Energy Storage Science and Technology ›› 2020, Vol. 9 ›› Issue (3): 848-855.doi: 10.19799/j.cnki.2095-4239.2019.0258
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LOU Ping1, XU Guohua1, YUE Lingping1, LI Shouding2, CHENG Qi2, CAO Yuancheng2(), DENG Heming3
Received:
2019-11-13
Revised:
2019-12-03
Online:
2020-05-05
Published:
2020-05-11
Contact:
Yuancheng CAO
E-mail:yccao@hust.edu.cn
CLC Number:
LOU Ping, XU Guohua, YUE Lingping, LI Shouding, CHENG Qi, CAO Yuancheng, DENG Heming. Degraded Li x Ni0.5Co0.2Mn0.3O2 (0 < x < 1) via eutectic solutions for direct regeneration of spent lithium ion battery cathodes[J]. Energy Storage Science and Technology, 2020, 9(3): 848-855.
Table 1
Element composition of different NCM523 anodes"
编号 | n(Li)/% | n(Ni)/% | n(Co)/% | n(Mn)/% |
---|---|---|---|---|
失效三元NCM523 | 0.6601 | 0.5027 | 0.2009 | 0.2964 |
300 ℃/4 h | 0.9795 | 0.5133 | 0.2052 | 0.2815 |
300 ℃/3 h | 0.9996 | 0.5073 | 0.2041 | 0.2887 |
300 ℃/2 h | 0.9951 | 0.5116 | 0.2050 | 0.2834 |
300 ℃/4 h-850 ℃/4 h | 1.0252 | 0.5110 | 0.2051 | 0.2839 |
300 ℃/3 h-850 ℃/4 h | 1.0452 | 0.5107 | 0.2065 | 0.2829 |
300℃/2 h-850 ℃/4 h | 1.0238 | 0.5108 | 0.2050 | 0.2842 |
Table 2
XRD patterns parameters of the different samples"
处理条件 | I 003 | I 101 | I 104 | I 003/I 104 | M1 | I 101/I 104 | M2 | a | c | c/a |
---|---|---|---|---|---|---|---|---|---|---|
300 ℃/4 h | 540 | 258 | 640 | 0.84 | 12.41% | 0.40 | 6.78% | 2.87249 | 14.23298 | 4.955 |
300 ℃/3 h | 2812 | 1082 | 2087 | 1.35 | 1.65% | 0.52 | 1.60% | 2.87244 | 14.246 | 4.960 |
300 ℃/2 h | 2879 | 1151 | 2145 | 1.34 | 1.75% | 0.54 | 0.84% | 2.87247 | 14.2428 | 4.958 |
300 ℃/4 h-850 ℃/4 h | 3964 | 1516 | 3162 | 1.25 | 3.48% | 0.48 | 3.28% | 2.87532 | 14.21978 | 4.945 |
300 ℃/3 h-850 ℃/4 h | 3976 | 1529 | 3057 | 1.30 | 2.56% | 0.50 | 2.38% | 2.87122 | 14.23814 | 4.959 |
300 ℃/2 h-850 ℃/4 h | 3030 | 1382 | 2937 | 1.03 | 8.10% | 0.47 | 3.67% | 2.87499 | 14.25395 | 4.958 |
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