锂离子电池阳极危害性析锂原位检测综述

doi:10.19799/j.cnki.2095-4239.2025.0241

储能科学与技术 ›› 2025, Vol. 14 ›› Issue (7): 2575-2589.doi: 10.19799/j.cnki.2095-4239.2025.0241

• 第十三届储能国际峰会暨展览会专辑 • 上一篇下一篇

锂离子电池阳极危害性析锂原位检测综述

翁雯媛¹(), 沈斌²(), 朱建功¹(), 汪洋², 路华鹏², 何乌利雅苏², 刘浩男¹, 戴海峰¹, 魏学哲¹

^1.同济大学汽车学院，上海 201804
^2.沃尔沃汽车技术(上海)有限公司，上海 201804

收稿日期:2025-03-14 修回日期:2025-04-06 出版日期:2025-07-28 发布日期:2025-07-11
通讯作者: 沈斌,朱建功 E-mail:2332933@tongji.edu.cn;bin.shen@volvocars.com;zhujiangong@tongji.edu.cn
作者简介:翁雯媛（2000—），女，硕士研究生，研究锂离子电池健康管理领域，E-mail：2332933@tongji.edu.cn；
基金资助:
国家自然科学基金(52377211);沃尔沃汽车技术（上海）有限公司危害性析锂测试和研究资助项目

Detecting hazardous lithium plating on anodes of lithium-ion batteries—A review of in situ methods

Wenyuan WENG¹(), Bin SHEN²(), Jiangong ZHU¹(), Yang WANG², Huapeng LU², Wuliyasu HE², Haonan LIU¹, Haifeng DAI¹, Xuezhe WEI¹

^1.School of Mechanical Engineering, Tongji University, Shanghai 201804, China
^2.Volvo Car Technology (Shanghai) Co. , Ltd. , Shanghai 201804, China

Received:2025-03-14 Revised:2025-04-06 Online:2025-07-28 Published:2025-07-11
Contact: Bin SHEN, Jiangong ZHU E-mail:2332933@tongji.edu.cn;bin.shen@volvocars.com;zhujiangong@tongji.edu.cn

摘要/Abstract

摘要：

锂离子电池在实现碳中和目标中发挥了重要作用，广泛应用于电动汽车、便携式电子设备和储能系统等领域，然而，析锂现象引发的安全与性能问题也日益凸显。本文系统分析了锂离子电池析锂的形成机理及影响因素，指出电池设计缺陷和极端工况(低温环境、快充和过充)等因素耦合作用下易导致阳极对锂电位低于0V，从而诱发锂离子电池阳极析锂。沉积锂的可逆性变差会导致SEI膜增厚、死锂堆积及锂枝晶生长，造成能量密度降低和容量加速衰减，甚至引发安全问题。针对析锂检测难题，本文从原位检测视角对现有技术进行分类介绍，定量检测方法涵盖差分电压分析、核磁共振波谱等电化学与物理表征技术；定性检测方法包括电化学阻抗谱、厚度和压力检测等。相较于需拆解电池的非原位检测，这些方法为在线、原位检测提供了新思路。本文创新性地从热安全与性能安全两个维度构建析锂安全评估体系，为开发长寿命高安全电池奠定基础。最后展望了多技术融合检测、智能预警系统等未来研究方向，为突破析锂原位检测技术瓶颈提供科学指导。

关键词: 锂离子电池, 析锂, 原位检测, 电池安全, 热失控

Abstract:

