高比能二次电池正极材料的X射线谱学研究进展

doi:10.19799/j.cnki.2095-4239.2023.0802

储能科学与技术 ›› 2024, Vol. 13 ›› Issue (1): 113-129.doi: 10.19799/j.cnki.2095-4239.2023.0802

• 高比能二次电池关键材料与先进表征专刊 • 上一篇下一篇

高比能二次电池正极材料的X射线谱学研究进展

陈淑媛¹(), 程晨¹(), 夏啸¹, 鞠焕鑫²(), 张亮¹^,³()

^1.苏州大学功能纳米与软物质研究院，江苏苏州 215123
^2.PHI表面分析实验室，爱发科费恩斯（南京）仪器有限公司，江苏南京 211111
^3.江苏省先进负碳技术重点实验室，江苏苏州 215123

收稿日期:2023-11-07 修回日期:2023-11-23 出版日期:2024-01-05 发布日期:2024-01-22
通讯作者: 鞠焕鑫,张亮 E-mail:20224214077@stu.suda.edu.cn;chencheng2023@suda.edu.cn;huanxin.ju@coretechint.com;liangzhang2019@suda.edu.cn
作者简介:陈淑媛（2000—），女，硕士研究生，研究方向为钠离子电池层状氧化物正极材料，E-mail：20224214077@stu.suda.edu.cn；
程晨（1995—），男，博士，研究方向为钠离子电池正极材料的原位同步辐射表征及调控机制，E-mail：chencheng2023@suda.edu.cn；
基金资助:
国家自然科学基金(12275189)

Research progress in the X-ray spectroscopy investigation of cathode materials for high-energy-density secondary batteries

Shuyuan CHEN¹(), Chen CHENG¹(), Xiao XIA¹, Huanxin JU²(), Liang ZHANG¹^,³()

^1.Institute of Functional Nano & Soft Materials, Suzhou 215123, Jiangsu, China
^2.PHI Analytical Laboratory, ULVAC-PHI Instruments Co. , Ltd. , Nanjing 21111, Jiangsu, China
^3.Jiangsu Key Laboratory of Advanced Negative Carbon Technologies, Suzhou 215123, Jiangsu, China

Received:2023-11-07 Revised:2023-11-23 Online:2024-01-05 Published:2024-01-22
Contact: Huanxin JU, Liang ZHANG E-mail:20224214077@stu.suda.edu.cn;chencheng2023@suda.edu.cn;huanxin.ju@coretechint.com;liangzhang2019@suda.edu.cn

摘要/Abstract

摘要：

二次电池具有高能量密度和长循环寿命等特点，为储存并利用清洁能源提供了有效的解决方案。为了满足社会日益增长的能源需求，进一步研究和开发二次电池迫在眉睫，而X射线表征技术可以为二次电池的研究、设计与应用提供全方位视角。基于此，本综述通过对近几年相关文献进行归纳总结，综述了X射线谱学技术在二次电池领域的最新进展以及遇到的问题，重点介绍了X射线表征技术（主要包括X射线光电子能谱、X射线吸收谱和共振非弹性X射线散射等）的基本原理、在二次电池领域的最新研究成果和科学挑战，详细阐释了不同X射线表征手段的技术特点、适用条件和独特优势，并对未来X射线谱学在二次电池领域的应用提出展望。综合分析表明，X射线表征技术可以提供一系列电极材料晶格、电子、物相结构等基本信息，实现从宏观尺度到微观尺度的电极材料结构表征，进而系统揭示电极材料晶体结构与电子结构演变、电荷补偿机制、离子与电子输运以及表界面化学过程等信息，为二次电池性能提升和技术瓶颈突破提供支持。

关键词: 二次电池, 正极材料, X射线谱学, 同步辐射

Abstract:

Secondary batteries offer the advantages of high energy density and long cycle life, which have provided an effective solution for the storage and use of clean energy. To meet the ever-increasing demand of our society for energy, further in-depth research and development of high-energy-density secondary batteries are imminent. X-ray characterization techniques can provide a comprehensive insight into the research, design, and application of secondary batteries. This review summarizes relevant literature studies published in recent years, with a review of the latest progress and challenges of the X-ray spectroscopy methods in the research of secondary batteries. This review focuses on the technical principles, latest progress, and major scientific challenges of different X-ray characterization techniques, primarily including X-ray photoelectron spectroscopy, X-ray absorption spectroscopy, and resonant inelastic X-ray scattering. The technical characteristics, applicable conditions, and main advantages of different X-ray characterization methods are explained in detail, and the future application of X-ray spectroscopy in the field of secondary batteries is prospected. Comprehensive analysis shows that the X-ray technology provides various advanced characterization techniques that are sensitive and non-destructive to the lattice, electrons, and morphological structure of the electrode materials, and the structure of the electrode materials could be characterized from the macroscopic scale to the microscopic scale, reflecting the corresponding crystal structure and electronic structure evolution, charge compensation mechanism, ion and electron transport, and surface/interface chemical processes of electrode materials. Consequently, X-ray characterization techniques provide technical support for the design of high-performance secondary batteries.

Key words: secondary batteries, cathode materials, X-ray spectroscopy, synchrotron radiation

中图分类号:

TM 911

陈淑媛, 程晨, 夏啸, 鞠焕鑫, 张亮. 高比能二次电池正极材料的X射线谱学研究进展[J]. 储能科学与技术, 2024, 13(1): 113-129.

Shuyuan CHEN, Chen CHENG, Xiao XIA, Huanxin JU, Liang ZHANG. Research progress in the X-ray spectroscopy investigation of cathode materials for high-energy-density secondary batteries[J]. Energy Storage Science and Technology, 2024, 13(1): 113-129.

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高比能二次电池正极材料的X射线谱学研究进展

Research progress in the X-ray spectroscopy investigation of cathode materials for high-energy-density secondary batteries

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