Energy Storage Science and Technology ›› 2023, Vol. 12 ›› Issue (3): 743-753.doi: 10.19799/j.cnki.2095-4239.2022.0738

• Energy Storage Materials and Devices • Previous Articles     Next Articles

Electrochemical performance of chemical prelithiated Li xMg, Ni, Zn, Cu, Co1-x O high-entropy oxide as anode material for lithium ion battery

Shugang LIU1(), Bo MENG2, Zhenglong LI3, Yaxiong YANG3(), Jian CHEN1   

  1. 1.The Materials Science and Chemical Engineering of Xi'an Technological University, Xi'an 710021, Shaanxi, China
    2.The Fourth Academy of CASC, Xi'an 710025, Shaanxi, China
    3.Institute of Science and Technology for New Energy of Xi'an Technological University, Xi'an 710021, Shaanxi, China
  • Received:2022-12-09 Revised:2022-12-16 Online:2023-03-05 Published:2023-01-18
  • Contact: Yaxiong YANG E-mail:897260704@qq.com;yangyaxiong@xatu.edu.cn

Abstract:

High-entropy oxides, a new class of single-phase solid solution materials, have recently attracted significant attention as conversion-type anode material for lithium-ion batteries (LIBs). Prelithiated Li x (Mg, Ni, Zn, Cu, Co)1-x O (x=0, 0.08, 0.16, 0.2) high-entropy oxide anode materials are synthesized by a chemical reaction of LiH with metal oxides, and the electrochemical performance of the prepared high-entropy oxides are investigated in this study. Introduction of low-valence Li+ in the lattice and charge compensation effect facilitate the formation of Co3+, Ni3+ and oxygen vacancies. Existence of high-valence Co3+ and Ni3+ increases the electron transfer number of the conversion reaction. The oxygen vacancies promote the electron/ion transportation of the oxide electrode and improve the conversion reaction kinetics. Meanwhile, the inactive Mg2+ makes the high entropy oxides maintain the stable rock salt structure upon lithiation/delithiation, which ensures the structural stability during the electrochemical process. As a result, a high reversible specific capacity (679 mAh/g at 100 mA/g), an improved first Coulomb efficiency (63.7%), a decreased polarization (voltage discrepancy between charge and discharge plateaus of -0.9 V), a good cycling stability and high rate capability (reversible specific capacity of 651 mAh/g after 800 cycles at 1000 mA/g) are achieved for prelithiated Li0.16(Mg, Ni, Zn, Cu, Co)0.84O high-entropy oxide anode material.

Key words: lithium-ion batteries, anode materials, high-entropy oxides, prelithiation

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