Lithium-ion batteries play a pivotal role in achieving carbon neutrality goals through their widespread applications in electric vehicles, portable electronics, and energy storage systems. However, lithium plating—a critical process that occurs at the anode during charging—poses a significant challenge, compromising both safety and performance. This study systematically investigates the formation mechanisms and influencing factors of lithium plating, revealing that the synergistic effects of battery design flaws and extreme operating conditions (such as a low-temperature environment, fast charging, and overcharging) can drive the anode potential below 0 V vs. $L i / L i +$ , triggering the deposition of metallic lithium. The irreversibility of lithium deposition leads to three critical consequences: continuous thickening of the solid electrolyte interphase (SEI) layer, accumulation of “dead lithium”, and dendritic lithium growth. These effects collectively contribute to capacity degradation and thermal runaway risks.To address the challenges in detecting lithium deposition, this study provides a comprehensive classification and critical review of existing technologies from the perspective of in situ detection. Quantitative detection methodologies include electrochemical characterization techniques (e.g., differential voltage analysis, differential voltage relaxation analysis, incremental and capacity analysis and physical characterization approaches (e.g., nuclear magnetic resonance spectroscopy and X-ray technology). Qualitative detection strategies involve electrochemical impedance spectroscopy (EIS) and thickness or pressure monitoring systems. Compared to postmortem analysis requiring battery disassembly, these advanced methods offer novel insights for real-time monitoring applications.This study establishes an innovative dual-dimensional safety assessment framework encompassing thermal safety and performance safety, with the former focusing on heat generation characteristics and thermal stability thresholds during lithium plating and the latter on quantifying capacity fade rates and impedance growth patterns. This systematic approach provides a theoretical foundation for developing high-safety, long-cycle-life batteries.Finally, to address the shortcomings in current in situ lithium plating detection, the following recommendations are made: ① establishing a systematic definition of battery safety standards and correlating lithium plating detection with thermal and performance safety; ② combining electrochemical detection with big data to extract and fuse useful features for online safety diagnosis; ③ developing innovative in situ quantitative methods for visual monitoring and quantifying complex internal reactions, and ④ providing scientific guidance to overcome the bottlenecks in in situ lithium plating detection technology.

Key words: lithium-ion battery, lithium plating, in-situ detection, battery safety, thermal runaway

中图分类号:

TH 842

翁雯媛, 沈斌, 朱建功, 汪洋, 路华鹏, 何乌利雅苏, 刘浩男, 戴海峰, 魏学哲. 锂离子电池阳极危害性析锂原位检测综述[J]. 储能科学与技术, 2025, 14(7): 2575-2589.

Wenyuan WENG, Bin SHEN, Jiangong ZHU, Yang WANG, Huapeng LU, Wuliyasu HE, Haonan LIU, Haifeng DAI, Xuezhe WEI. Detecting hazardous lithium plating on anodes of lithium-ion batteries—A review of in situ methods[J]. Energy Storage Science and Technology, 2025, 14(7): 2575-2589.

