Multiscale and multiphysics theoretical model and computational method for lithium-ion batteries

doi:10.19799/j.cnki.2095-4239.2023.0301

Abstract

Abstract:

Lithium-ion batteries have the advantages of high energy density, high working voltage, low self-discharge rate, and fast charging. They are widely used in various fields related to national defense industry and human life. After considerable efforts in developing the domestic battery industry, China has built a strong foundation in battery research and production. However, owing to the lack of battery computing models and design software, the design of novel batteries is still based on experience. Thus, relevant quantitative theoretical models and algorithm implementations are urgently needed. Lithium-ion battery systems have complex multiphysics coupling characteristics and multiscale characteristics in time and space. Unclear multifield coupling mechanisms related to lithiation and delithiation, the hard scale transitions in time and space, and the lack of design software are the main factors preventing the commercialization of novel materials in next-generation high-energy-density batteries. Herein, we propose a multiscale theoretical model and algorithm realization using the coupling of the electrochemomechanical behaviors of the batteries, including ① electrochemomechanical coupling theory of electrodes in lithium-ion batteries, ② finite element realization of multifield coupling behavior at various scales, ③ concurrent and hierarchical multiscale theoretical and numerical models of electrodes, and ④ electrochemomechanical behavior of the interface between the electrode and electrolyte.

Key words: lithium ion battery, multi-physics coupling, multi-scale, computational method

CLC Number:

O 34

Yikun WU, Jie HE, Le YANG, Weili SONG, Haosen CHEN. Multiscale and multiphysics theoretical model and computational method for lithium-ion batteries[J]. Energy Storage Science and Technology, 2023, 12(7): 2141-2154.

