Recent progress in shape-stabilized phase change materials

doi:10.3969/j.issn.2095-4239.2013.04.004

Abstract

Abstract: Shape-stabilized phase change materials (SSPCM) uses polymer as a matrix with the phase change materials dispersed in the matrix. SSPCM shows a solid state macroscopically and hence possesses some salient features including excellent mechanical properties, good processability and high safety. This paper provides a review on the SSPCM, including preparation, thermal conductivity enhancement and flame retardation. An assessment is then made on the use of the materials with a specific focus on energy saving in buildings.

Key words: shape-stabilized phase change materials, polymer, flame retardation, thermal conductivity, simulation

CLC Number:

O631

WANG Yi, YANG Rui, ZHANG Yinping, WANG Xin. Recent progress in shape-stabilized phase change materials[J]. Energy Storage Science and Technology, 2013, 2(4): 362-368.

References

[1] Wang Yi(王毅),Xia Tiandong(夏天东),Feng Huixia(冯辉霞). Research and development of heat storage using organic phase change materials[J]. Mater. Rev. (材料导报),2011,25(2):66-74.
[2] Xie Pengcheng(谢鹏程),Yan Hua(晏华),Yu Rongsheng(余荣升). Recent progress in solid-liquid shape-stabilized phase change materials[J]. China Storage & Transport (中国储运),2012(11):59-61.
[3] Inaba H,Tu P. Evaluation of thermal physical characteristics on shape stabilized paraffin as a solid-liquid phase change material[J]. Heat and Mass Transfer ,1997,32(4):307-312.
[4] Ye H,Ge X. Preparation of polyethylene-paraffin compound as a form-stable solid-liquid phase change material[J]. Solar Energy Materials and Solar Cells ,2000,64:37-44.
[5] Sari A. Form-stable paraffin/high density polyethylene composites as solid-liquid phase change material for thermal energy storage:Preparation and thermal properties[J]. Energy Convers. Mgmt. ,2004,45(13-14):2033-2042.
[6] Qin Penghua(秦鹏华),Yang Rui(杨睿),Zhang Yinping(张寅平). Thermal performance of shape-stabilized phase-change materials[J]. Journal of Tsinghua University : Science & Technology (清华大学学报:自然科学版),2003,43(6):833-835.
[7] Chen Yunshen(陈云深),Chen Kai(陈凯),Shen Binjun(沈斌君), et al . Preparation of cross2 linked shape-stabilized phase change materials[J]. Acta Materiae Compositae Sinica (复合材料学报),2006,23(3):67-70.
[8] Lin K,Zhang Y,Xu X, et al . Experimental study of under-floor electric heating system with shape-stabilized PCM plates[J]. Energy and Buildings ,2005,37(3):215-220.
[9] Krupa I,Mikova G,Luyt A S. Polypropylene as a potential matrix for the reaction of shape stabilized phase change materials[J]. Eur. Polym. ,2007,43:895-907.
[10] Krupa I,Mikova G,Luyt AS. Phase change materials based on low-density polyethylene/paraffin wax blends[J]. Eur. Polym. , 2007,43:4695-4705.
[11] Alkan C,Kaya K,Sarı A. Preparation, thermal properties and thermal reliability of form-stable paraffin/polypropylene composite for thermal energy storage[J]. Polym. Environ. ,2009,17:254-258.
[12] Liu Xing(刘星),Wang Shujun(汪树军),Liu Hongyan(刘红研). Research of paraffin-polyolefins as form-stable phase change materials[J]. Fine Chemicals (精细化工),2006,23(3):209-211.
[13] Luo Chaoyun(罗超云),Lin Xuechun(林雪春),Xiao Wangdong(肖望东), et al . Research on different polyolefin encapsulating paraffin as form-stable phase change materials[J]. New Chemical Materials (化工新型材料),2010(7):100-102.
[14] Xiao M,Feng B,Gong K. Thermal performance of a high conductive shape-stabilized thermal storage material[J]. Solar Energy Materials and Solar Cells ,2001,69:293-296.
[15] Song G,Ma S,Tang G, et al . Preparation and characterization of flame retardant form-stable phase change materials composed by EPDM,paraffin and nano magnesium hydroxide[J]. Energy ,2010,35(5):2179-2183.
[16] Xu X,Zhang Y,Lin K, et al. Modeling and simulation on the thermal performance of shape-stabilized phase change material floor used in passive solar buildings[J]. Energy and Buildings ,2005,37(10):1084-1091.
[17] Zhang Y P,Lin K P,Yang R,Di H F,Jiang Y. Preparation,thermal performance and application of shape-stabilized PCM in energy efficient buildings[J]. Energy Build ,2006,38(10):1262-1269.
[18] Cai Y,Hu Y,Song L,Lu H,Chen Z,Fan W. Preparation and characterizations of HDPE-EVA alloy/OMT nanocomposites / paraffin compounds as a shape stabilized phase change thermal energy storage material [J]. Thermochimica Acta ,2006,451(1-2):44-51.
[19] Wirtz R A,Peng S,Fuchs A. A polymer-based thermal energy storage composite for temperature control of sensors and electronics in paper TED-AJ03-359[C]//The 6th ASME-JSME Thermal Engineering Joint Conference,2003.
