液态金属电池研究进展

doi:10.12028/j.issn.2095-4239.2017.0122

储能科学与技术 ›› 2017, Vol. 6 ›› Issue (5): 981-989.doi: 10.12028/j.issn.2095-4239.2017.0122

液态金属电池研究进展

黎朝晖1,2，朱方方1，李浩秒1，胡林2，彭勃3，李建颖2，何亚玲2，方瑛2，郭姣姣3，张坤3，王康丽1，蒋凯1

1 华中科技大学强电磁工程与新技术国家重点实验室，湖北武汉430074；2威胜集团有限公司，湖南长沙 410205；3西安西电电气研究院有限责任公司，陕西西安 710075）

收稿日期:2017-06-22 修回日期:2017-08-11 出版日期:2017-09-01 发布日期:2017-09-01
通讯作者: 蒋凯，教授，主要研究方向为新型电化学储能材料与技术等，E-mail：kjiang@hust.edu.cn。
作者简介:黎朝晖（1981—），男，博士，工程师，主要研究方向为液态金属电池及其它规模化储能技术，E-mail：lizhaohui@wasion.com
基金资助:
国家自然科学基金（51622703），湖北省技术创新专项（2016AAA038）项目。

Research progresses of liquid metal batteries

LI Zhaohui1, 2, ZHU Fangfang1, LI Haomiao1, HU Lin2, PENG Bo3, LI Jianying2, HE Yaling2, FANG Ying2, GUO Jiaojiao3, ZHANG Kun3, WANG Kangli1, JIANG Kai1

1 State Key Laboratory of Advanced Electromagnetic Engineering and Technology, Huazhong University of Science and Technology, Wuhan 430074, Hubei, China; 2Wasion Group, Changsha 410205, Hunan, China; 3Xi’an XD Electric Research Institute Co.,Ltd., Xi’an 710075, Shaanxi, China

Received:2017-06-22 Revised:2017-08-11 Online:2017-09-01 Published:2017-09-01

摘要/Abstract

摘要： 规模电能存储技术在有效利用可再生能源、构建智能电网、提高电能质量等领域的重要性日益凸显。液态金属电池作为一类新型储能电池技术，其电解质和正负极分别采用无机熔盐和液态金属，具有成本低、容量大、效率高、寿命长等特点，在规模储能领域具有广阔的应用前景。本文主要从电池设计和体系优化等方面介绍液态金属电池的重要研发进展，分析其主要技术挑战，在此基础上提出了面向电力储能应用的新型液态金属电池的发展方向。

关键词: 液态金属电池, 电化学储能, 电能存储

Abstract: Large-scale energy storage becomes more and more important in the applications of efficient utilization of renewable energy, development of smart grid and improvement of power supply quality. Liquid metal battery (LMB) is a newly developing battery with molten salt and metal/alloy as electrolyte and electrodes, respectively. LMB has potential applications in the large-scale stationary energy storage area, with the merits of low-cost, large-capacity, high-efficiency and long-life, etc. This paper mainly focuses on the R&D progresses of LMB, analyzes the technological challenges and points out the developing direction of novel LMB for large-scale applications.

Key words: liquid metal battery, electrochemical energy storage, electric energy storage

黎朝晖1,2，朱方方1，李浩秒1，胡林2，彭勃3，李建颖2，何亚玲2，方瑛2，郭姣姣3，张坤3，王康丽1，蒋凯1. 液态金属电池研究进展[J]. 储能科学与技术, 2017, 6(5): 981-989.

LI Zhaohui1, 2, ZHU Fangfang1, LI Haomiao1, HU Lin2, PENG Bo3, LI Jianying2, HE Yaling2, FANG Ying2, GUO Jiaojiao3, ZHANG Kun3, WANG Kangli1, JIANG Kai1. Research progresses of liquid metal batteries[J]. Energy Storage Science and Technology, 2017, 6(5): 981-989.

