Advances in the application of solid-state nuclear magnetic resonance for the study of ion diffusion mechanism in battery materials

doi:10.19799/j.cnki.2095-4239.2020.0317

Abstract

Abstract:

In this review, we introduce the basic principles of solid-state nuclear magnetic resonance (NMR) spectroscopy, focusing on magic angle spinning and cross-polarization, which can reduce or eliminate partial interactions in the nuclear spin system to improve the resolution of NMR spectra. Several solid-state NMR techniques for obtaining ion migration dynamics information are summarized, including pulsed-field gradient NMR, central transition line width analysis, relaxation time analysis, 2D exchange NMR, and spin alignment echo NMR. Further, we review the application of these techniques to a series of typical cases, such as cathode materials, anode materials, LISICON, Thio-LISICON, NASICON, and garnet type solid electrolyte materials. A comparison of the advantages and disadvantages of each technology is also included. Finally, the recent developments in the field of solid-state NMR spectroscopy for the study of the mechanism of ion diffusion in batteries is discussed.

Key words: solid-state NMR, lithium-ion batteries, ionic dynamic, ion diffusion pathway

CLC Number:

TQ 028.8

Hengrui ZHANG, Yue SHEN, Yao YU, Yunhui HUANG, Liwei CHEN. Advances in the application of solid-state nuclear magnetic resonance for the study of ion diffusion mechanism in battery materials[J]. Energy Storage Science and Technology, 2020, 9(S1): 78-94.

Figures/Tables 15

References 65

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