Figures/Tables 10

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References 106

1	RIEGER B, SCHLUETER S, ERHARD S V, et al. Multi-scale investigation of thickness changes in a commercial pouch type lithium-ion battery[J]. Journal of Energy Storage, 2016, 6: 213-221.
2	GRIMSMANN F, BRAUCHLE F, GERBERT T, et al. Hysteresis and current dependence of the thickness change of lithium-ion cells with graphite anode[J]. Journal of Energy Storage, 2017, 12: 132-137.
3	SAUERTEIG D, IVANOV S, REINSHAGEN H, et al. Reversible and irreversible dilation of lithium-ion battery electrodes investigated by in situ dilatometry[J]. Journal of Power Sources, 2017, 342: 939-946.
4	PRADO A Y R, RODRIGUES M T F, TRASK S E, et al. Electrochemical dilatometry of Si-bearing electrodes: Dimensional changes and experiment design[J]. Journal of the Electrochemical Society, 2020, 167(16): 160551.
5	PRUSSIN S. Generation and distribution of dislocations by solute diffusion[J]. Journal of Applied Physics, 1961, 32(10): 1876-1881.
6	CHENG Y T, VERBRUGGE M W. Evolution of stress within a spherical insertion electrode particle under potentiostatic and galvanostatic operation[J]. Journal of Power Sources, 2009, 190(2): 453-460.
7	DESHPANDE R, CHENG Y T, VERBRUGGE M W, et al. Diffusion induced stresses and strain energy in a phase-transforming spherical electrode particle[J]. Journal of the Electrochemical Society, 2011, 158(6): A718-A724.
8	LI J, FANG Q H, LIU F, et al. Analytical modeling of dislocation effect on diffusion induced stress in a cylindrical lithium ion battery electrode[J]. Journal of Power Sources, 2014, 272: 121-127.
9	ZHANG X Y, HAO F, CHEN H S, et al. Diffusion-induced stresses in transversely isotropic cylindrical electrodes of lithium-ion batteries[J]. Journal of the Electrochemical Society, 2014, 161(14): A2243-A2249.
10	LI J C M. Physical chemistry of some microstructural phenomena[J]. Metallurgical Transactions A, 1978, 9(10): 1353-1380.
11	LARCHÉ F, CAHN J W. A linear theory of thermochemical equilibrium of solids under stress[J]. Acta Metallurgica, 1973, 21(8): 1051-1063.
12	LARCHÉ F, CAHN J W. A nonlinear theory of thermochemical equilibrium of solids under stress[J]. Acta Metallurgica, 1978, 26(1): 53-60.
13	LARCHÉ F C, CAHN J W. Overview no. 41 The interactions of composition and stress in crystalline solids[J]. Acta Metallurgica, 1985, 33(3): 331-357.
14	CHRISTENSEN J, NEWMAN J. Stress generation and fracture in lithium insertion materials[J]. Journal of Solid State Electrochemistry, 2006, 10(5): 293-319.
15	SETHURAMAN V A, CHON M J, SHIMSHAK M, et al. In situ measurement of biaxial modulus of Si anode for Li-ion batteries[J]. Electrochemistry Communications, 2010, 12(11): 1614-1617.
16	SETHURAMAN V A, CHON M J, SHIMSHAK M, et al. In situ measurements of stress evolution in silicon thin films during electrochemical lithiation and delithiation[J]. Journal of Power Sources, 2010, 195(15): 5062-5066.
17	SETHURAMAN V A, SRINIVASAN V, BOWER A F, et al. In situ measurements of stress-potential coupling in lithiated silicon[J]. Journal of the Electrochemical Society, 2010, 157(11): A1253.
18	LIU X H, ZHENG H, ZHONG L, et al. Anisotropic swelling and fracture of silicon nanowires during lithiation[J]. Nano Letters, 2011, 11(8): 3312-3318.
19	KUSHIMA A, HUANG J Y, LI J. Quantitative fracture strength and plasticity measurements of lithiated silicon nanowires by in situ TEM tensile experiments[J]. ACS Nano, 2012, 6(11): 9425-9432.
20	ZHAO K J, LI Y G, BRASSART L. Pressure-sensitive plasticity of lithiated silicon in Li-ion batteries[J]. Acta Mechanica Sinica, 2013, 29(3): 379-387.
21	YANG H, FAN F F, LIANG W T, et al. A chemo-mechanical model of lithiation in silicon[J]. Journal of the Mechanics and Physics of Solids, 2014, 70: 349-361.
22	ZHAO K J, PHARR M, VLASSAK J J, et al. Inelastic hosts as electrodes for high-capacity lithium-ion batteries[J]. Journal of Applied Physics, 2011, 109(1): 016110.
