三维孔道NiMn-MOF电极材料制备及电化学性能研究

doi:10.19799/j.cnki.2095-4239.2023.0545

储能科学与技术 ›› 2024, Vol. 13 ›› Issue (2): 361-369.doi: 10.19799/j.cnki.2095-4239.2023.0545

三维孔道NiMn-MOF电极材料制备及电化学性能研究

刘新¹^,²(), 毛喜玲²^,³(), 闫欣雨²^,³, 王俊强²^,³, 李孟委²^,³

^1.中北大学能源与动力工程学院
^2.中北大学前沿交叉科学研究院
^3.中北大学仪器与电子学院，山西太原 030051

收稿日期:2023-08-14 修回日期:2023-09-15 出版日期:2024-02-28 发布日期:2024-03-01
通讯作者: 毛喜玲 E-mail:xinlau6688@163.com;xlmao0620@nuc.edu.cn
作者简介:刘新（1998—），男，硕士研究生，主要从事NiMn-MOF及其衍生物电极材料设计与调控研究，E-mail：xinlau6688@163.com；
基金资助:
国家自然科学基金青年基金项目(62004178);山西省基础研究计划(202203021212149)

Preparation and electrochemical properties of NiMn-MOF with 3D pore network electrode materials

Xin LIU¹^,²(), Xiling MAO²^,³(), Xinyu YAN²^,³, Junqiang WANG²^,³, Mengwei LI²^,³

^1.School of Energy and Power Engineering, North University of China
^2.Academy for Advanced Interdisciplinary Research, North University of China
^3.School of Instrument and Electronics, North University of China, Taiyuan 030051, Shanxi, China

Received:2023-08-14 Revised:2023-09-15 Online:2024-02-28 Published:2024-03-01
Contact: Xiling MAO E-mail:xinlau6688@163.com;xlmao0620@nuc.edu.cn

摘要/Abstract

摘要：

针对目前超级电容器电极材料能量密度较低、制备工艺复杂的难题，利用MOF材料的高比表面积、多孔结构的优势，本工作采用简单可控的一步水热法制备具有三维孔道网络结构的双金属NiMn-MOF纳米片，Ni与Mn相近的原子半径有利于双金属NiMn-MOF的合成以及暴露出更多的活性位点，通过不断优化工艺参数（水热温度和水热时间），进行对比获得了高比容的NiMn-MOF电极材料。同时借助扫描电子显微技术（SEM）、能谱分析技术（EDS）、X射线衍射技术（XRD）对电极材料的形貌和晶体结构进行详细的表征，利用循环伏安（CV）、恒流充放电（GCD）、交流阻抗（EIS）进行电化学性能分析。在6 mol/L的KOH电解液中进行三电极测试，结果表明当电流密度为0.5 A/g时，其比容量高达1023.5 F/g。以双金属NiMn-MOF为正极，活性炭（AC）为负极组装的非对称超级电容器，在电流密度为0.5 A/g时，其比容量为94.37 F/g，并使用该器件成功点亮红色LED灯，表明所制备的双金属NiMn-MOF纳米片具有良好的电化学性能，为超级电容器电极材料的制备提供了新的思路。

关键词: 镍锰过渡金属有机框架材料, 电极材料, 超级电容器, 电化学性能

Abstract:

Addressing the issue of low energy density and complex preparation process associated with supercapacitor electrode materials, this study capitalizes on the high specific surface area and porous structure of MOF materials. Bimetallic NiMn-MOF nanosheets with a three-dimensional pore network structure were prepared through a simple and controllable one-step hydrothermal method. The close atomic radius of Ni and Mn proved beneficial for synthesizing bimetallic NiMn-MOF, exposing additional active sites. The optimization of process parameters resulted in bimetallic NiMn-MOF electrode materials with high specific volumes. The morphology and crystal structure of the electrode materials were characterized in detail via scanning electron microscopy, energy-dispersive spectroscopy, and X-ray diffraction. The electrochemical properties were also analyzed using cyclic voltammetry, galvanostatic charge/discharge, and electrochemical impedance spectroscopy. The results showed an impressive specific capacitance of 1023.5 F/g at 0.5 A/g in a 6 mol/L KOH electrolyte. Additionally, an assembled asymmetric supercapacitor delivered a capacitance of 94.37 F/g at 0.5 A/g, successfully powered a red LED. This outcome underscores the excellent electrochemical performance of NiMn-MOF, offering a new approach to preparing electrode materials for supercapacitors.