图/表 7

图1

图2

图3

图4

图5

图6

图7

参考文献 77

[1]	LIU K L, WEI Z B, ZHANG C H, et al. Towards long lifetime battery: AI-based manufacturing and management[J]. IEEE/CAA Journal of Automatica Sinica, 2022, 9(7): 1139-1165.
[2]	LIU Q Q, DU C Y, SHEN B, et al. Understanding undesirable anode lithium plating issues in lithium-ion batteries[J]. RSC Advances, 2016, 6(91): 88683-88700. DOI: 10.1039/C6RA19482F.
[3]	YANG X G, GE S, LIU T, et al. A look into the voltage plateau signal for detection and quantification of lithium plating in lithium-ion cells [J]. Electrochemical Energy Storage, 2018, 395: 251-61.
[4]	WHITEHEAD A H, PERKINS M, OWEN J R. A graphical aid to evaluation of carbon-based Li-ion electrodes [J]. Journal of the Electrochemical Society, 1997, 144(4): L92-L94. DOI:10.1149/1. 1837564.
[5]	VERBRUGGE M W, KOCH B J. The effect of large negative potentials and overcharge on the electrochemical performance of lithiated carbon[J]. Journal of Electroanalytical Chemistry, 1997, 436(1/2): 1-7. DOI: 10.1016/S0022-0728(97)00031-4.
[6]	JEON Y, KANG S J, JOO S H, et al. Pyridinic-to-graphitic conformational change of nitrogen in graphitic carbon nitride by lithium coordination during lithium plating[J]. Energy Storage Materials, 2020, 31: 505-514. DOI: 10.1016/j.ensm.2020.06.041.
[7]	CHEN K H, WOOD K N, KAZYAK E, et al. Dead lithium: Mass transport effects on voltage, capacity, and failure of lithium metal anodes[J]. Journal of Materials Chemistry A, 2017, 5(23): 11671-11681. DOI: 10.1039/C7TA00371D.
[8]	JIANG Y, WANG Z X, XU C X, et al. Atomic layer deposition for improved lithiophilicity and solid electrolyte interface stability during lithium plating[J]. Energy Storage Materials, 2020, 28: 17-26. DOI: 10.1016/j.ensm.2020.01.019.
[9]	YANG T Z, SUN Y W, QIAN T, et al. Lithium dendrite inhibition via 3D porous lithium metal anode accompanied by inherent SEI layer[J]. Energy Storage Materials, 2020, 26: 385-390. DOI: 10. 1016/j.ensm.2019.11.009.
[10]	CHEN R, MIAO S, JIA Y, et al. A review of detecting Li plating on graphite anodes based on electrochemical methods[J]. Journal of Materials Chemistry A, 2024, 12(48): DOI:10.1039/D4TA05871B.
[11]	LIU S, XIONG L, HE C. Long cycle life lithium ion battery with lithium nickel cobalt manganese oxide (NCM) cathode[J]. Journal of Power Sources, 2014, 261: 285-291.DOI:10.1016/j.jpowsour. 2014.03.083.
[12]	邓林旺, 冯天宇, 舒时伟,等. 锂离子电池无损析锂检测研究进展[J]. 储能科学与技术, 2023, 12(1): 263-277. DOI: 10.19799/j.cnki. 2095-4239.2022.0428.
	DENG L W, FENG T Y, SHU S W, et al. Nondestructive lithium plating online detection for lithium-ion batteries: A review[J]. Energy Storage Science and Technology, 2023, 12(1): 263-277. DOI: 10.19799/j.cnki.2095-4239.2022.0428.
[13]	王羽, 周星, 王睿茜, 等. 面向BMS应用的锂离子电池析锂诊断方法综述[J]. 中国电机工程学报, 2024, 44(21): 8444-8462. DOI: 10. 13334/j.0258-8013.pcsee.230872.
	WANG Y, ZHOU X, WANG R X, et al. Lithium plating detection methods in Li-ion batteries for battery management system application: A review[J]. Proceedings of the CSEE, 2024, 44(21): 8444-8462. DOI: 10.13334/j.0258-8013.pcsee.230872.
[14]	陈佳慧, 王飞, 危荃, 等. 锂电池安全性能无损检测技术研究进展[J]. 无损检测, 2022, 44(12): 72-75.
	CHEN J H, WANG F, WEI Q, et al. Research progress on nondestructive testing technology of lithium battery safety performance[J]. Nondestructive Testing, 2022, 44(12): 72-75.
[15]	LIU X M, ARNOLD C B. Effects of current density on defect-induced capacity fade through localized plating in lithium-ion batteries[J]. Journal of the Electrochemical Society, 2020, 167(13): 130519. DOI: 10.1149/1945-7111/abb838.