23	ZHAO K J, PHARR M, CAI S Q, et al. Large plastic deformation in high-capacity lithium-ion batteries caused by charge and discharge[J]. Journal of the American Ceramic Society, 2011, 94: s226-s235.
24	CUI Z W, GAO F, QU J M. A finite deformation stress-dependent chemical potential and its applications to lithium ion batteries[J]. Journal of the Mechanics and Physics of Solids, 2012, 60(7): 1280-1295.
25	CUI Z W, GAO F, QU J M. Interface-reaction controlled diffusion in binary solids with applications to lithiation of silicon in lithium-ion batteries[J]. Journal of the Mechanics and Physics of Solids, 2013, 61(2): 293-310.
26	CHEN L, FAN F, HONG L, et al. A phase-field model coupled with large elasto-plastic deformation: Application to lithiated silicon electrodes[J]. Journal of the Electrochemical Society, 2014, 161(11): F3164-F3172.
27	DI LEO C V, REJOVITZKY E, ANAND L. A Cahn-Hilliard-type phase-field theory for species diffusion coupled with large elastic deformations: Application to phase-separating Li-ion electrode materials[J]. Journal of the Mechanics and Physics of Solids, 2014, 70: 1-29.
28	DAL H, MIEHE C. Computational electro-chemo-mechanics of lithium-ion battery electrodes at finite strains[J]. Computational Mechanics, 2015, 55(2): 303-325.
29	DI LEO C V, REJOVITZKY E, ANAND L. Diffusion-deformation theory for amorphous silicon anodes: The role of plastic deformation on electrochemical performance[J]. International Journal of Solids and Structures, 2015, 67: 283-296.
30	ZHANG S L. Chemomechanical modeling of lithiation-induced failure in high-volume-change electrode materials for lithium ion batteries[J]. Npj Computational Materials, 2017, 3(1): 1-11.
31	WEN J C, WEI Y J, CHENG Y T. Stress evolution in elastic-plastic electrodes during electrochemical processes: A numerical method and its applications[J]. Journal of the Mechanics and Physics of Solids, 2018, 116: 403-415.
32	LEE E H. Elastic-plastic deformation at finite strains[J]. Journal of Applied Mechanics, 1969, 36(1): 1-6.
33	WU C H. The role of Eshelby stress in composition-generated and stress-assisted diffusion[J]. Journal of the Mechanics and Physics of Solids, 2001, 49(8): 1771-1794.
34	HU B, MA Z S, LEI W X, et al. A chemo-mechanical model coupled with thermal effect on the hollow core-shell electrodes in lithium-ion batteries[J]. Theoretical and Applied Mechanics Letters, 2017, 7(4): 199-206.
35	LIM C, YAN B, YIN L L, et al. Simulation of diffusion-induced stress using reconstructed electrodes particle structures generated by micro/nano-CT[J]. Electrochimica Acta, 2012, 75: 279-287.
36	APPIAH W A, PARK J, BYUN S, et al. A coupled chemo-mechanical model to study the effects of adhesive strength on the electrochemical performance of silicon electrodes for advanced lithium ion batteries[J]. Journal of Power Sources, 2018, 407: 153-161.
37	冯燕, 郑莉莉, 戴作强, 等. 锂离子电池仿真模型的进展[J]. 储能科学与技术, 2019, 8(S1): 18-22.
	FENG Y, ZHENG L L, DAI Z Q, et al. Progress in lithium ion battery simulation model[J]. Energy Storage Science and Technology, 2019, 8(S1): 18-22.
38	DELUCA C M, MAUTE K, DUNN M L. Effects of electrode particle morphology on stress generation in silicon during lithium insertion[J]. Journal of Power Sources, 2011, 196(22): 9672-9681.
39	STEIN P, XU B X. 3D Isogeometric Analysis of intercalation-induced stresses in Li-ion battery electrode particles[J]. Computer Methods in Applied Mechanics and Engineering, 2014, 268: 225-244.
40	WEN J C, WEI Y J, CHENG Y T. Examining the validity of Stoney-equation for in situ stress measurements in thin film electrodes using a large-deformation finite-element procedure[J]. Journal of Power Sources, 2018, 387: 126-134.
41	CHEN Y X, SANG M S, JIANG W J, et al. Fracture predictions based on a coupled chemo-mechanical model with strain gradient plasticity theory for film electrodes of Li-ion batteries[J]. Engineering Fracture Mechanics, 2021, 253: 107866.
42	MAGRI M, BOZ B, CABRAS L, et al. Quantitative investigation of the influence of electrode morphology in the electro-chemo-mechanical response of li-ion batteries[J]. Electrochimica Acta, 2022, 405: 139778.
43	ZHANG X Y, BAO Y H, CHEN J, et al. Heterogeneous effects on chemo-mechanical coupling behaviors at the single-particle level[J]. Journal of the Electrochemical Society, 2022, 169(1): 010522.
44	AN Y H, JIANG H Q. A finite element simulation on transient large deformation and mass diffusion in electrodes for lithium ion batteries[J]. Modelling and Simulation in Materials Science and Engineering, 2013, 21(7): 074007.
45	YANG L, CHEN H S, JIANG H Q, et al. Failure mechanisms of 2D silicon film anodes: in situ observations and simulations on crack evolution[J]. Chemical Communications, 2018, 54(32): 3997-4000.
46	LIU X H, ZHONG L, HUANG S, et al. Size-dependent fracture of silicon nanoparticles during lithiation[J]. ACS Nano, 2012, 6(2): 1522-1531.
47	BOWER A F, GUDURU P R. A simple finite element model of diffusion, finite deformation, plasticity and fracture in lithium ion insertion electrode materials[J]. Modelling and Simulation in Materials Science and Engineering, 2012, 20(4): 045004.
48	GAO Y F, CHO M, ZHOU M. Mechanical reliability of alloy-based electrode materials for rechargeable Li-ion batteries[J]. Journal of Mechanical Science and Technology, 2013, 27(5): 1205-1224.
49	GRITTON C, GUILKEY J, HOOPER J, et al. Using the material point method to model chemical/mechanical coupling in the deformation of a silicon anode[J]. Modelling and Simulation in Materials Science and Engineering, 2017, 25(4): 045005.
50	DING B, WU H, XU Z P, et al. Stress effects on lithiation in silicon[J]. Nano Energy, 2017, 38: 486-493.
51	SANGRÓS GIMÉNEZ C, FINKE B, SCHILDE C, et al. Numerical simulation of the behavior of lithium-ion battery electrodes during the calendaring process via the discrete element method[J]. Powder Technology, 2019, 349: 1-11.
52	SCHREINER D, LINDENBLATT J, GÜNTER J, et al. DEM simulations of the calendering process: parameterization of the electrode material of lithium-ion batteries[J]. Procedia CIRP, 2021, 104: 91-97.
53	NGANDJONG A C, LOMBARDO T, PRIMO E N, et al. Investigating electrode calendering and its impact on electrochemical performance by means of a new discrete element method model: Towards a digital twin of Li-Ion battery manufacturing[J]. Journal of Power Sources, 2021, 485: 229320.
54	GE R H, CUMMING D J, SMITH R M. Discrete element method (DEM) analysis of lithium ion battery electrode structures from X-ray tomography-the effect of calendering conditions[J]. Powder Technology, 2022, 403: 117366.
55	GOONEIE A, SCHUSCHNIGG S, HOLZER C. A review of multiscale computational methods in polymeric materials[J]. Polymers, 2017, 9(1): 16.
56	KIM G H, SMITH K, LEE K J, et al. Multi-domain modeling of lithium-ion batteries encompassing multi-physics in varied length scales[J]. Journal of the Electrochemical Society, 2011, 158(8): A955.
57	LIU B H, WANG X, CHEN H S, et al. A simultaneous multiscale and multiphysics model and numerical implementation of a core-shell model for lithium-ion full-cell batteries[J]. Journal of Applied Mechanics, 2019, 86(4): 041005.
58	HOFMANN T, WESTHOFF D, FEINAUER J, et al. Electro-chemo-mechanical simulation for lithium ion batteries across the scales[J]. International Journal of Solids and Structures, 2020, 184(C): 24-39.
59	KIM H K, CHOI J H, LEE K J. A numerical study of the effects of cell formats on the cycle life of lithium ion batteries[J]. Journal of the Electrochemical Society, 2019, 166(10): A1769-A1778.
60	GOLMON S, MAUTE K, DUNN M L. Numerical modeling of electrochemical-mechanical interactions in lithium polymer batteries[J]. Computers & Structures, 2009, 87(23/24): 1567-1579.
61	FAN G D, PAN K, STORTI G L, et al. A reduced-order multi-scale, multi-dimensional model for performance prediction of large-format Li-Ion cells[J]. Journal of the Electrochemical Society, 2017, 164(2): A252-A264.
62	GWAK Y, MOON J, CHO M. Multi-scale analysis of an electrochemical model including coupled diffusion, stress, and nonideal solution in a silicon thin film anode[J]. Journal of Power Sources, 2016, 307: 856-865.