Key words: NiMn-MOF, electrode materials, supercapacitors, electrochemical performances

中图分类号:

TM 53

刘新, 毛喜玲, 闫欣雨, 王俊强, 李孟委. 三维孔道NiMn-MOF电极材料制备及电化学性能研究[J]. 储能科学与技术, 2024, 13(2): 361-369.

Xin LIU, Xiling MAO, Xinyu YAN, Junqiang WANG, Mengwei LI. Preparation and electrochemical properties of NiMn-MOF with 3D pore network electrode materials[J]. Energy Storage Science and Technology, 2024, 13(2): 361-369.

图/表 6

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参考文献 27

1	MOURAD E, COUSTAN L, LANNELONGUE P, et al. Biredox ionic liquids with solid-like redox density in the liquid state for high-energy supercapacitors[J]. Nature Materials, 2017, 16: 446-453.
2	CHEN L F, LU Y, YU L, et al. Designed formation of hollow particle-based nitrogen-doped carbon nanofibers for high-performance supercapacitors[J]. Energy & Environmental Science, 2017, 10(8): 1777-1783.
3	RAN F T, YANG X B, SHAO L. Recent progress in carbon-based nanoarchitectures for advanced supercapacitors[J]. Advanced Composites and Hybrid Materials, 2018, 1(1): 32-55.
4	毛喜玲. 高比容电极材料及微型超级电容器特性研究[D]. 成都: 电子科技大学, 2019.
	MAO X L. Investigation of high specific capacitance electrode materials and microsupercapacitors[D]. Chengdu: University of Electronic Science and Technology of China, 2019.
5	ZHANG X, YANG S X, LU W, et al. MXenes induced formation of Ni-MOF microbelts for high-performance supercapacitors[J]. Journal of Colloid and Interface Science, 2021, 592: 95-102.
6	魏振山, 吴磊, 李龙, 等. 柔性超级电容器及其研究进展[J]. 纺织科技进展, 2023(3): 1-5.
	WEI Z S, WU L, LI L, et al. Flexible supercapacitors and their research progress[J]. Progress in Textile Science & Technology, 2023(3): 1-5.
7	RAZA N, KUMAR T, SINGH V, et al. Recent advances in bimetallic metal-organic framework as a potential candidate for supercapacitor electrode material[J]. Coordination Chemistry Reviews, 2021, 430: 213660.
8	ZHANG R, PANG H. Application of graphene-metal/conductive polymer based composites in supercapacitors[J]. Journal of Energy Storage, 2021, 33: 102037.
9	LIU R, ZHOU A, ZHANG X R, et al. Fundamentals, advances and challenges of transition metal compounds-based supercapacitors[J]. Chemical Engineering Journal, 2021, 412: 128611.
10	WANG R, LI X Y, NIE Z G, et al. Metal/metal oxide nanoparticles-composited porous carbon for high-performance supercapacitors[J]. Journal of Energy Storage, 2021, 38: 102479.
11	佟永丽, 武祥. 金属有机框架衍生的Co₃O₄电极材料及其电化学性能[J]. 储能科学与技术, 2022, 11(3): 1035-1043.
	TONG Y L, WU X. Electrochemical performance of Co₃O₄ electrode materials derived from Co metal-organic framework[J]. Energy Storage Science and Technology, 2022, 11(3): 1035-1043.
12	张成光. MOFs/导电聚合物复合材料制备及其电化学特性研究[D]. 成都: 电子科技大学, 2020.
	ZHANG C G. Preparation and electrochemical properties of MOFs/conductive polymer composites[D]. Chengdu: University of Electronic Science and Technology of China, 2020.
13	孙雪娇, 王晨鹏, 潘晓阳, 等. MOFs基多孔碳材料在气体吸附与分离中的应用[J]. 科学通报, 2021, 66(27): 3590-3603.
	SUN X J, WANG C P, PAN X Y, et al. MOFs-derived porous carbon materials for gas adsorption and separation[J]. Chinese Science Bulletin, 2021, 66(27): 3590-3603.
14	YUAN B Q, WANG X, ZHOU X, et al. Novel room-temperature synthesis of MIL-100(Fe) and its excellent adsorption performances for separation of light hydrocarbons[J]. Chemical Engineering Journal, 2019, 355: 679-686.