[20] Sari A,Alkan C,Kolemen U,Uzun O. Eudragit S(methyl methacrylate methacrylic acid copolymer)/fatty acid blends as form-stable phase change material for latent heat thermal energy storage[J]. Applied Polymer ,2006,101(3):1401-406.
[21] Kaygusuz K,Alkan C,Sarı A,Uzun O. Encapsulated fatty acids in an acrylic resin as shape-stabilized phase change materials for latent heat thermal energy storage[J]. Energy Sources : Recovery, Utilization and Environmental Effects ,2008,30(11):1050-1059.
[22] Sari A,Kaygusuz K. Studies on poly(vinyl chloride)/fatty acid blends as shape-stabilized phase change material for latent heat thermal energy storage[J]. Indian Eng. Mater. Sci. ,2006,13:253-258.
[23] Sari A,Kaygusuz K. Poly(vinyl alcohol)/fatty acid blends for thermal energy storage[J]. Energy Sources : Recovery, Utilization and Environmental Effects ,2007,29(10):873-883.
[24] Sari A,Alkan C,Karaipekli A,Onal A. Preparation, characterization and thermal properties of styrene maleic anhydride copolymer (SMA)/fatty acid composites as form stable phase change materials[J]. Energy Convers. Mgmt. ,2008,49:373-380.
[25] Alkan C,Sari A. Fatty acid/ poly(methyl methacrylate)blends as form-stable phase change materials for latent heat storage[J]. Solar Energy ,2008,82(2):118-124.
[26] Wang L,Meng D. Fatty acid eutectic/polymethyl methacrylate composite as form-stable phase change material for thermal energy storage[J]. Applied Energy ,2010,87:2660-2665.
[27] Zhang Y,Ding J,Wang X, et al . Influence of additives on thermal conductivity of shape-stabilized phase change material[J]. Solar Energy Materials and Solar Cells ,2006,90(11):1692-1702.
[28] Sari A,Karaipekli A. Thermal conductivity and latent heat thermal energy storage characteristics of paraffin/expanded graphite composite as phase change material[J]. Applied Thermal Engineering ,2007,27:1271-1277.
[29] Cheng Wenlong,Zhang Rongming,Xie Kun. Heat conduction enhanced shape-stabilized paraffin/HDPE composite PCMs by graphite addition:Preparation and thermal properties[J]. Solar Energy Materials and Solar Cells ,2010,94:1636-1642.
[30] Mhike W,Focke W W,Mofokeng J P. Thermally conductive phase-change materials for energy storage based on low-density polyethylene,soft Fischer-Tropsch wax and graphite[J]. Thermochimica Acta ,2012,527:75-82.
[31] Ji P,Sun H,Zhong Y, et al . Improvement of the thermal conductivity of a phase change material by the functionalized carbon nanotubes[J]. Chemical Engineering Science ,2012,81:140-145.
[32] Teng T P,Cheng C M,Cheng C P. Performance assessment of heat storage by phase change materials containing MWCNTs and graphite[J]. Applied Thermal Engineering ,2012,50(1):637-644.
[33] Zeng J L,Zhu F R,Yu S B, et al . Effects of copper nanowires on the properties of an organic phase change material[J]. Solar Energy Materials and Solar Cells ,2012,105:174-178.
[34] Tang B,Qiu M,Zhang S. Thermal conductivity enhancement of PEG/SiO 2 composite PCM by in situ Cu doping[J]. Solar Energy Materials and Solar Cells ,2012,105:242-248.
[35] Cai Y,Hu Y,Song L, et al . Flammability and thermal properties of high density polyethylene/paraffin hybrid as a form-stable phase change material[J]. Journal of Applied Polymer Science ,2006,99(4):1320-1327.
[36] Cai Y,Hu Y,Song L, et al . Preparation and flammability of high density polyethylene/paraffin/organophilic montmorillonite hybrids as a form stable phase change material[J]. Energy Conversion and Management ,2007,48(2):462-469.
[37] Sittisart P,Farid M M. Fire retardants for phase change materials[J]. Applied Energy ,2011,88(9):3140-3145.
[38] Yan Q,Li L,Liang C. Thermal performance of shape-stabilized phase change paraffin wallboard[J]. Sustain Energy ,2010,29(4):185-190.
[39] Lin K,Zhang Y,Xu X, et al . Modeling and simulation of under-floor electric heating system with shape-stabilized PCM plates[J]. Building and Environment ,2004,39(12):1427-1434.
[40] Zhou G B,Zhang Y P,Wang X,Lin K P,Xiao W. An assessment of mixed type PCM-gypsum and shape-stabilized PCM plates in a building for passive solar heating[J]. Solar Energy ,2007,81:1351-1360.
[41] Zhou G B,Zhang Y P,Zhang Q L,Lin K P,Di H F. Performance of a hybrid heating system with thermal storage usingshape-stabilized phase-change material plates[J]. Applied Energy ,2007,84:1068-1077.
[42] Zhou G,Zhang Y,Lin K,Xiao W. Thermal analysis of a direct-gain room with shape-stabilized PCM plates[J]. Renew Energy ,2008,33:1228-1236.
[43] Zhou G B,Zhang Y P,Wang X,Zhou S X. Numerical analysis of effect of shape stabilized phase change material plates in a building combined with night ventilation[J]. Applied Energy ,2009,86(1):52-59.