[16]	ZHAO X C, YIN Y L, HU Y, et al. Electrochemical-thermal modeling of lithium plating/stripping of Li(Ni_0.6Mn_0.2Co_0.2)O₂/carbon lithium-ion batteries at subzero ambient temperatures[J]. Journal of Power Sources, 2019, 418: 61-73. DOI: 10.1016/j.jpowsour. 2019.02.001.
[17]	REN D S, SMITH K, GUO D X, et al. Investigation of lithium plating-stripping process in Li-ion batteries at low temperature using an electrochemical model[J]. Journal of the Electrochemical Society, 2018, 165(10): A2167-A2178. DOI: 10.1149/2.0661810jes.
[18]	YANG X, ZHANG G, GE S, et al. Fast charging of lithium-ion batteries at all temperatures[J]. Proceedings of the National Academy of Sciences of the United States of America, 2018, 115: DOI:10.1073/pnas.1807115115.
[19]	WALDMANN T, HOGG B I, WOHLFAHRT MEHRENS M. Li plating as unwanted side reaction in commercial Li-ion cells—A review [J]. Journal of Power Sources, 2018, 384: 107-124. DOI:10.1016/j.jpowsour.2018.02.063.
[20]	TANIM T R, DUFEK E J, DICKERSON C C, et al. Electrochemical quantification of lithium plating: Challenges and considerations[J]. Journal of the Electrochemical Society, 2019, 166(12): A2689-A2696. DOI: 10.1149/2.1581912jes.
[21]	RANGARAJAN S P, BARSUKOV Y, P P M. In operando signature and quantification of lithium plating[J]. Journal of Materials Chemistry A, 2019, 7(36): 20683-20695.DOI:10.1039/C9TA07314K.
[22]	ZHANG L, ZHANG Z C, REDFERN P C, et al. Molecular engineering towards safer lithium-ion batteries: A highly stable and compatible redox shuttle for overcharge protection[J]. Energy & Environmental Science, 2012, 5(8): 8204-8207. DOI: 10.1039/C2EE21977H.
[23]	JUAREZ-ROBLES D, VYAS A A, FEAR C, et al. Overcharge and aging analytics of Li-ion cells[J]. Journal of the Electrochemical Society, 2020, 167(9): 090547. DOI: 10.1149/1945-7111/ab9569.
[24]	COSBY M R, CARIGNAN G M, LI Z, et al. operando synchrotron studies of inhomogeneity during anode-free plating of Li metal in pouch cell batteries[J]. Journal of the Electrochemical Society, 2022, 169(2): 020571. DOI: 10.1149/1945-7111/ac5345.
[25]	BLOOM I D, JANSEN A N, ABRAHAM D P, et al. Differential voltage analyses of high-power, lithium-ion cells: 1. Technique and application [J]. Journal of Power Sources, 2005, 139(1/2): 295-303. DOI:10.1016/j.jpowsour.2004.07.022.
[26]	PETZL M, DANZER M A. Nondestructive detection, characterization, and quantification of lithium plating in commercial lithium-ion batteries [J]. Journal of Power Sources, 2014, 254(15): 80-87.DOI:10.1016/j.jpowsour.2013.12.060.
[27]	O'KANE S E J, CAMPBELL I D, MARZOOK M W J, et al. Physical origin of the differential voltage minimum associated with lithium plating in Li-ion batteries[J]. Journal of the Electrochemical Society, 2020, 167(9): 090540. DOI: 10.1149/1945-7111/ab90ac.
[28]	CAMPBELL I D, MARZOOK M, MARINESCU M, et al. How observable is lithium plating? Differential voltage analysis to identify and quantify lithium plating following fast charging of cold lithium-ion batteries[J]. Journal of the Electrochemical Society, 2019, 166(4): A725-A739. DOI: 10.1149/2.0821904jes.
[29]	UHLMANN C, ILLIG J, ENDER M, et al. In situ detection of lithium metal plating on graphite in experimental cells[J]. Journal of Power Sources, 2015, 279: 428-438. DOI: 10.1016/j.jpowsour. 2015.01.046.
[30]	KATZER F, JAHN L, HAHN M, et al. Model-based lithium deposition detection method using differential voltage analysis[J]. Journal of Power Sources, 2021, 512: DOI: 10.1016/j.jpowsour. 2021.230449.
[31]	SCHINDLER S, BAUER M, PETZL M, et al. Voltage relaxation and impedance spectroscopy as In-operando methods for the detection of lithium plating on graphitic anodes in commercial lithium-ion cells[J]. Journal of Power Sources, 2016, 304: 170-180. DOI: 10.1016/j.jpowsour.2015.11.044.
[32]	KOLETI U R, DINH T Q, MARCO J. A new on-line method for lithium plating detection in lithium-ion batteries [J]. Journal of Power Sources, 2020, 451: DOI:10.1016/j.jpowsour.2020.227798.
[33]	JANAKIRAMAN U, GARRICK T R, FORTIER M E. Review-lithium plating detection methods in Li-ion batteries[J]. Journal of The Electrochemical Society, 2020, 167(16): DOI:10.1149/1945-7111/abd3b8.
[34]	ANSEÁN D, DUBARRY M, DEVIE A, et al. operando lithium plating quantification and early detection of a commercial LiFePO₄ cell cycled under dynamic driving schedule[J]. Journal of Power Sources, 2017, 356: 36-46. DOI: 10.1016/j.jpowsour. 2017.04.072.
[35]	YOU H Z, JIANG B, ZHU J G, et al. In-situ quantitative detection of irreversible lithium plating within full-lifespan of lithium-ion batteries[J]. Journal of Power Sources, 2023, 564: 232892. DOI: 10.1016/j.jpowsour.2023.232892.
[36]	HE J T, BIAN X L, LIU L C, et al. Comparative study of curve determination methods for incremental capacity analysis and state of health estimation of lithium-ion battery[J]. Journal of Energy Storage, 2020, 29: 101400. DOI: 10.1016/j.est.2020. 101400.
[37]	BLANC F, LESKES M, GREY C P. In situ solid-state NMR spectroscopy of electrochemical cells: Batteries, supercapacitors, and fuel cells[J]. Accounts of Chemical Research, 2013, 46(9):1952-63.DOI:10.1021/ar400022u.
[38]	XIE P, PENG Y M, LIU X B, et al. Electronegative graphene film based interface-chemistry regulation for stable lithium metal batteries[J]. Chemical Engineering Journal, 2023, 478: 147304. DOI: 10.1016/j.cej.2023.147304.
[39]	ARAI J, OKADA Y, SUGIYAMA T, et al. In situ solid state ⁷Li NMR observation of lithium metal deposition during overcharge in lithium ion battery[J]. Journal of the Electrochemical Society, 2014, 62(1): 159-187.
[40]	HSIEH Y C, LEIßING M, NOWAK S, et al. Quantification of dead lithium via in situ nuclear magnetic resonance spectroscopy[J]. Cell Reports Physical Science, 2020, 1(8): 100139. DOI: 10.1016/j.xcrp.2020.100139.
[41]	KITADA K, PECHER O, MAGUSIN P C M M, et al. Unraveling the reaction mechanisms of SiO anodes for Li-ion batteries by combining in situ ⁷Li and ex situ ⁷Li/²⁹Si solid-state NMR spectroscopy[J]. Journal of the American Chemical Society, 2019, 141(17): 7014-7027. DOI: 10.1021/jacs.9b01589.
[42]	HOPE M A, RINKEL B L D, GUNNARSDÓTTIR A B, et al. Selective NMR observation of the SEI-metal interface by dynamic nuclear polarisation from lithium metal[J]. Nature Communications, 2020, 11: 2224. DOI: 10.1038/s41467-020-16114-x.
[43]	GEISE N R, KASSE R M, WEKER J N, et al. Quantification of efficiency in lithium metal negative electrodes via operando X-ray diffraction[J]. Chemistry of Materials: A Publication of the American Chemistry Society, 2021, 33(18): 7537-7545.
[44]	PAUL P P, THAMPY V, CAO C T, et al. Quantification of heterogeneous, irreversible lithium plating in extreme fast charging of lithium-ion batteries[J]. Energy & Environmental Science, 2021, 14(9): 4979-4988. DOI: 10.1039/D1EE01216A.
[45]	SADD M, XIONG S Z, BOWEN J R, et al. Investigating microstructure evolution of lithium metal during plating and stripping via operando X-ray tomographic microscopy[J]. Nature Communications, 2023, 14: 854. DOI: 10.1038/s41467-023-36568-z.
[46]	TAIWO O O, FINEGAN D P, PAZ-GARCIA J M, et al. Investigating the evolving microstructure of lithium metal electrodes in 3D using X-ray computed tomography[J]. Physical Chemistry Chemical Physics, 2017, 19(33): 22111-22120. DOI: 10.1039/C7CP02872E.
