Energy Storage Science and Technology ›› 2019, Vol. 8 ›› Issue (1): 116-122.doi: 10.12028/j.issn.2095-4239.2018.0122

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Nitrogen doped secondary particle graphite anode for high capacity and high rate Li ion battery

LI Ronghui1, YAN Wei2, WU Xiaoqiang2, FAN Qinna3   

  1. 1 Tianjin Lishen Battery Joint Stock Co. LTD., Tianjin 300384, China;
    2 Inner Mongolia University for the Nationalities, Tongliao 028000, Inner Mongolia, China;
    3 Shijiazhuang Tiedao University, Shijiazhuang 050043, Hebei, Chian
  • Received:2018-07-20 Revised:2018-10-11 Online:2019-01-01 Published:2018-10-25

Abstract: The high specific capacity with high rate characteristic graphite anode was synthesized by nitrogen doping and secondary particle bonding technologies. The reversible capacity of the obtained graphite was 359.8mAh/g. The full pouch cells with the minimal energy density of 230Wh/Kg (650Wh/L) were assembled to evaluate the electrical performance. The charging capacity can research 51% within 10 minutes, and 100% within 30 minutes, demonstrating an excellent fast charging characteristics. The fast charge cycle test with 3C-rate charge and 1C-rate discharge was conducted at room temperature. It shows that even after 1000 cycles, there is still 88% of the initial capacity, and the maximum swelling rate is 10.1%, which can meet the demand of most electron devices and electric vehicles.

Key words: N doped graphite, secondary particle, fast charge, high specific capacity

CLC Number: