储能科学与技术 ›› 2024, Vol. 13 ›› Issue (3): 1096-1105.doi: 10.19799/j.cnki.2095-4239.2023.0468

• 储能专利 • 上一篇    下一篇

有机无机复合锂离子电池固态电解质专利分析

孙明明()   

  1. 国家知识产权局专利局专利审查协作天津中心, 天津 300304, China
  • 收稿日期:2023-07-06 修回日期:2023-07-21 出版日期:2024-03-28 发布日期:2024-03-28
  • 作者简介:孙明明(1984—),女,硕士,副研究员,研究方向为材料领域专利审查,E-mail:sunmingming0228@163.com

Patent analysis of organic-inorganic composite solid-state electrolytes for lithium-ion batteries

Mingming SUN()   

  1. Patent Exanmination Cooperation(Tianjin) Center of the Patent Office, CNIPA, Tianjin 300304, China
  • Received:2023-07-06 Revised:2023-07-21 Online:2024-03-28 Published:2024-03-28

摘要:

随着新能源汽车产业的飞速发展,传统液态电解质已经不能满足市场需求,固态电解质因其安全和能量密度优势已经成为未来发展的理想方向。然而由于无机电解质界面性能差和聚合物电解质材料离子电导率低的固有缺陷,严重阻碍了其实际应用,兼具无机电解质离子电导率高、力学性能好以及有机电解质柔韧性好且不与锂金属反应的复合体系固态电解质已经成为当前研究热点。为了解有机无机复合锂离子电池固态电解质发展态势,本文基于智慧芽Patsnap专利数据库检索结果,总结了全球及中国专利申请数量变化趋势和法律状态,对比了专利主要来源国和主要申请人情况,梳理了技术手段和技术效果之间的关系,重点从有机、无机、添加剂等材料组成,物理共混、三维、多层等复合方式以及特定制备工艺三个维度总结分析了专利技术发展情况。研究发现,我国在有机无机复合锂离子电池固态电解质专利布局方面具有数量优势,但目前申请人较为分散,且技术保护更多限于材料本身,建议加强合作交流,以及对上下游产业的整体技术保护,技术发展方向方面,高无机相用量的三维复合体系具有更佳的综合性能,但从产业化角度,聚合物填充无机颗粒体系可能发展得更快。

关键词: 锂离子电池, 有机无机复合, 固态电解质, 专利

Abstract:

Traditional liquid electrolytes fail to meet market demands in the rapidly advancing new energy vehicle industry. Solid electrolytes, boasting safety and energy density advantages, are the focus of future development. However, practical applications are hindered by inherent issues such as the poor interface performance of inorganic electrolytes and the low ion conductivity of polymer electrolyte materials. To address this, researchers have concentrated on composite solid electrolytes. These aim to combine the high ion conductivity and excellent mechanical properties of inorganic electrolytes with the flexibility of organic electrolytes that do not react with lithium metals. This study examines solid-state electrolyte trends for organic-inorganic composite lithium-ion batteries. It analyzes global and Chinese patent applications using Patsnap's database, comparing primary source countries and applicant status. The correlation between technical means and effects is also established. Patented technologies are analyzed across three dimensions: material composition (organic, inorganic, and additive), composite methods (physical blending, three-dimensional and multilayer composites), and specific preparation processes. The analysis indicates China's quantitative advantage in organic-inorganic composite solid-state electrolytes. However, applicants are dispersed, and technical protection mainly focuses on materials. Collaboration is recommended for comprehensive technical protection in upstream and downstream industries. Regarding technological direction, three-dimensional composite systems with a high inorganic phase content exhibit superior comprehensive performance. Moreover, from an industrialization perspective, polymer-filled inorganic particle systems may develop faster.

Key words: lithium-ion batteries, organic-inorganic composite, solid-state electrolyte, patent

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