[47]	BURNS J C, STEVENS D A, DAHN J R. In-situ detection of lithium plating using high precision Coulometry[J]. Journal of the Electrochemical Society, 2015, 162(6): A959-A964. DOI: 10.1149/2.0621506jes.
[48]	TALIAN S D, BOBNAR J, SINIGOJ A R, et al. Transmission line model for description of the impedance response of Li electrodes with dendritic growth [J]. National Institute of Chemistry, 2019, 123(46): 27997-28007.
[49]	KOSEOGLOU M, TSIOUMAS E, FERENTINOU D, et al. Lithium plating detection using dynamic electrochemical impedance spectroscopy in lithium-ion batteries[J]. Journal of Power Sources, 2021, 512: 230508. DOI: 10.1016/j.jpowsour.2021.230508.
[50]	WALDMANN T, HOGG B I, KASPER M, et al. Interplay of operational parameters on lithium deposition in lithium-ion cells: Systematic measurements with reconstructed 3-electrode pouch full cells[J]. Journal of the Electrochemical Society, 2016, 163(7): A1232-A1238. DOI: 10.1149/2.0591607jes.
[51]	RANGARAJAN S P, BARSUKOV Y, MUKHERJEE P P. In operando signature and quantification of lithium plating[J]. Journal of Materials Chemistry A, 2019, 7(36): 20683-20695. DOI: 10.1039/C9TA07314K.
[52]	ABRAHAM D P, POPPEN S D, JANSEN A N, et al. Application of a lithium-tin reference electrode to determine electrode contributions to impedance rise in high-power lithium-ion cells[J]. Electrochimica Acta, 2004, 49(26): 4763-4775. DOI: 10.1016/j.electacta.2004. 05.040.
[53]	MANTIA F L, WESSELLS C D, DESHAZER H D, et al. Reliable reference electrodes for lithium-ion batteries[J]. Electrochemistry Communications, 2013, 31: 141-144. DOI: 10.1016/j.elecom. 2013.03.015.
[54]	YANG F F, SONG X B, DONG G Z, et al. A Coulombic efficiency-based model for prognostics and health estimation of lithium-ion batteries[J]. Energy, 2019, 171: 1173-1182. DOI: 10.1016/j.energy. 2019.01.083.
[55]	TANIM T R, DUFEK E J, DICKERSON C C, et al. Electrochemical quantification of lithium plating: Challenges and considerations[J]. Journal of the Electrochemical Society, 2019, 166(12): A2689-A2696. DOI: 10.1149/2.1581912jes.
[56]	PELED E, MENKIN S. Review-SEI: Past, present and future[J]. Journal of the Electrochemical Society, 2017, 164(7): A1703-A1719. DOI: 10.1149/2.1441707jes.
[57]	PETZL M, KASPER M, DANZER M A. Lithium plating in a commercial lithium-ion battery—A low-temperature aging study[J]. Journal of Power Sources, 2015, 275: 799-807. DOI: 10.1016/j.jpowsour.2014.11.065.
[58]	PASTOR-FERNÁNDEZ C, UDDIN K, CHOUCHELAMANE G H, et al. A comparison between electrochemical impedance spectroscopy and incremental capacity-differential voltage as Li-ion diagnostic techniques to identify and quantify the effects of degradation modes within battery management systems[J]. Journal of Power Sources, 2017, 360: 301-318. DOI: 10.1016/j.jpowsour.2017. 03.042.
[59]	SCHINDLER S, BAUER M, PETZL M, et al. Voltage relaxation and impedance spectroscopy as In-operando methods for the detection of lithium plating on graphitic anodes in commercial lithium-ion cells[J]. Journal of Power Sources, 2016, 304: 170-180. DOI: 10.1016/j.jpowsour.2015.11.044.
[60]	BROWN D E, MCSHANE E J, KONZ Z M, et al. Detecting onset of lithium plating during fast charging of Li-ion batteries using operando electrochemical impedance spectroscopy[J]. Cell Reports Physical Science, 2021, 2(10): 100589. DOI: 10.1016/j.xcrp.2021.100589.
[61]	WANG P, QU W J, SONG W L, et al. Electro-chemo-mechanical issues at the interfaces in solid-state lithium metal batteries[J]. Advanced Functional Materials, 2019, 29(27): 1900950. DOI: 10.1002/adfm.201900950.