15	葛全倩, 徐迈, 梁铣, 等. MOFs材料在光电催化领域应用的研究进展[J]. 化工进展, 2023, 42(9): 4692-4705.
	GE Q Q, XU M, LIANG X, et al. Research progress on the application of MOFs in photoelectrocatalysis[J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4692-4705.
16	JIAO L, WANG Y, JIANG H L, et al. Metal-organic frameworks as platforms for catalytic applications[J]. Advanced Materials, 2018, 30(37): e1703663.
17	RAN F T, XU X Q, PAN D, et al. Ultrathin 2D metal–organic framework nanosheets in situ interpenetrated by functional CNTs for hybrid energy storage device[J]. Nano-Micro Letters, 2020, 12(1): 46.
18	王全璐, 宋慧敏, 张展鹏, 等. 金属有机骨架及其复合材料超电容性能研究进展[J]. 化学推进剂与高分子材料, 2021, 19(6): 19-25.
	WANG Q L, SONG H M, ZHANG Z P, et al. Research progress of metal-organic frameworks and supercapacitor performance of their composite materials[J]. Chemical Propellants & Polymeric Materials, 2021, 19(6): 19-25.
19	WANG Y L, SONG J, WONG W Y. Constructing 2D sandwich-like MOF/MXene heterostructures for durable and fast aqueous zinc-ion batteries[J]. Angewandte Chemie (International Ed in English), 2023, 62(8): e202218343.
20	LIU X J, ZHANG X L, LIU R M, et al. A Ni-doped Mn-MOF decorated on Ni-foam as an electrode for high-performance supercapacitors[J]. Journal of Nanoparticle Research, 2022, 24(2): 23.
21	PAN Y F, GAO D Y, DANG Y P, et al. Bimetallic electronic effects of Mn-doped Ni-MOF shuttle-like nanosheets remarkably enhance the supercapacitive performance[J]. Inorganic Chemistry Frontiers, 2022, 9(22): 5982-5993.
22	BABU S K, RAJ J J D, VIJAYAKUMAR T, et al. Experimental and DFT studies on spinel NiMn₂O₄ flower derived from bimetallic MOF as an efficient electrode for next-generation supercapacitor[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2022, 655: 130244.
23	朱涛. 高容量超级电容器电极材料的制备与性能研究[D]. 上海: 上海大学, 2016.
	ZHU T. Studies on synthesis and electrochemical properties of high capacity electrode materials for supercapacitor applications[D]. Shanghai: Shanghai University, 2016.
24	YUAN H, GUO Y M, JIANG L H. A porous MOF-derived NiMn₂O₄ material and its superior energy storage performance for high-performance supercapacitors[J]. New Journal of Chemistry, 2022, 46(12): 5741-5750.
25	王跃迪, 仇中柱, 吴渺, 等. 多孔NiMoO₄/NiCo₂S₄复合材料的制备及其电化学性能[J]. 储能科学与技术, 2023, 12(4): 1034-1044.
	WANG Y D, QIU Z Z, WU M, et al. Preparation and electrochemical properties of porous NiMoO₄/NiCo₂S₄ composites[J]. Energy Storage Science and Technology, 2023, 12(4): 1034-1044.
26	祝玉婷, 闫共芹, 林羽芊. MoS₂/RGO复合材料的电化学性能和第一性原理研究[J]. 储能科学与技术, 2023, 12(3): 698-709.
	ZHU Y T, YAN G Q, LIN Y Q. Electrochemical properties and First-principles study of MoS₂/rGO composite[J]. Energy Storage Science and Technology, 2023, 12(3): 698-709.
27	蔡婷婷, 刘镕玮, 王媛媛, 等. 镍钴硫化物/碳微球电极的制备与电化学性能测试[J]. 化工新型材料, 2018, 46(8): 119-122.
	CAI T T, LIU R W, WANG Y Y, et al. Preparation and electrochemical performance test of nickel cobalt sulfide/carbon microsphere electrode[J]. New Chemical Materials, 2018, 46(8): 119-122.

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三维孔道NiMn-MOF电极材料制备及电化学性能研究

Preparation and electrochemical properties of NiMn-MOF with 3D pore network electrode materials

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