致密储能：基于石墨烯的方法学和应用实例

doi:10.19799/j.cnki.2095-4239.2022.0174

储能科学与技术 ›› 2022, Vol. 11 ›› Issue (6): 1865-1873.doi: 10.19799/j.cnki.2095-4239.2022.0174

致密储能：基于石墨烯的方法学和应用实例

韩俊伟¹^,²^,⁶(), 肖菁¹^,³^,⁶, 陶莹¹^,³, 孔德斌⁴^,⁶, 吕伟², 杨全红¹^,³^,⁵^,⁶()

^1.天津大学化工学院，天津 300072
^2.清华大学深圳国际研究生院，广东深圳 518055
^3.物质绿色创造与制造海河实验室，天津 300192
^4.中国石油大学（华东）新能源学院，山东青岛 266580
^5.天津大学-新加坡国立大学福州联合学院，福建福州 350207
^6.天目湖先进储能技术研究院，江苏溧阳 213300

收稿日期:2022-03-30 修回日期:2022-04-27 出版日期:2022-06-05 发布日期:2022-06-13
通讯作者: 杨全红 E-mail:hardway@tju.edu.cn;qhyangcn@tju.edu.cn
作者简介:韩俊伟（1990—），男，博士，主要研究方向为碳基储能材料，E-mail：hardway@tju.edu.cn；
基金资助:
国家自然科学基金项目(51872195);国家重点研发计划项目(2021YFF0500600)

Compact energy storage： Methodology with graphenes and the applications

HAN Junwei¹^,²^,⁶(), XIAO Jing¹^,³^,⁶, TAO Ying¹^,³, KONG Debin⁴^,⁶, LV Wei², YANG Quanhong¹^,³^,⁵^,⁶()

^1.School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China
^2.Tsinghua Shenzhen International Graduate School, Tsinghua University, Shenzhen 518055, Guangdong, China
^3.Haihe Laboratory of Sustainable Chemical Transformations, Tianjin 300192, China
^4.College of New Energy, China University of Petroleum (East China), Qingdao 266580, Shandong, China
^5.Joint School of National University of Singapore and Tianjin University, International Campus of Tianjin University, Binhai New City, Fuzhou 350207, Fujian, China
^6.Tianmu Lake Institute of Advanced Energy Storage Technologies, Liyang 213300, Jiangsu, China

Received:2022-03-30 Revised:2022-04-27 Online:2022-06-05 Published:2022-06-13
Contact: YANG Quanhong E-mail:hardway@tju.edu.cn;qhyangcn@tju.edu.cn

摘要/Abstract

摘要：

“致密储能”，即在尽可能小的体积内存储尽可能多的能量，是解决储能器件“空间焦虑”的必由之路。以石墨烯为基元组装获得的碳材料用作电极关键材料，可促进电化学反应并在优化电极和电池体积性能方面扮演着重要的角色。本文首先总结了二次电池致密储能的重要性及其关键挑战，立足石墨烯致密自组装及其在高体积比容量超级电容器电极中的应用，提出了基于石墨烯的致密储能方法论；基于此着重梳理了高体积性能二次电池，特别是致密型锂离子电池电极中“收放自如”碳网络构建的研究进展，最后展望了实用工况下致密储能体系循环稳定性、快充、热安全等方面问题的应对思路。

关键词: 致密储能, 锂离子电池, 体积能量密度, 碳材料, 石墨烯

Abstract:

The only way to address the emerging "space anxiety" in rapidly developing energy storage devices is through "compact energy storage," or storing as much energy as possible in the smallest possible space. Carbon materials assembled from graphene basic units can be used as key components in electrodes to promote electrochemical reactions and play an important role in optimizing electrode and battery volumetric performance. This review summarizes the significance of compact energy storage in rechargeable batteries as well as the major challenges. We propose a compact energy storage methodology based on the dense self-assembly process of graphenes, as well as its application in high-volumetric-capacitor electrodes, and then extend it to build compact high-energy rechargeable batteries, particularly lithium-ion batteries. To achieve compact energy storage from materials to electrodes and devices, the strategy of densifying the electrodes using customized carbon structures is highlighted. For future development, special concerns about cycling stability, fast charging, and thermal safety under practical working conditions in compact batteries are discussed.

Key words: compact energy storage, lithium-ion batteries, volumetric energy density, carbon, graphene

中图分类号:

TQ 152

韩俊伟, 肖菁, 陶莹, 孔德斌, 吕伟, 杨全红. 致密储能：基于石墨烯的方法学和应用实例[J]. 储能科学与技术, 2022, 11(6): 1865-1873.