63	XIAO X R, WU W, HUANG X S. A multi-scale approach for the stress analysis of polymeric separators in a lithium-ion battery[J]. Journal of Power Sources, 2010, 195(22): 7649-7660.
64	WU B, LU W. A consistently coupled multiscale mechanical-electrochemical battery model with particle interaction and its validation[J]. Journal of the Mechanics and Physics of Solids, 2019, 125: 89-111.
65	MICHAEL H, IACOVIELLO F, HEENAN T M M, et al. A dilatometric study of graphite electrodes during cycling with X-ray computed tomography[J]. Journal of the Electrochemical Society, 2021, 168(1): 010507.
66	SHEARING P R, HOWARD L E, JØRGENSEN P S, et al. Characterization of the 3-dimensional microstructure of a graphite negative electrode from a Li-ion battery[J]. Electrochemistry Communications, 2010, 12(3): 374-377.
67	VANPEENE V, VILLANOVA J, SUURONEN J P, et al. Monitoring the morphological changes of Si-based electrodes by X-ray computed tomography: A 4D-multiscale approach[J]. Nano Energy, 2020, 74: 104848.
68	冯小龙, 杨乐, 张明亮, 等. 锂离子电池内部力学与温度参量在位表征方法[J]. 储能科学与技术, 2019, 8(6): 1062-1075.
	FENG X L, YANG L, ZHANG M L, et al. Failure mechanics inner lithium ion batteries: In-situ multi-field experimental methods[J]. Energy Storage Science and Technology, 2019, 8(6): 1062-1075.
69	STEPHENSON D E, WALKER B C, SKELTON C B, et al. Modeling 3D microstructure and ion transport in porous Li-ion battery electrodes[J]. Journal of the Electrochemical Society, 2011, 158(7): A781.
70	WILSON J R, CRONIN J S, BARNETT S A, et al. Measurement of three-dimensional microstructure in a LiCoO₂ positive electrode[J]. Journal of Power Sources, 2011, 196(7): 3443-3447.
71	TREMBACKI B L, NOBLE D R, BRUNINI V E, et al. Mesoscale effective property simulations incorporating conductive binder[J]. Journal of the Electrochemical Society, 2017, 164(11): E3613-E3626.
72	EBNER M, GELDMACHER F, MARONE F, et al. X-ray tomography of porous, transition metal oxide based lithium ion battery electrodes[J]. Advanced Energy Materials, 2013, 3(7): 845-850.
73	ENDER M, JOOS J, CARRARO T, et al. Three-dimensional reconstruction of a composite cathode for lithium-ion cells[J]. Electrochemistry Communications, 2011, 13(2): 166-168.
74	WIEDEMANN A H, GOLDIN G M, BARNETT S A, et al. Effects of three-dimensional cathode microstructure on the performance of lithium-ion battery cathodes[J]. Electrochimica Acta, 2013, 88: 580-588.
75	WIESER C, PRILL T, SCHLADITZ K. Multiscale simulation process and application to additives in porous composite battery electrodes[J]. Journal of Power Sources, 2015, 277: 64-75.
76	陈玉丽, 马勇, 潘飞, 等. 多尺度复合材料力学研究进展[J]. 固体力学学报, 2018, 39(1): 1-68.
	CHEN Y L, MA Y, PAN F, et al. Research progress in multi-scale mechanics of composite materials[J]. Chinese Journal of Solid Mechanics, 2018, 39(1): 1-68.
77	FISH J, WAGNER G J, KETEN S. Mesoscopic and multiscale modelling in materials[J]. Nature Materials, 2021, 20(6): 774-786.
78	MIEHE C. Computational micro-to-macro transitions for discretized micro-structures of heterogeneous materials at finite strains based on the minimization of averaged incremental energy[J]. Computer Methods in Applied Mechanics and Engineering, 2003, 192(5/6): 559-591.
79	ESHELBY J D. The determination of the elastic field of an ellipsoidal inclusion, and related problems[J]. Proceedings of the Royal Society of London Series A Mathematical and Physical Sciences, 1957, 241(1226): 376-396.
80	ZHUO M Z, GRAZIOLI D, SIMONE A. Tensorial effective transport properties of Li-ion battery separators elucidated by computational multiscale modeling[J]. Electrochimica Acta, 2021, 393: 139045.
81	SALVADORI A, BOSCO E, GRAZIOLI D. A computational homogenization approach for Li-ion battery cells: Part 1-Formulation[J]. Journal of the Mechanics and Physics of Solids, 2014, 65: 114-137.
82	VAN'T HOFF J H. Etudes de dynamique chimique[M]. Frederik Muller, 1884.
83	BUTLER J A V. Studies in heterogeneous equilibria. Part Ⅱ.—The kinetic interpretation of the Nernst theory of electromotive force[J]. Transactions of the Faraday Society, 1924, 19(March): 729-733.
