定形相变材料的研究进展

doi:10.3969/j.issn.2095-4239.2013.04.004

摘要/Abstract

摘要： 定形相变材料是以聚合物为基体,相变物质分布在聚合物三维网状结构中的一种新型相变材料.定形相变材料在相变过程中表现为宏观固相,微观液相,支撑和力学性能优秀,不易泄漏,因其优良的加工性能和安全性能而受到广泛关注,并表现出了广阔的应用前景.本文综述了定形相变材料的制备,导热和阻燃性能等方面的研究进展,并从实验和模拟两方面综合评价了定形相变材料在建筑节能方面的使用性能,展望了定形相变材料的发展前景.

关键词: 定形相变材料, 聚合物, 阻燃, 导热, 模拟

Abstract: Shape-stabilized phase change materials (SSPCM) uses polymer as a matrix with the phase change materials dispersed in the matrix. SSPCM shows a solid state macroscopically and hence possesses some salient features including excellent mechanical properties, good processability and high safety. This paper provides a review on the SSPCM, including preparation, thermal conductivity enhancement and flame retardation. An assessment is then made on the use of the materials with a specific focus on energy saving in buildings.

Key words: shape-stabilized phase change materials, polymer, flame retardation, thermal conductivity, simulation

中图分类号:

O631

汪意, 杨睿, 张寅平, 王馨. 定形相变材料的研究进展[J]. 储能科学与技术, 2013, 2(4): 362-368.

WANG Yi, YANG Rui, ZHANG Yinping, WANG Xin. Recent progress in shape-stabilized phase change materials[J]. Energy Storage Science and Technology, 2013, 2(4): 362-368.