HAN Junwei, XIAO Jing, TAO Ying, KONG Debin, LV Wei, YANG Quanhong. Compact energy storage： Methodology with graphenes and the applications[J]. Energy Storage Science and Technology, 2022, 11(6): 1865-1873.

图/表 4

图1

图2

图3

图4

参考文献 41

1	CHOI J W, AURBACH D. Promise and reality of post-lithium-ion batteries with high energy densities[J]. Nature Reviews Materials, 2016, 1: 16013.
2	李文俊, 徐航宇, 杨琪, 等. 高能量密度锂电池开发策略[J]. 储能科学与技术, 2020, 9(2): 448-478.
	LI W J, XU H Y, YANG Q, et al. Development of strategies for high-energy-density lithium batteries[J]. Energy Storage Science and Technology, 2020, 9(2): 448-478.
3	ZHANG C, LV W, TAO Y, et al. Towards superior volumetric performance: Design and preparation of novel carbon materials for energy storage[J]. Energy & Environmental Science, 2015, 8(5): 1390-1403.
4	HAN J W, LI H, YANG Q H. Compact energy storage enabled by graphenes: Challenges, strategies and progress[J]. Materials Today, 2021, 51: 552-565.
5	LUO F, LIU B N, ZHENG J Y, et al. Review—nano-silicon/carbon composite anode materials towards practical application for next generation Li-ion batteries[J]. Journal of the Electrochemical Society, 2015, 162(14): A2509-A2528.
6	张辰, 刘东海, 吕伟, 等. 高体积能量密度锂硫电池的构建: 材料和电极[J]. 储能科学与技术, 2017, 6(3): 550-556.
	ZHANG C, LIU D H, LV W, et al. Construction of Li-S battery with high volumetric performance: Materials and electrode[J]. Energy Storage Science and Technology, 2017, 6(3): 550-556.
7	陶莹, 李欢, 杨全红. 致密储能—石墨烯用于超级电容器的机遇和展望[J]. 储能科学与技术, 2016, 5(6): 781-787.
	TAO Y, LI H, YANG Q H. Compact energy storage: Opportunities and challenges of graphene for supercapacitors[J]. Energy Storage Science and Technology, 2016, 5(6): 781-787.
8	NITTA N, WU F X, LEE J T, et al. Li-ion battery materials: Present and future[J]. Materials Today, 2015, 18(5): 252-264.
9	SUN Y M, LIU N, CUI Y. Promises and challenges of nanomaterials for lithium-based rechargeable batteries[J]. Nature Energy, 2016, 1: 16071.
10	WANG J Y, LIAO L, LI Y Z, et al. Shell-protective secondary silicon nanostructures as pressure-resistant high-volumetric-capacity anodes for lithium-ion batteries[J]. Nano Letters, 2018, 18(11): 7060-7065.
11	HAN J W, KONG D B, LV W, et al. Caging tin oxide in three-dimensional graphene networks for superior volumetric lithium storage[J]. Nature Communications, 2018, 9: 402.
12	XUE W J, SHI Z, SUO L M, et al. Intercalation-conversion hybrid cathodes enabling Li-S full-cell architectures with jointly superior gravimetric and volumetric energy densities[J]. Nature Energy, 2019, 4(5): 374-382.
13	WANG J Y, CUI Y. Electrolytes for microsized silicon[J]. Nature Energy, 2020, 5(5): 361-362.
14	PARK S H, KING P J, TIAN R Y, et al. High areal capacity battery electrodes enabled by segregated nanotube networks[J]. Nature Energy, 2019, 4(7): 560-567.
15	HAN J W, LI H, KONG D B, et al. Realizing high volumetric lithium storage by compact and mechanically stable anode designs[J]. ACS Energy Letters, 2020, 5(6): 1986-1995.
16	LV W, LI Z J, DENG Y Q, et al. Graphene-based materials for electrochemical energy storage devices: Opportunities and challenges[J]. Energy Storage Materials, 2016, 2: 107-138.
17	TAO Y, XIE X Y, LV W, et al. Towards ultrahigh volumetric capacitance: Graphene derived highly dense but porous carbons for supercapacitors[J]. Scientific Reports, 2013, 3: 2975.
18	QI C S, LUO C, TAO Y, et al. Capillary shrinkage of graphene oxide hydrogels[J]. Science China Materials, 2020, 63(10): 1870-1877.
19	XU Y, TAO Y, ZHENG X Y, et al. A metal-free supercapacitor electrode material with a record high volumetric capacitance over 800 F·cm^-3[J]. Advanced Materials, 2015, 27(48): 8082-8087.
20	LI H, TAO Y, ZHENG X Y, et al. Ultra-thick graphene bulk supercapacitor electrodes for compact energy storage[J]. Energy & Environmental Science, 2016, 9(10): 3135-3142.
