Energy Storage Science and Technology ›› 2024, Vol. 13 ›› Issue (6): 2022-2029.doi: 10.19799/j.cnki.2095-4239.2023.0953
• Energy Storage Test: Methods and Evaluation • Previous Articles Next Articles
Zhengde TAO(), Zhichao ZHANG(
), Changliang GUO
Received:
2023-12-28
Revised:
2024-01-18
Online:
2024-06-28
Published:
2024-06-26
Contact:
Zhichao ZHANG
E-mail:t1595031208@163.com;17806240276@163.com
CLC Number:
Zhengde TAO, Zhichao ZHANG, Changliang GUO. Reverse simulation modeling and parameter identification of power batteries based on electrochemical-thermal coupling model[J]. Energy Storage Science and Technology, 2024, 13(6): 2022-2029.
Table 2
Cell parameter table"
序号 | 项目 | 电池参数 | 正极 | 负极 | 注释 |
---|---|---|---|---|---|
1 | 电池尺寸 | 电芯宽度/mm | 144.33 | 干电芯宽度(含隔膜伸出部分) | |
电芯高度/mm | 91.47 | 干电芯高度(含隔膜伸出部分) | |||
电芯厚度/mm | 24.7 | 干电芯厚度(含隔膜伸出部分) | |||
2 | 集流体 | 材料 | 铝 | 铜 | 材质 |
厚度/um | 9 | 7 | 厚度 | ||
宽度/mm | 140.71 | 141.09 | 宽度 | ||
长度/mm | 85.82 | 89.5 | 长度 | ||
3 | 活性材料 | 材料 | NCM622 | 石墨 | 材料成分 |
真密度/(g/cm3) | 4.8 | 2.3 | 真实密度 | ||
颗粒粒径/μm | 1.65×10-6 | 5.97×10-6 | D50直径 | ||
质量分数 | 0.967 | 0.985 | 混料质量分数 | ||
4 | 导电剂 | 材料 | superC65 | SBR | 材料成分 |
真密度/(g/cm3) | 2.26 | 1.8 | 真实密度 | ||
质量分数 | 0.0186 | 0.013 | 混料质量分数 | ||
5 | 黏结剂 | 材料 | PVDF5130 | CMC2200 | 材料成分 |
真密度/(g/cm3) | 1.8 | 1.8 | 真实密度 | ||
质量分数 | 0.0154 | 0.033 | 混料质量分数 | ||
6 | 涂层 | 厚度/μm | 108 | 133 | 双面加箔材,辊压回弹后厚度 |
宽度/mm | 140.71 | 141.09 | 极片料区宽度 | ||
高度/mm | 85.82 | 89.5 | 极片料区长度 | ||
单面涂布面质量/(g/m2) | 161 | 102 | 单面涂布固相材料面质量 | ||
涂层固相电阻率/(Ω⋅cm) | 47.1 | 0.6 | 涂层固相电阻率 | ||
孔隙率 | 0.66 | 0.67 | 孔隙率 | ||
7 | 隔膜 | 厚度/um | 14 | 厚度 | |
孔隙率 | 0.4 | 孔隙率 | |||
隔膜NM值 | 15.7 | 拟合值 | |||
8 | 电解液 | 锂盐成分 | LiPF6 | 如LiPF6 | |
锂盐浓度/(mol/L) | 1.2 | 来自材料库 | |||
溶剂成分 | EC, EMC, DEC | 如EC, PC, EMC | |||
溶剂成分、质量分数 | 31∶46∶23 | 如70∶20∶10 | |||
9 | 电池基本 特性参数 | 质量/g | 916 | 电池质量 | |
容量/Ah | 58 | 电池设计容量(明确定容倍率) | |||
卷心导热系数/[W/(m⋅K)] | 20 | 来自文献 | |||
电池比热容/[J/(g⋅K)] | 1133 | 来自文献 | |||
上限电压/V | 4.35 | 来自规格书 | |||
下限电压/V | 2.75 | 来自规格书 | |||
正极上下限电压/V | 3.0~4.35 | 来自规格书 | |||
负极上下限电压/V | 0.005~1.0 | 来自规格书 | |||
10 | 活性材料 | 开路电压/V | 来自实验 | 开路电压随嵌锂量的变化 | |
熵系数/(V/K) | 来自实验 | 熵系数随嵌锂量的变化 | |||
扩散系数/(m2/s) 与活化能/(J/mol) | 5.00×10-13 | 4.50×10-13 | 25℃扩散系数与活化能 | ||
30000 | 40000 | ||||
反应速率常数/(m/s)与活化能/(J/mol) | 1.79×10-11 | 3.80×10-11 | 25℃反应速率常数与活化能 | ||
16738 | 15176 | ||||
11 | 电解液 | 电导率/(S/m) | 来自材料库 | 随锂离子浓度和温度的变化 | |
扩散系数/(m2/s) | 来自材料库 | 随锂离子浓度和温度的变化 | |||
锂离子迁移数 | 来自材料库 | 随锂离子浓度和温度的变化 | |||
活度相关性 | 来自材料库 | 锂离子浓度和温度的变化 | |||
12 | 极片 | 涂层迂曲度 | 2.2 | 2.92 | — |
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