参考文献

[1] YANG Z, ZHANG J, KINTNER-MEYER M C W, et al. Electrochemical energy storage for green grid[J]. Chemical Reviews, 2011, 111(5): 3577-3613.
[2] 李琼慧, 王彩霞, 张静, 宁娜. 适用于电网的先进大容量储能技术发展路线图[J]. 储能科学与技术, 2017, 6(1): 141-146.
LI Qionghui, WANG Caixia, ZHANG Jing, NING Na. A roadmap for large scale energy storage for grid-level applications[J]. Energy Storage Science and Technology, 2017, 6(1): 141-146.
[3] SHIMOTAKE H, ROGERS G L, CAIRMS E J. Secondary cells with lithium anodes and immobilized fused-salt electrolytes[J]. Industrial and Engineering Chemistry process Design and Development, 1969, 8(1): 51-56.
[4] YEAGER E. Fuel cells: Basic considerations, in power sources division[C]//Proceedings of 12th Annual Battery Research and Development, Fort Monmouth, 1958.
[5] KIM H, BOYSEN D A, NEWHOUSE J M, et al. Liquid metal batteries: Past, present, and future[J]. Chemical Reviews, 2012, 113(3): 2075-2099.
[6] LI H, YIN H, WANG K, et al. Liquid metal electrodes for energy storage batteries[J]. Advanced Energy Materials, 2016, 6(14): 1600483.
[7] ARTSDALEN E R V, YAFFE I S. Electrical conductance and density of molten salt systems: KCl-LiCl, KCl-NaCl and KCl-KI[J]. The Journal of Physical Chemistry, 1955, 59(2): 118-127.
[8] MASSET P, HENRY A, POINSO J Y, et al. Ionic conductivity measurements of molten iodide-based electrolytes[J]. Journal of Power Sources, 2006, 160(1): 752-757.
[9] LEISER D B, JRO J W. The system LiI-KI[J]. Journal of the American Ceramic Society, 1967, 50(1): 60.
[10] SANGSTER J, PELTON A D. Phase diagrams and thermodynamic properties of the 70 binary alkali halide systems having common ions[J]. Journal of Physical & Chemical Reference Data, 1987, 16(3): 509-561.
[11] SELMAN J R, DENUCCIO D K, SY C J, et al. Cheminform abstract: EMF studies of lithium-rich lithium-aluminum alloys for high-energy secondary batteries[J]. Physical Inorganic Chemistry, 1977, 8(47): 1160-1164.
[12] REDEY L, GUIDOTTIR A. Re-evaluation of the eutectic region of the LiBr-KBr-LiF system[C]//Power Sources Conference, 1996.
[13] REDEY L, MCPARLAND M, GUIDOTTI R. Resistivity measurements of halide-salt/MgO separators for thermal cells[C]. Power Sources Symposium, Proceedings of the International. IEEE Xplore, 1990: 128-131.
[14] KAUN T D. Li-Al/FeS2cell with LiCl-LiBr-KBr electrolyte[J]. Journal of the Electro- Chemical Society, 1985, 132(12): 3063-3064.
[15] MAMANTOY G, BLANDER M, HUSSEY C, et al. Proceedings of the joint international symposium on molten salts[C]//Electrochemical Society Pennington NJ, 1987.
[16] VISSERS D R, REDEY L, KAUN T D. Molten salt electrolytes for high-temperature lithium cells[J]. Journal of Power Sources, 1989, 26(1/2): 37-48.
[17] JANZ G J, KREBS U, SIEGENTHALER H, et al. Molten salts: Volume 3 nitrates, nitrites, and mixtures: Electrical conductance, density, viscosity, and surface tension data[J]. Journal of Physical and Chemical Reference Data, 1972(3): 581-746.
[18] MASSET P, SCHOEFFERT S, POINSO J, et al. LiF-LiCl-LiI vs. LiF-LiBr-KBr as molten salt electrolyte in thermal batteries[J]. Journal of the Electrochemical Society, 2005, 152(2): A405-A410.
[19] JOHNSON C E, HATHAWAY E J. Solid-liquid phase equilibria for the ternary systems Li(F,Cl,I) and Na(F,Cl,I)[J]. Journal of the Electrochemical Society, 1971, 118(4): 631-634.
[20] MCMURDIE H F, HALL F P. Phase diagrams for ceramists, supplement No.1[J]. Journal of the American Ceramic Society, 2006, 32(1): 154-164.
[21] JOHNSON C E, FOSTER M S. Phase equilibrium studies of lithium halide-containing electrolytes[J]. Journal of the Electrochemical Society, 1969, 116(11): 1612-1613.
[22] BADER M, BUSSE C A. Wetting by sodium at high temperatures in pure vapour atmosphere[J]. Journal of Nuclear Materials, 1977, 67(3): 295-300.
[23] BREDIG M A. Mixtures of metals with molten salts[R]. Oak Ridge National Lab, Tenn, 1963, doi: 10.2172/4658668.
[24] BREDIG M A, JOHNSON J W, SMITH J R W T. Miscibility of liquid metals with salts. I. the sodium-sodium halide systems[J]. Journal of the American Chemical Society, 1955, 77(2): 307-312.
[25] BREDIG M A, BRONSTEIN H R. Miscibility of liquid metals with salts. IV. The sodium-sodium halide systems at high temperatures[J]. The Journal of Physical Chemistry, 1960, 64(1): 64-67.
[26] UKSHEk E A, BUKUN N G. The dissolution of metals in fused halides[J]. Russian Chemical Reviews, 1961, 30(2): 243-273.
[27] NING X, PHADKE S, CHUNG B, et al. Self-healing Li-Bi liquid metal battery for grid-scale energy storage[J]. Journal of Power Sources, 2014, 275: 370-376.
[28] BRADWELL D J, KIM H, SIRK A H C, et al. Magnesium-antimony liquid metal battery for stationary energy storage[J]. Journal of the American Chemical Society, 2012, 134(4): 1895-1897.
[29] WANG K, JIANG K, CHUNG B, et al. Lithium-antimony-lead liquid metal battery for grid-level energy storage[J]. Nature, 2014, 514(7522): 348-350.
[30] LI H, WANG K, CHENG S, JIANG K. High performance liquid metal battery with environmentally friendly antimony-tin positive electrode[J]. Acs Applied Materials & Interfaces, 2016, 8(20): 12830-12835.
[31] 李浩秒. 基于熔盐电化学的新型储能材料与技术研究[D]. 武汉: 华中科技大学, 2016.
[32] 陶宏伟. 液态金属高温电池密封材料的研究[D]. 武汉: 华中科技大学, 2014.
TAO Hongwei. A dissertation submitted in partial fulfillment of the requirments for the degree of master of engineering[D]. Wuhan: Huazhong University of Science and Technology, 2014.
[33] 蒋凯, 黎朝晖, 王康丽, 等. 耐腐蚀密封绝缘装置及中高温储能电池, CN205960043U[P]. 2017-02-15.
[34] 王大磊, 王康丽, 程时杰, 蒋凯. 液态金属电池储能特性建模及荷电状态估计[J]. 中国电机工程学报, 2017(8): 2253-2261.
WANG Dalei, WANG Kangli, CHENG Shijie, JIANG Kai. Modeling of energy storage properties and SOC estimation for liquid metal batteries[J]. Proceedings of the CSEE, 2017(8): 2253-2261.
[35] 蒋凯, 李浩秒, 李威, 程时杰. 几类面向电网的储能电池介绍[J]. 电力系统自动化, 2013, 37(1): 47-53.
JIANG Kai, LI Haomiao, LI Wei, CHENG Shijie. On several battery technologies for power grids[J]. Automation of Electric Power Systems, 2013, 37(1): 47-53.