21	HONG L. A high capacity nano-Si composite anode material for lithium rechargeable batteries[J]. Electrochemical and Solid-State Letters, 1999, 2(11): 547.
22	周军华, 罗飞, 褚赓, 等. 锂离子电池纳米硅碳负极材料研究进展[J]. 储能科学与技术, 2020, 9(2): 569-582.
	ZHOU J H, LUO F, CHU G, et al. Research progress on nano silicon-carbon anode materials for lithium ion battery[J]. Energy Storage Science and Technology, 2020, 9(2): 569-582.
23	XU Q, LI J Y, SUN J K, et al. Watermelon-inspired Si/C microspheres with hierarchical buffer structures for densely compacted lithium-ion battery anodes[J]. Advanced Energy Materials, 2017, 7(3): doi: 10.1002/aenm.201601481.
24	LI Y Z, YAN K, LEE H W, et al. Growth of conformal graphene cages on micrometre-sized silicon particles as stable battery anodes[J]. Nature Energy, 2016, 1: 15029.
25	周琳, 杨佯, 胡勇胜. 合金电极失效机制:体积膨胀?电解液分解?[J]. 储能科学与技术, 2021, 10(3): 813-820.
	ZHOU L, YANG Y, HU Y S. Failure mechanism of alloy electrodes: Volume change? decomposition of electrolyte?[J]. Energy Storage Science and Technology, 2021, 10(3): 813-820.
26	CHEN F Q, HAN J W, KONG D B, et al. 1000 Wh·L^-1 lithium-ion batteries enabled by crosslink-shrunk tough carbon encapsulated silicon microparticle anodes[J]. National Science Review, 2021, 8(9): doi: 10.1093/nsr/nwab012.
27	HAN J W, ZHANG C, KONG D B, et al. Flowable sulfur template induced fully interconnected pore structures in graphene artefacts towards high volumetric potassium storage[J]. Nano Energy, 2020, 72: doi: 10.1016/j.nanoen.2020.104729.
28	MA H Y, GENG H Y, YAO B W, et al. Highly ordered graphene solid: An efficient platform for capacitive sodium-ion storage with ultrahigh volumetric capacity and superior rate capability[J]. ACS Nano, 2019, 13(8): 9161-9170.
29	LIU Y T, LIU S, LI G R, et al. Strategy of enhancing the volumetric energy density for lithium-sulfur batteries[J]. Advanced Materials, 2021, 33(8): doi: 10.1002/adma.202003955.
30	ZHANG C, LIU D H, LV W, et al. A high-density graphene-sulfur assembly: A promising cathode for compact Li-S batteries[J]. Nanoscale, 2015, 7(13): 5592-5597.
31	LI H, TAO Y, ZHANG C, et al. Dense graphene monolith for high volumetric energy density Li-S batteries[J]. Advanced Energy Materials, 2018, 8(18): doi: 10.1002/aenm.201703438.
32	PAN H L, CHEN J Z, CAO R G, et al. Non-encapsulation approach for high-performance Li-S batteries through controlled nucleation and growth[J]. Nature Energy, 2017, 2(10): 813-820.
33	LIAO Y Q, YUAN L X, XIANG J W, et al. Realizing both high gravimetric and volumetric capacities in Li/3D carbon composite anode[J]. Nano Energy, 2020, 69: doi: 10.1016/j.nanoen.2020.104471.
34	CHEN Y M, WANG Z Q, LI X Y, et al. Li metal deposition and stripping in a solid-state battery via Coble creep[J]. Nature, 2020, 578(7794): 251-255.
35	BOLES S T, TAHMASEBI M H. Are foils the future of anodes?[J]. Joule, 2020, 4(7): 1342-1346.
36	HELIGMAN B T, KREDER K J III, MANTHIRAM A. Zn-Sn interdigitated eutectic alloy anodes with high volumetric capacity for lithium-ion batteries[J]. Joule, 2019, 3(4): 1051-1063.
37	ZHOU T H, LYU W, LI J, et al. Twinborn TiO₂-TiN heterostructures enabling smooth trapping-diffusion-conversion of polysulfides towards ultralong life lithium-sulfur batteries[J]. Energy & Environmental Science, 2017, 10 (7): 1694-1703.
38	GRIFFITH K J, WIADEREK K M, CIBIN G, et al. Niobium tungsten oxides for high-rate lithium-ion energy storage[J]. Nature, 2018, 559(7715): 556-563.
39	NIU C J, LEE H, CHEN S R, et al. High-energy lithium metal pouch cells with limited anode swelling and long stable cycles[J]. Nature Energy, 2019, 4(7): 551-559.
40	ZHU Z, YU D W, SHI Z, et al. Gradient-morph LiCoO₂ single crystals with stabilized energy density above 3400 Wh·L^-1[J]. Energy & Environmental Science, 2020, 13(6): 1865-1878.
41	ZHANG J N, LI Q H, OUYANG C Y, et al. Trace doping of multiple elements enables stable battery cycling of LiCoO₂ at 4.6 V[J]. Nature Energy, 2019, 4(7): 594-603.