84	ERDEY-GRÚZ T, VOLMER M. Zur theorie der wasserstoff überspannung[J]. Zeitschrift Für Physikalische Chemie, 1930, 150A(1): 203-213.
85	DICKINSON E J F, WAIN A J. The Butler-Volmer equation in electrochemical theory: Origins, value, and practical application[J]. Journal of Electroanalytical Chemistry, 2020, 872: 114145.
86	INZELT G. Milestones of the development of kinetics of electrode reactions[J]. Journal of Solid State Electrochemistry, 2011, 15(7): 1373-1389.
87	LABORDA E, HENSTRIDGE M C, BATCHELOR-MCAULEY C, et al. Asymmetric Marcus-Hush theory for voltammetry[J]. Chemical Society Reviews, 2013, 42(12): 4894-4905.
88	SRIPAD S, KORFF D, DECALUWE S C, et al. Kinetics of lithium electrodeposition and stripping[J]. The Journal of Chemical Physics, 2020, 153(19): 194701.
89	KURCHIN R, VISWANATHAN V. Marcus-Hush-Chidsey kinetics at electrode-electrolyte interfaces[J]. The Journal of Chemical Physics, 2020, 153(13): 134706.
90	HENSTRIDGE M C, LABORDA E, REES N V, et al. Marcus-Hush-Chidsey theory of electron transfer applied to voltammetry: A review[J]. Electrochimica Acta, 2012, 84: 12-20.
91	FRUMKIN A. Wasserstoffüberspannung und struktur der doppelschicht[J]. Zeitschrift Für Physikalische Chemie, 1933, 164A(1): 121-133.
92	GUTMAN E M. Theoretical problems in solid electrocapillarity[J]. Journal of Solid State Electrochemistry, 2014, 18(12): 3217-3237.
93	MARCUS R A. Electrostatic free energy and other properties of states having nonequilibrium polarization. I[J]. The Journal of Chemical Physics, 1956, 24(5): 979-989.
94	GURNEY R W. The quantum mechanics of electrolysis[J]. Proceedings of the Royal Society of London. Series A, Containing Papers of a Mathematical and Physical Character, 1931, 134(823): 137-154.
95	DOBLHOFF-DIER K, KOPER M T M. Modeling the Gouy-Chapman diffuse capacitance with attractive ion-surface interaction[J]. The Journal of Physical Chemistry C, 2021, 125(30): 16664-16673.
96	FRAGGEDAKIS D, MCELDREW M, SMITH R B, et al. Theory of coupled ion-electron transfer kinetics[J]. Electrochimica Acta, 2021, 367: 137432.
97	BAZANT M Z. Theory of chemical kinetics and charge transfer based on nonequilibrium thermodynamics[J]. Accounts of Chemical Research, 2013, 46(5): 1144-1160.
98	CHEONG J Y, JUNG J W, KIM C, et al. Scalable top-down synthesis of functional carbon nanosheets by aronia fruit powder for Li⁺ and K⁺ storage[J]. Electrochimica Acta, 2021, 377: 138068.
99	CHEN R T, REN Z F, LIANG Y, et al. Spatiotemporal imaging of charge transfer in photocatalyst particles[J]. Nature, 2022, 610(7931): 296-301.
100	NEWNS D M. Self-consistent model of hydrogen chemisorption[J]. Physical Review, 1969, 178(3): 1123-1135.
101	BOWER A F, GUDURU P R, SETHURAMAN V A. A finite strain model of stress, diffusion, plastic flow, and electrochemical reactions in a lithium-ion half-cell[J]. Journal of the Mechanics and Physics of Solids, 2011, 59(4): 804-828.
102	HE J, YANG L, HUANG J, et al. Hybrid quantum-classical model of mechano-electrochemical effects on graphite-electrolyte interfaces in metal-ion batteries[J]. Extreme Mechanics Letters, 2023, 59: 101971.
103	HE J, YANG L, HUANG J, et al. Hybrid quantum-classical treatment of lithium ion transfer reactions at graphite-electrolyte interfaces[J]. Journal of Power Sources, 2023, 564: 232880.
104	GOLMON S, MAUTE K, LEE S.-H, et al. Stress generation in silicon particles during lithium insertion[J]. Applied Physics Letters, 2010, 97(3): 33111.
105	GANSER M, HILDEBRAND F E, KAMLAH M, et al. A finite strain electro-chemo-mechanical theory for ion transport with application to binary solid electrolytes[J]. Journal of the Mechanics and Physics of Solids, 2019, 125: 681-713.
106	BRASSART L, STAINIER L. Effective transient behaviour of heterogeneous media in diffusion problems with a large contrast in the phase diffusivities[J]. Journal of the Mechanics and Physics of Solids, 2019, 124: 366-391.

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