[62]	HUANG W X, YE Y S, CHEN H, et al. Onboard early detection and mitigation of lithium plating in fast-charging batteries[J]. Nature Communications, 2022, 13: 7091. DOI: 10.1038/s41467-022-33486-4.
[63]	KIM S, RAJ A, LI B, et al. Correlation of electrochemical and mechanical responses: Differential analysis of rechargeable lithium metal cells[J]. Journal of Power Sources, 2020, 463: 228180. DOI: 10.1016/j.jpowsour.2020.228180.
[64]	BITZER B, GRUHLE A. A new method for detecting lithium plating by measuring the cell thickness [J]. Journal of Power Sources, 2014, 262(4): 297-302. DOI:10.1016/j.jpowsour.2014. 03.142.
[65]	WINTER E, SCHMIDT T J, TRABESINGER S. Potentiostatic lithium plating as a fast method for electrolyte evaluation in lithium metal batteries[J]. Electrochimica Acta, 2023, 439: 141547. DOI: 10.1016/j.electacta.2022.141547.
[66]	RIEGER B, SCHUSTER S F, ERHARD S V, et al. Multi-directional laser scanning as innovative method to detect local cell damage during fast charging of lithium-ion cells[J]. Journal of Energy Storage, 2016, 8: 1-5. DOI: 10.1016/j.est.2016.09.002.
[67]	GRIMSMANN F, GERBERT T, BRAUCHLE F, et al. Determining the maximum charging currents of lithium-ion cells for small charge quantities[J]. Journal of Power Sources, 2017, 365: 12-16. DOI: 10.1016/j.jpowsour.2017.08.044.
[68]	ESCHER I, A FERRERO G, GOKTAS M, et al. In situ (operando) electrochemical dilatometry as a method to distinguish charge storage mechanisms and metal plating processes for sodium and lithium ions in hard carbon battery electrodes[J]. Advanced Materials Interfaces, 2022, 9(8): 2100596. DOI: 10.1002/admi. 202100596.
[69]	TIAN Y, LIN C, LI H L, et al. Detecting undesired lithium plating on anodes for lithium-ion batteries—A review on the in situ methods[J]. Applied Energy, 2021, 300: 117386. DOI: 10.1016/j.apenergy.2021.117386.
[70]	CAI W, YAN C, YAO Y X, et al. The boundary of lithium plating in graphite electrode for safe lithium-ion batteries[J]. Angewandte Chemie, 2021, 60(23): 13007-13012. DOI:10.1002/anie.202102593.
[71]	LIN Y, HU W, DING M, et al. Unveiling the three stages of Li plating and dynamic evolution processes in pouch C/LiFePO₄ batteries[J]. Advanced Energy Materials. 2024, 2400894.https://doi.org/10.1002/aenm.202400894.
[72]	REN D S, LIU X, FENG X N, et al. Model-based thermal runaway prediction of lithium-ion batteries from kinetics analysis of cell components[J]. Applied Energy, 2018, 228: 633-644. DOI: 10.1016/j.apenergy.2018.06.126.
[73]	FLEISCHHAMMER M, WALDMANN T, BISLE G, et al. Interaction of cyclic ageing at high-rate and low temperatures and safety in lithium-ion batteries[J]. Journal of Power Sources, 2015, 274: 432-439. DOI: 10.1016/j.jpowsour.2014.08.135.
[74]	LI H, JI W J, ZHANG P, et al. Safety boundary of power battery based on quantitative lithium deposition[J]. Journal of Energy Storage, 2022, 52: 104789. DOI: 10.1016/j.est.2022.104789.
[75]	FENG X N, ZHENG S Q, REN D S, et al. Investigating the thermal runaway mechanisms of lithium-ion batteries based on thermal analysis database[J]. Applied Energy, 2019, 246: 53-64. DOI: 10.1016/j.apenergy.2019.04.009.
[76]	WALDMANN T, WOHLFAHRT-MEHRENS M. Effects of rest time after Li plating on safety behavior-ARC tests with commercial high-energy 18650 Li-ion cells[J]. Electrochimica Acta, 2017, 230: 454-460. DOI: 10.1016/j.electacta.2017.02.036.
[77]	ZHOU H W, FEAR C, CARTER R E, et al. Correlating lithium plating quantification with thermal safety characteristics of lithium-ion batteries[J]. Energy Storage Materials, 2024, 66: 103214. DOI: 10.1016/j.ensm.2024.103214.

