层状金属二硫化物作为钠离子电池负极的研究进展

doi:10.19799/j.cnki.2095-4239.2022.0160

储能科学与技术 ›› 2022, Vol. 11 ›› Issue (10): 3062-3075.doi: 10.19799/j.cnki.2095-4239.2022.0160

层状金属二硫化物作为钠离子电池负极的研究进展

成伟翔¹(), 黄兴文¹, 李越珠¹, 胡俊祺¹, 廖松义²(), 闵永刚¹^,²^,³()

^1.广东工业大学材料与能源学院，广东广州 510006
^2.仲恺农业工程学院化学化工学院，广东广州 510225
^3.慧迈材料科技（广东）有限公司，广东佛山 528200

收稿日期:2022-03-28 修回日期:2022-04-27 出版日期:2022-10-05 发布日期:2022-10-10
通讯作者: 廖松义,闵永刚 E-mail:weixiangcheng2021@126.com;songyiliao@gdut.edu.cn;ygmin@gdut.edu.cn
作者简介:成伟翔（1996—），男，硕士研究生，主要从事锂离子及钠离子电极材料制备，E-mail： weixiangcheng2021@126.com；
基金资助:
广东省引进创新创业团队项目(501170009);国家重点研发计划项目(2020YFB0408100);广东省基础与应用基础研究项目(2021A1515111103);汕尾海上风电实验室科技项目(2021A2407S0010003);佛山市科技创新团队(1920001000108)

Advances in layered metal disulfide as anode material for Na-ion batteries

Weixiang CHENG¹(), Xingwen HUANG¹, Yuezhu LI¹, Junqi HU¹, Songyi LIAO²(), Yonggang MIN¹^,²^,³()

^1.School of Materials and Energy, Guangdong University of Technology, Guangzhou 510006, Guangdong, China
^2.College of Chemistry and Chemical Engineering, Zhongkai University of Agriculture and Engineering, Guangzhou 510225, Guangdong, China
^3.Huimai Material Technology(Guangdong)Co. , Ltd. , Foshan 528200, Fujian, China

Received:2022-03-28 Revised:2022-04-27 Online:2022-10-05 Published:2022-10-10
Contact: Songyi LIAO, Yonggang MIN E-mail:weixiangcheng2021@126.com;songyiliao@gdut.edu.cn;ygmin@gdut.edu.cn

摘要/Abstract

摘要：

钠离子电池（NIBs）因其资源丰富、环境友好等特点被认为是最有望替代锂离子电池（LIBs）的新一代储能系统。然而，钠离子半径大于锂离子，传统锂离子电池负极材料在充放电过程中钠离子嵌入/脱出困难，容易造成材料结构的坍塌。目前，缺乏合适的负极材料仍是限制NIBs大规模应用的主要障碍之一。与传统的NIBs负极材料（碳材料、金属氧化物、金属磷化物等）相比，层状金属二硫化物（TMDs）由于其独特的层状结构可“额外”储存钠离子，并有效地缓解电化学反应中的体积变化已被广泛研究。本文将首先将介绍三种常见关于TMDs材料的合成方法（水/溶剂热法，化学气相沉积法，液相剥离法）。接下来对几种作为NIBs负极的常用TMDs（MoS2、SnS2、WS2、VS2）的研究进展进行综述。最后将对不同TMDs材料合成方法的优缺点进行比较并进一步展望其目前所遇到的挑战及未来的发展前景，为进一步推动TMDs在NIBs的产业化应用提供一些理论参考和科学借鉴。

关键词: 层状金属二硫化物, 钠离子电池, 负极材料

Abstract:

Na-ion batteries (NIBs) are considered the most promising new-generation energy storage systems to replace Li-ion batteries (LIBs) because of their abundant resources and environmental friendliness. However, the radius of sodium ions is larger than that of lithium ions, and traditional Li-ion battery anode materials have difficulties in the insertion/extraction of sodium ions during the charging and discharging process, which easily leads to the collapse of the material structure. Currently, the lack of suitable anode materials is still one of the main obstacles limiting the large-scale application of NIBs. Compared with traditional NIBs anode materials (carbon materials, metal oxides, metal phosphides, etc.), layered metal dichalcogenides (TMDs) have been extensively studied due to their unique layered structures that "extra" store Na ions and effectively mitigate volume changes in electrochemical reactions. In this paper, three common synthesis methods for TMDs materials will firstly be introduced, namely water/solvothermal, chemical vapor deposition, liquid phase exfoliation method. Then, the research progress of several commonly used TMDs (MoS2, SnS2, WS2, VS2) as NIBs anodes is reviewed. Finally, the advantages and disadvantages of different TMDs material synthesis methods will be compared, and the current challenges and future development prospects will be further prospected, so as to provide some theoretical and scientific references for further promoting the industrial application of TMDs in NIBs.

Key words: layered metal disulfide (TMDs), Na-ion batteries (NIBs), anode materials

中图分类号:

TQ 152

成伟翔, 黄兴文, 李越珠, 胡俊祺, 廖松义, 闵永刚. 层状金属二硫化物作为钠离子电池负极的研究进展[J]. 储能科学与技术, 2022, 11(10): 3062-3075.

Weixiang CHENG, Xingwen HUANG, Yuezhu LI, Junqi HU, Songyi LIAO, Yonggang MIN. Advances in layered metal disulfide as anode material for Na-ion batteries[J]. Energy Storage Science and Technology, 2022, 11(10): 3062-3075.

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材料种类	材料名称	电化学性能
TMDs	MoS₂	56 mAh/g(20 A/g) 394 mAh/g(1 A/g循环350圈)^[24]
	SnS₂	343 mAh/g(5 A/g) 396 mAh/g(1 A/g循环500圈)^[55]
	WS₂	194 mAh/g(5 A/g) 182 mAh/g(5 A/g循环6000圈)^[56]
	VS₂	117 mAh/g(20 A/g) 176 mAh/g(10 A/g循环5000圈)^[57]
金属氧化物	MoO₃	127 mAh/g(5 A/g) 105 mAh/g(5 A/g循环1200圈)^[11]
	SnO₂	203 mAh/g(0.15 A/g) 488 mAh/g(0.02 A/g循环70圈)^[12]
	WO₃	204.6 mAh/g(5 A/g) 306.5 mAh/g(2 A/g循环3000圈)^[13]
金属磷化物	MoP	133 mAh/g(4.1 A/g) 307 mAh/g(0.06 A/g循环100圈)^[14]
	Sn₄P₃	853 mAh/g(0.1 A/g) 718 mAh/g(0.1 A/g循环100圈)^[15]
	V₄P₇	90 mAh/g(0.8 A/g) 122 mAh/g(0.2 A/g循环500圈)^[16]
	WP	56 mAh/g(2 A/g) 50 mAh/g(2 A/g循环1000圈)^[17]

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层状金属二硫化物作为钠离子电池负极的研究进展

Advances in layered metal disulfide as anode material for Na-ion batteries

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