[1]	李海涛, 孔令丽, 张欣, 余传军, 王纪威, 徐琳. N/P设计对高镍NCM/Gr电芯性能的影响[J]. 储能科学与技术, 2022, 11(7): 2040-2045.
[2]	姚祯, 张琦, 王锐, 刘庆华, 王保国, 缪平. 生物质衍生碳材料在全钒液流电池电极方面的应用[J]. 储能科学与技术, 2022, 11(7): 2083-2091.
[3]	刘显茜, 孙安梁, 田川. 基于仿生翅脉流道冷板的锂离子电池组液冷散热[J]. 储能科学与技术, 2022, 11(7): 2266-2273.
[4]	陈龙, 夏权, 任羿, 曹高萍, 邱景义, 张浩. 多物理场耦合下锂离子电池组可靠性研究现状与展望[J]. 储能科学与技术, 2022, 11(7): 2316-2323.
[5]	易顺民, 谢林柏, 彭力. 基于VF-DW-DFN的锂离子电池剩余寿命预测[J]. 储能科学与技术, 2022, 11(7): 2305-2315.
[6]	祝庆伟, 俞小莉, 吴启超, 徐一丹, 陈芬放, 黄瑞. 高能量密度锂离子电池老化半经验模型[J]. 储能科学与技术, 2022, 11(7): 2324-2331.
[7]	王宇作, 王瑨, 卢颖莉, 阮殿波. 孔结构对软碳负极储锂性能的影响[J]. 储能科学与技术, 2022, 11(7): 2023-2029.
[8]	孔为, 金劲涛, 陆西坡, 孙洋. 对称蛇形流道锂离子电池冷却性能[J]. 储能科学与技术, 2022, 11(7): 2258-2265.
[9]	霍思达, 薛文东, 李新丽, 李勇. 基于CiteSpace知识图谱的锂电池复合电解质可视化分析[J]. 储能科学与技术, 2022, 11(7): 2103-2113.
[10]	邓健想, 赵金良, 黄成德. 高能量锂离子电池硅基负极黏结剂研究进展[J]. 储能科学与技术, 2022, 11(7): 2092-2102.
[11]	欧宇, 侯文会, 刘凯. 锂离子电池中的智能安全电解液研究进展[J]. 储能科学与技术, 2022, 11(6): 1772-1787.
[12]	辛耀达, 李娜, 杨乐, 宋维力, 孙磊, 陈浩森, 方岱宁. 锂离子电池植入传感技术[J]. 储能科学与技术, 2022, 11(6): 1834-1846.
[13]	燕乔一, 吴锋, 陈人杰, 李丽. 锂离子电池负极石墨回收处理及资源循环[J]. 储能科学与技术, 2022, 11(6): 1760-1771.
[14]	沈秀, 曾月劲, 李睿洋, 李佳霖, 李伟, 张鹏, 赵金保. γ射线辐照交联原位固态化阻燃锂离子电池[J]. 储能科学与技术, 2022, 11(6): 1816-1821.
[15]	于春辉, 何姿颖, 张晨曦, 林贤清, 肖哲熙, 魏飞. 硅基负极与电解液化学反应的分析与抑制策略[J]. 储能科学与技术, 2022, 11(6): 1749-1759.

致密储能：基于石墨烯的方法学和应用实例

Compact energy storage： Methodology with graphenes and the applications

RichHTML

PDF

可视化

摘要/Abstract

引用本文

使用本文

图/表 4

参考文献 41

相关文章 15

编辑推荐

Metrics

本文评价