锂离子电池阳极危害性析锂原位检测综述

Detecting hazardous lithium plating on anodes of lithium-ion batteries—A review of in situ methods

RichHTML

PDF

可视化

摘要/Abstract

引用本文

使用本文

图/表 7

参考文献 77

相关文章 15

编辑推荐

Metrics

本文评价

[1]	胡力月, 黄威, 周云, 周英强, 邵常政, 王柯. 基于模糊推理的储能系统锂离子电池模组热扩散概率评估方法[J]. 储能科学与技术, 2025, 14(7): 2662-2674.
[2]	王薇, 梁惠施, 李棉刚, 周奎, 王薇, 王姿尧, 史梓男. 基于迁移学习的锂电池不可逆析锂监测方法[J]. 储能科学与技术, 2025, 14(7): 2698-2706.
[3]	熊峰, 孔得朋, 平平, 张越, 任宪通, 吕耀. 电热耦合诱导三元锂离子电池热失控特性[J]. 储能科学与技术, 2025, 14(7): 2752-2760.
[4]	张子敬, 原蓓蓓, 李红, 高颖. 锂离子电池热失控气体检测分析及预警[J]. 储能科学与技术, 2025, 14(7): 2820-2832.
[5]	刘佳辉, 卞伟翔, 李大伟. 锂电池石墨复合电极力-电耦合性能原位测量分析[J]. 储能科学与技术, 2025, 14(6): 2240-2247.
[6]	陈峥, 多功东, 申江卫, 沈世全, 刘昱, 魏福星. 基于容量增量分析与VMD-GWO-KELM的锂电池健康状态估计[J]. 储能科学与技术, 2025, 14(6): 2476-2487.
[7]	阮晶晶, 巫湘坤, 李勇慧, 赵冲冲, 李珅珅, 王童飞, 梁圣杰, 高桂红. 低成本干法石墨厚电极的制备与性能研究[J]. 储能科学与技术, 2025, 14(6): 2248-2255.
[8]	韩丹丹, 张武卫, 张亮, 王宗江. 核壳结构LiMn₁_-_y Fe _y PO₄/C正极材料设计与电化学性能研究[J]. 储能科学与技术, 2025, 14(6): 2215-2222.
[9]	王功瑞, 张安萍, 任萱萱, 杨铭哲, 韩宇宁, 吴忠帅. 高电压钴酸锂正极：关键挑战、改性策略与未来展望[J]. 储能科学与技术, 2025, 14(6): 2278-2319.
[10]	周海洋, 张振东, 盛雷, 朱泽华, 张晓军, 张春风. 储能用锂电池浸没式热性能调控仿真及热安全实验研究[J]. 储能科学与技术, 2025, 14(5): 1866-1874.
[11]	宋海飞, 王乐红, 原义栋, 赵天挺, 陈捷. 基于改进卡尔曼算法的电池采样电压滤波估计[J]. 储能科学与技术, 2025, 14(5): 2106-2113.
[12]	曾州岚, 尚雷, 胡志金, 王宗凡, 辛小超, 刘瑛. 高容量锂离子电池正极补锂材料Li₅FeO₄@C的性能研究[J]. 储能科学与技术, 2025, 14(5): 1875-1883.
[13]	莫子鸣, 饶宗昕, 杨建飞, 杨孟昊, 蔡黎明. 锂离子电池过充热失控气热模型构建及关键参数影响分析[J]. 储能科学与技术, 2025, 14(5): 1784-1796.
[14]	彭磊, 倪照鹏, 于越, 孙福鹏, 夏修龙, 张鹏, 孙思博. 过充导致三元锂电池电动汽车火灾的试验研究[J]. 储能科学与技术, 2025, 14(4): 1484-1495.
[15]	申江卫, 折亦鑫, 舒星, 刘永刚, 魏福星, 夏雪磊, 陈峥. 基于短时随机充电数据和优化卷积神经网络的锂电池健康状态估计[J]. 储能科学与技术, 2025, 14(4): 1585-1595.