参考文献

[1] Wang Yi(王毅),Xia Tiandong(夏天东),Feng Huixia(冯辉霞). Research and development of heat storage using organic phase change materials[J]. Mater. Rev. (材料导报),2011,25(2):66-74.
[2] Xie Pengcheng(谢鹏程),Yan Hua(晏华),Yu Rongsheng(余荣升). Recent progress in solid-liquid shape-stabilized phase change materials[J]. China Storage & Transport (中国储运),2012(11):59-61.
[3] Inaba H,Tu P. Evaluation of thermal physical characteristics on shape stabilized paraffin as a solid-liquid phase change material[J]. Heat and Mass Transfer ,1997,32(4):307-312.
[4] Ye H,Ge X. Preparation of polyethylene-paraffin compound as a form-stable solid-liquid phase change material[J]. Solar Energy Materials and Solar Cells ,2000,64:37-44.
[5] Sari A. Form-stable paraffin/high density polyethylene composites as solid-liquid phase change material for thermal energy storage:Preparation and thermal properties[J]. Energy Convers. Mgmt. ,2004,45(13-14):2033-2042.
[6] Qin Penghua(秦鹏华),Yang Rui(杨睿),Zhang Yinping(张寅平). Thermal performance of shape-stabilized phase-change materials[J]. Journal of Tsinghua University : Science & Technology (清华大学学报:自然科学版),2003,43(6):833-835.
[7] Chen Yunshen(陈云深),Chen Kai(陈凯),Shen Binjun(沈斌君), et al . Preparation of cross2 linked shape-stabilized phase change materials[J]. Acta Materiae Compositae Sinica (复合材料学报),2006,23(3):67-70.
[8] Lin K,Zhang Y,Xu X, et al . Experimental study of under-floor electric heating system with shape-stabilized PCM plates[J]. Energy and Buildings ,2005,37(3):215-220.
[9] Krupa I,Mikova G,Luyt A S. Polypropylene as a potential matrix for the reaction of shape stabilized phase change materials[J]. Eur. Polym. ,2007,43:895-907.
[10] Krupa I,Mikova G,Luyt AS. Phase change materials based on low-density polyethylene/paraffin wax blends[J]. Eur. Polym. , 2007,43:4695-4705.
[11] Alkan C,Kaya K,Sarı A. Preparation, thermal properties and thermal reliability of form-stable paraffin/polypropylene composite for thermal energy storage[J]. Polym. Environ. ,2009,17:254-258.
[12] Liu Xing(刘星),Wang Shujun(汪树军),Liu Hongyan(刘红研). Research of paraffin-polyolefins as form-stable phase change materials[J]. Fine Chemicals (精细化工),2006,23(3):209-211.
[13] Luo Chaoyun(罗超云),Lin Xuechun(林雪春),Xiao Wangdong(肖望东), et al . Research on different polyolefin encapsulating paraffin as form-stable phase change materials[J]. New Chemical Materials (化工新型材料),2010(7):100-102.
[14] Xiao M,Feng B,Gong K. Thermal performance of a high conductive shape-stabilized thermal storage material[J]. Solar Energy Materials and Solar Cells ,2001,69:293-296.
[15] Song G,Ma S,Tang G, et al . Preparation and characterization of flame retardant form-stable phase change materials composed by EPDM,paraffin and nano magnesium hydroxide[J]. Energy ,2010,35(5):2179-2183.
[16] Xu X,Zhang Y,Lin K, et al. Modeling and simulation on the thermal performance of shape-stabilized phase change material floor used in passive solar buildings[J]. Energy and Buildings ,2005,37(10):1084-1091.
[17] Zhang Y P,Lin K P,Yang R,Di H F,Jiang Y. Preparation,thermal performance and application of shape-stabilized PCM in energy efficient buildings[J]. Energy Build ,2006,38(10):1262-1269.
[18] Cai Y,Hu Y,Song L,Lu H,Chen Z,Fan W. Preparation and characterizations of HDPE-EVA alloy/OMT nanocomposites / paraffin compounds as a shape stabilized phase change thermal energy storage material [J]. Thermochimica Acta ,2006,451(1-2):44-51.
[19] Wirtz R A,Peng S,Fuchs A. A polymer-based thermal energy storage composite for temperature control of sensors and electronics in paper TED-AJ03-359[C]//The 6th ASME-JSME Thermal Engineering Joint Conference,2003.
[20] Sari A,Alkan C,Kolemen U,Uzun O. Eudragit S(methyl methacrylate methacrylic acid copolymer)/fatty acid blends as form-stable phase change material for latent heat thermal energy storage[J]. Applied Polymer ,2006,101(3):1401-406.
[21] Kaygusuz K,Alkan C,Sarı A,Uzun O. Encapsulated fatty acids in an acrylic resin as shape-stabilized phase change materials for latent heat thermal energy storage[J]. Energy Sources : Recovery, Utilization and Environmental Effects ,2008,30(11):1050-1059.
[22] Sari A,Kaygusuz K. Studies on poly(vinyl chloride)/fatty acid blends as shape-stabilized phase change material for latent heat thermal energy storage[J]. Indian Eng. Mater. Sci. ,2006,13:253-258.
[23] Sari A,Kaygusuz K. Poly(vinyl alcohol)/fatty acid blends for thermal energy storage[J]. Energy Sources : Recovery, Utilization and Environmental Effects ,2007,29(10):873-883.
[24] Sari A,Alkan C,Karaipekli A,Onal A. Preparation, characterization and thermal properties of styrene maleic anhydride copolymer (SMA)/fatty acid composites as form stable phase change materials[J]. Energy Convers. Mgmt. ,2008,49:373-380.
[25] Alkan C,Sari A. Fatty acid/ poly(methyl methacrylate)blends as form-stable phase change materials for latent heat storage[J]. Solar Energy ,2008,82(2):118-124.
[26] Wang L,Meng D. Fatty acid eutectic/polymethyl methacrylate composite as form-stable phase change material for thermal energy storage[J]. Applied Energy ,2010,87:2660-2665.
[27] Zhang Y,Ding J,Wang X, et al . Influence of additives on thermal conductivity of shape-stabilized phase change material[J]. Solar Energy Materials and Solar Cells ,2006,90(11):1692-1702.
[28] Sari A,Karaipekli A. Thermal conductivity and latent heat thermal energy storage characteristics of paraffin/expanded graphite composite as phase change material[J]. Applied Thermal Engineering ,2007,27:1271-1277.
[29] Cheng Wenlong,Zhang Rongming,Xie Kun. Heat conduction enhanced shape-stabilized paraffin/HDPE composite PCMs by graphite addition:Preparation and thermal properties[J]. Solar Energy Materials and Solar Cells ,2010,94:1636-1642.
[30] Mhike W,Focke W W,Mofokeng J P. Thermally conductive phase-change materials for energy storage based on low-density polyethylene,soft Fischer-Tropsch wax and graphite[J]. Thermochimica Acta ,2012,527:75-82.
[31] Ji P,Sun H,Zhong Y, et al . Improvement of the thermal conductivity of a phase change material by the functionalized carbon nanotubes[J]. Chemical Engineering Science ,2012,81:140-145.
[32] Teng T P,Cheng C M,Cheng C P. Performance assessment of heat storage by phase change materials containing MWCNTs and graphite[J]. Applied Thermal Engineering ,2012,50(1):637-644.
[33] Zeng J L,Zhu F R,Yu S B, et al . Effects of copper nanowires on the properties of an organic phase change material[J]. Solar Energy Materials and Solar Cells ,2012,105:174-178.
[34] Tang B,Qiu M,Zhang S. Thermal conductivity enhancement of PEG/SiO 2 composite PCM by in situ Cu doping[J]. Solar Energy Materials and Solar Cells ,2012,105:242-248.
[35] Cai Y,Hu Y,Song L, et al . Flammability and thermal properties of high density polyethylene/paraffin hybrid as a form-stable phase change material[J]. Journal of Applied Polymer Science ,2006,99(4):1320-1327.
[36] Cai Y,Hu Y,Song L, et al . Preparation and flammability of high density polyethylene/paraffin/organophilic montmorillonite hybrids as a form stable phase change material[J]. Energy Conversion and Management ,2007,48(2):462-469.
[37] Sittisart P,Farid M M. Fire retardants for phase change materials[J]. Applied Energy ,2011,88(9):3140-3145.
[38] Yan Q,Li L,Liang C. Thermal performance of shape-stabilized phase change paraffin wallboard[J]. Sustain Energy ,2010,29(4):185-190.
[39] Lin K,Zhang Y,Xu X, et al . Modeling and simulation of under-floor electric heating system with shape-stabilized PCM plates[J]. Building and Environment ,2004,39(12):1427-1434.
[40] Zhou G B,Zhang Y P,Wang X,Lin K P,Xiao W. An assessment of mixed type PCM-gypsum and shape-stabilized PCM plates in a building for passive solar heating[J]. Solar Energy ,2007,81:1351-1360.
[41] Zhou G B,Zhang Y P,Zhang Q L,Lin K P,Di H F. Performance of a hybrid heating system with thermal storage usingshape-stabilized phase-change material plates[J]. Applied Energy ,2007,84:1068-1077.
[42] Zhou G,Zhang Y,Lin K,Xiao W. Thermal analysis of a direct-gain room with shape-stabilized PCM plates[J]. Renew Energy ,2008,33:1228-1236.
[43] Zhou G B,Zhang Y P,Wang X,Zhou S X. Numerical analysis of effect of shape stabilized phase change material plates in a building combined with night ventilation[J]. Applied Energy ,2009,86(1):52-59.