锂电池用参比电极的设计与应用

doi:10.19799/j.cnki.2095-4239.2023.0638

摘要/Abstract

摘要：

参比电极对于解析高安全、高性能锂电池内部物理化学过程具有重要意义。然而在科学研究及产品开发中，可靠参比电极的实际构建和集成仍具有挑战性。本文首先阐明锂电池用参比电极的原理和特性，进而梳理基本设计参数，包括活性材料选择、几何尺寸、制备工艺和检测设置。然后介绍了引入参比电极的三电极体系在锂电池工作/失效机制分析方面的应用实例。最后展望了开发和部署锂电池用参比电极的挑战和发展方向。

关键词: 参比电极, 锂离子电池, 锂金属电池, 电极电势, 电化学阻抗谱

Abstract:

The significance of a reference electrode in elucidating internal physical and chemical processes in high-safety, high-performance lithium batteries cannot be overstated. Despite this importance, constructing and integrating a reliable reference electrode remains a challenge in academic research and product development. In this study, we explore the fundamental principles and characteristics of reference electrodes for lithium batteries. In addition, we outline key design parameters, including the selection of active materials, geometric dimensions, manufacturing processes, and detection setups. Furthermore, we present the application of a three-electrode system that integrates the reference electrode to analyze the working and failure mechanisms of lithium batteries. This approach enhances our understanding of the complex electrochemical processes within the battery system. In conclusion, we discuss the challenges associated with developing and deploying reference electrodes for lithium batteries, along with prospective directions for future research and implementation.

Key words: reference electrode, lithium-ion battery, lithium metal battery, electrode potential, electrochemical impedance spectroscopy

中图分类号:

TM 911

肖也, 徐磊, 闫崇, 黄佳琦. 锂电池用参比电极的设计与应用[J]. 储能科学与技术, 2024, 13(1): 82-91.

Ye XIAO, Lei XU, Chong YAN, Jiaqi HUANG. Design and application of reference electrodes for lithium batteries[J]. Energy Storage Science and Technology, 2024, 13(1): 82-91.

图/表 4

参考文献 102

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