储能科学与技术 ›› 2024, Vol. 13 ›› Issue (1): 178-192.doi: 10.19799/j.cnki.2095-4239.2023.0784
• 高比能二次电池关键材料与先进表征专刊 • 上一篇 下一篇
李宇航(
), 韩卓, 安旭飞, 张丹丰, 郑国瑞, 柳明(), 贺艳兵()
收稿日期:2023-11-01
修回日期:2023-11-06
出版日期:2024-01-05
发布日期:2024-01-22
通讯作者:
柳明,贺艳兵
E-mail:l-yh23@mails.tsinghua.edu.cn;liuming@sz.tsinghua.edu.cn;he.yanbing@sz.tsinghua.edu.cn
作者简介:李宇航（1998—），男，博士研究生，研究方向为固态电解质，E-mail：l-yh23@mails.tsinghua.edu.cn；
基金资助:
Yuhang LI(), Zhuo HAN, Xufei AN, Danfeng ZHANG, Guorui ZHENG, Ming LIU(), Yanbing HE()
Received:2023-11-01
Revised:2023-11-06
Online:2024-01-05
Published:2024-01-22
Contact:
Ming LIU, Yanbing HE
E-mail:l-yh23@mails.tsinghua.edu.cn;liuming@sz.tsinghua.edu.cn;he.yanbing@sz.tsinghua.edu.cn
摘要：
中图分类号:
李宇航, 韩卓, 安旭飞, 张丹丰, 郑国瑞, 柳明, 贺艳兵. 固体核磁共振技术解析固态电池离子输运机制研究进展[J]. 储能科学与技术, 2024, 13(1): 178-192.
Yuhang LI, Zhuo HAN, Xufei AN, Danfeng ZHANG, Guorui ZHENG, Ming LIU, Yanbing HE. Progress of ion transport in solid-state battery research based on solid state nuclear magnetic resonance[J]. Energy Storage Science and Technology, 2024, 13(1): 178-192.
图1
LAO-LLZOF无机固态电解质 6Li-7Li置换实验结果[17](1 ppm=10-6)"
图2
(a) 通过单脉冲(黑线)和饱和反转脉冲(红线和蓝线)的方法测得的Li6-3y Al y La3Zr1.5W0.5O陶瓷电解质的 6Li魔角旋转谱[20]；(b) Li6-3y Al y La3Zr1.5W0.5O固态电解质的二维交换谱[20]；(c) PEO-LAGP复合固态电解质 6Li-7Li置换实验结果[21]；(d) PVDF-LATP复合固态电解质离子传输示意图[3]"
图3
LiTFSI-PEO固态电解质固体核磁结果：(a) 固态电解质 7Li谱以及 (b), (c) 7Li-7Li和 6Li-6Li二维交换谱；(d), (e) 1H-6Li交叉极化谱及其异核相关谱；(f) 复合电解质中锂离子扩散路径示意图[30]"
图4
(a) BTO-LLTO纳米线的作用机制；(b) 复合固态电解质 6Li-7Li置换实验结果[31]"
图5
固态电池LiFePO4(LFP)正极的锂离子输运机制示意图：(a) 传统正极的传输路径；(b) 添加La2Zr2O7 纳米线(LZONs)的复合正极的传输路径；(c) 传统正极在空隙和 (d) PEO黏结剂中的锂离子传输路径；(e) 锂盐在PEO黏结剂中的解离；(f) 在嵌入LZONs和 (g) PEO@LZONs复合材料黏结剂的复合正极内的“固体-聚合物-固体”弹性锂离子传输路径；(h) 锂盐在PEO@LZONs黏结剂中的解离和对TFSI- 阴离子的吸附；(i) LZONs的锂离子传输隧道 (j) 循环后正极 7Li核磁谱[46]"
图6
(a), (b) 原位固体核磁共振锂金属信号的等高线图及对应的充放电曲线；(c), (d), (e), (f) 四种体系中的固体核磁共振锂金属信号的积分结果[50]"
图7
(a) LPSC和Li2S-LiI粉末混合物的二维交换光谱；(b), (c) 交叉峰强度对 Tmix 的函数；(d), (e) 通过拟合 (b), (d) 中的数据获得的变温扩散系数；(f) Li2S(LiI)-LPSC-C正极混合物中提出的Li+ 传输机制示意图[62]"
图8
LiV2O5 和Li2V2O5 与LAGP的界面及其对离子传输的影响[69]"
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