液态金属电池研究进展

Research progresses of liquid metal batteries

PDF

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	林楠, KREWER Ulrike, ZAUSCH Jochen, STEINER Konrad, 林海波, 冯守华. 电化学能量储存和转换体系多物理场模型的建立及其应用[J]. 储能科学与技术, 2022, 11(4): 1149-1164.
[2]	赵志伟, 杨智, 彭章泉. 飞行时间二次离子质谱在锂基二次电池中的应用[J]. 储能科学与技术, 2022, 11(3): 781-794.
[3]	施思齐, 涂章伟, 邹欣欣, 孙拾雨, 杨正伟, 刘悦. 数据驱动的机器学习在电化学储能材料研究中的应用[J]. 储能科学与技术, 2022, 11(3): 739-759.
[4]	刘坚. 适应可再生能源消纳的储能技术经济性分析[J]. 储能科学与技术, 2022, 11(1): 397-404.
[5]	汤匀, 岳芳, 郭楷模, 李岚春, 陈伟. 下一代电化学储能技术国际发展态势分析[J]. 储能科学与技术, 2022, 11(1): 89-97.
[6]	朱寰, 刘国静, 张兴, 岳芬, 俞振华. 天然气发电与电池储能调峰政策及经济性对比[J]. 储能科学与技术, 2021, 10(6): 2392-2402.
[7]	杨朝霞, 娄景媛, 李雪菁, 王涵文, 王柯忠, 尤东江. 锌镍单液流电池发展现状[J]. 储能科学与技术, 2020, 9(6): 1678-1690.
[8]	曹锐鑫, 张　瑾, 朱嘉坤. 用户侧电化学储能装置最优系统配置与充放电策略研究[J]. 储能科学与技术, 2020, 9(6): 1890-1896.
[9]	裴哲义, 范高锋, 秦晓辉. 我国电力系统对大规模储能的需求分析[J]. 储能科学与技术, 2020, 9(5): 1562-1565.
[10]	刘庆华, 张赛, 蒋明哲, 王秋实, 邢学奇, 杨虹, 黄峰, LEMMON P John, 缪平. 低成本液流电池储能技术研究[J]. 储能科学与技术, 2019, 8(S1): 60-64.
[11]	孟祥飞, 庞秀岚, 崇锋, 侯少攀, 祁斌. 电化学储能在电网中的应用分析及展望[J]. 储能科学与技术, 2019, 8(S1): 38-42.
[12]	王江林, 徐学良, 丁青青, 朱军平, 马永泉, 赵磊, 刘孝伟. 锌镍电池在储能技术领域中的应用及展望[J]. 储能科学与技术, 2019, 8(3): 506-511.
[13]	王嘉赫，杨晓伟. 可拉伸式电化学储能器件研究进展与展望[J]. 储能科学与技术, 2018, 7(2): 157-166.
[14]	王超1，郭继鹏1,2，钟国彬1，徐凯琪1，苏伟1，项宏发2. 电化学储能器件恒流与恒功率充放电特性比较[J]. 储能科学与技术, 2017, 6(6): 1313-.
[15]	汪奂伶，侯朝勇，贾学翠，胡娟，许守平. 电化学储能系统标准对比分析[J]. 储能科学与技术, 2016, 5(4): 583-589.