Energy Storage Science and Technology ›› 2022, Vol. 11 ›› Issue (6): 1706-1714.doi: 10.19799/j.cnki.2095-4239.2021.0556

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Effect of lithium acrylic-coated nature graphite on its electrochemical properties

WANG Can1(), MA Pan1(), ZHU Guoliang2, WEI Shuimiao1, YANG Zhilu1, ZHANG Zhiyu1   

  1. 1.Shanghai University of Engineering Science, Shanghai 201620, China
    2.Shanghai Jiao Tong University, Shanghai 200242, China
  • Received:2021-10-23 Revised:2021-11-20 Online:2022-06-05 Published:2022-06-13
  • Contact: MA Pan E-mail:2074578281@qq.com;mapan@sues.edu.cn

Abstract:

The effect of lithium acrylate content on the electrochemical performance of natural graphite was systematically analyzed using lithium acrylic, an organic small molecule salt containing carbon-carbon double bonds, to form an elastic solid electrolyte interphase (SEI) layer on the graphite surface through self-polymerization. The results reveal that at 5% lithium acrylic content, the overall electrochemical performance of lithium-ion batteries, including the first Coulomb efficiency, multiplicity performance, and high current long cycle performance, is significantly improved, thereby effectively suppressing side reactions on the graphite surface and inhibiting the rise of electrode impedance during the electrochemical cycle.

Key words: lithium-ion battery, natural graphite, lithium acrylic, SEI layer, self-polymerization

CLC Number: