thermal energy storage studies of CH3COONa·3H2O-KCl composites salt system with enhanced phase change performance[J]. Applied Thermal Engineering, 2016, 102:708-715. [68] 乔英钧, 张志宏, 付振海, 等. Na2S2O3·5H2O-CH3COONa·3H2O相变储能材料的性能及改性[J]. 无机盐工业, 2018, 50(11):27-30. QIAO Yingjun, ZHANG Zhihong, FU Zhenhai, et al. Properties and modification of Na2S2O3·5H2O-CH3COONa·3H2O as phase change material[J]. Inorganic Chemicals Industry, 2018, 50(11):27-30. [69] 李秀珍, 吕永康. Mg(NO3)2·6H2O-KNO3(NH4NO3)蓄热材料的制备及相变研究[J]. 无机化学学报, 2009, 25(10):1868-1872. LI Xiuzhen, LV Yongkang. Preparation and phase change effect of Mg(NO3)2·6H2O-KNO3(NH4NO3) for heat storage[J]. Chinese Journal of Inorganic Chemistry, 2009, 25(10):1868-1872. [70] LING Z Y, LIU J W, WANG Q H, et al. MgCl2·6H2O-Mg(NO3)2·6H2O eutectic/SiO2 composite phase change material with improved thermal reliability and enhanced thermal conductivity[J]. Solar Energy Materials and Solar Cells, 2017, 172:195-201. [71] YE R D, ZHANG C, SUN W C, et al. Novel wall panels containing CaCl2·6H2O-Mg(NO3)2·6H2O/expanded graphite composites with different phase change temperatures for building energy savings[J]. Energy & Buildings, 2018, 176:407-417. [72] 王智平, 田禾青, 王克振, 等. 钾明矾基低共熔相变储热材料的制备与研究[J]. 人工晶体学报, 2013, 42(3):491-496. WANG Z P, TIAN H Q, WANG K Z, et al. Preparation and study on the matrix of aluminum potassium sulfate eutectic phase change heat storage materials[J]. Journal of Synthetic Crystals, 2013, 4(3):491-496. [73] 纪珺, 曾涛, 章学来, 等. 改良六水氯化钙相变材料的制备及性能[J]. 低温与超导, 2017, 45(10):71-76. JI Jun, ZENG Tao, ZHANG Xuelai, et al. Preparation and properties of calcium chloride hexahydrate phase change material after modifed[J]. Cryogenics & Superconductivity, 2017, 45(10):71-76. [74] 柳馨, 铁健, 铁生年. 温室多壁碳纳米管芒硝基相变材料储能性能[J]. 农业工程学报, 2016, 32(6):226-231. LIU Xin, TIE Jian, TIE Shengnian. Energy storage properties of mans nitro phase transition materials of multi-walled carbon nano-tubes of greenhouse[J]. Transactions of the Chinese Society of Agricultural Engineering, 2016, 32(6):226-231. [75] 蒋自鹏, 铁生年. 芒硝基相变材料性能及其在简易温室中升温效果试验[J]. 农业工程学报, 2016, 32(20):209-216. JIANG Zipeng, TIE Shengnian. Property and heat storage performances of Glauber's salt-based phase change materials for solar greenhouse in Qinghai-Tibet plateau[J]. Transactions of the Chinese Society of Agricultural Engineering, 2016, 32(20):209-216. [76] 茅靳丰, 黄玉荣, 刁孝发, 等. 三水醋酸钠导热性能改善实验研究[J]. 制冷空调与电力机械, 2010, 31(136):12-15. MAO Jinfeng, HUANG Yurong, DIAO Xiaofa, et al. Experimental study on improvement of thermal conductivity of sodium acetate trihydrate[J]. Refrigeration Air Conditioning&Electric Power Machinery, 2010, 31(136):12-15. [77] 盛强, 邢玉明. Ba(OH)2·8H2O/泡沫铜相变复合材料的制备及传热性能[J]. 复合材料学报, 2014, 31(6):1556-1572. SHENG Qiang, XING Yuming. Preparation and heat transfer performance of Ba(OH)2·8H2O/copper foam phase change composites[J]. Acta Materiae Compositae Sinica, 2014, 31(6):1566-1572. [78] 宋婧, 曾令可, 陈丙璇, 等. 钾明矾热传导性能的研究与改善[J]. 功能材料, 2007, 38(8):1307-1309. SONG Jing, ZENG Lingke, CHEN Bingxuan, et al. Study on thermal conduction properties improvement of aluminum potassium sulfate[J]. Journal of Functional Materials, 2007, 38(8):1307-1309. [79] 蒋希芝, 徐磊, 柳军, 等. 农用低温相变蓄热材料磷酸氢二钠的制备与性能研究[J]. 江苏农业科学, 2017, 45(10):199-201. JIANG Xizhi, XU Lei, LIU Jun, et al. Preparation and properties of disodium hydrogen phosphate as a low temperature phase change regenerative material for agriculture[J]. Jiangsu Agricultural Sciences, 2017, 45(10):199-201. [80] 张宇迪, 章学来, 纪珺, 等. 尿素/三水醋酸钠复合相变材料热物性研究[J]. 能源研究与利用, 2018(6):28-33. ZHANG Yudi, ZHANG Xuelai, JI Jun, et al. Study on thermo-physical properties of urea/sodium acetate trihydrate composite phase change material[J]. Energy Research & Utilization, 2018(6):28-33. [81] YE R D, LIN W Z, FANG X M, et al. A numerical study of building integrated with CaCl2·6H2O/expanded graphite composite phase change material[J]. Applied Thermal Engineering, 2017, 126:480-488. [82] 袁维烨, 章学来, 华维三, 等. 膨胀石墨/三水乙酸钠复合相变材料储热的性能[J]. 化工进展, 2018, 37(11):4405-4411. YUAN Weiye, ZHANG Xuelai, HUA Weisan, et al. Thermal storage performance of sodium acetate trihydrate/expanded graphite composite phase change material[J]. Chemical Industrial and Engineering Progress, 2018, 37(11):4405-4411. [83] 彭勇刚, 纪俊玲, 汪媛, 等. 水合盐相变微胶囊的制备及在调温织物中的应用[J]. 印染助剂, 2016, 33(7):41-43. PENG Yonggang, JI Junling, WANG Yuan, et al. Synthesis of hydrated salt micro-encapsulated phase-change materialsand its application in the thermo-regulating fabric[J]. Textile Auxiliaries, 2016, 33(7):41-43. |
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