• XXXX •
钟国彬1(), 姚鑫2, 刘永超2, 侯倩2, 项宏发2()
收稿日期:
2023-12-29
修回日期:
2024-03-23
通讯作者:
项宏发
E-mail:zhongguobin001@163.com;hfxiang@hfut.edu.cn
作者简介:
钟国彬(1984—),男,材料学博士,正高级工程师,从事电化学储能技术研究。E-mail:zhongguobin001@163.com;
基金资助:
Guobin Zhong1(), Xin Yao2, Yongchao Liu2, Qian Hou2, Hongfa Xiang2()
Received:
2023-12-29
Revised:
2024-03-23
Contact:
Hongfa Xiang
E-mail:zhongguobin001@163.com;hfxiang@hfut.edu.cn
摘要:
隔膜作为锂电池的重要结构组成部分,起阻隔正负极接触、吸收并固定电解液、传递离子等关键作用。锂电池用商用隔膜面临高温热收缩等问题,影响电池的持久安全性。本文首先简要介绍了锂离子电池隔膜在孔隙结构、电解液润湿性、结构/热/化学/电化学稳定性以及隔膜-电解液相互作用等方面的要求,并通过对近期相关文献的探讨,重点综述了耐高温聚合物隔膜的研究进展;重点分析了高耐热聚合物基隔膜、阻燃添加剂涂敷隔膜和聚合物基底复合等策略对于阻燃多功能复合隔膜的改善机制;对于复合隔膜的锂枝晶抑制策略,主要介绍了物理阻隔锂枝晶生长、均匀化锂枝晶和调控锂离子迁移通量三种方法。综合分析表明,通过减薄聚烯烃隔膜同时引入高性能薄涂层、掺杂固态电解质、开发高耐热聚合物基底隔膜等策略,有望在实现高安全性的同时获得高离子电导率。
中图分类号:
钟国彬, 姚鑫, 刘永超, 侯倩, 项宏发. 锂离子电池高安全复合隔膜的挑战和未来展望[J]. 储能科学与技术, doi: 10.19799/j.cnki.2095-4239.2023.0961.
Guobin Zhong, Xin Yao, Yongchao Liu, Qian Hou, Hongfa Xiang. Challenges and prospects of high-safety composite separators for lithium-ion batteries[J]. Energy Storage Science and Technology, doi: 10.19799/j.cnki.2095-4239.2023.0961.
1 | XU J, CAI X, CAI S, SHAO Y, HU C, LU S, et al. High‐energy lithium‐ion batteries: Recent progress and a promising future in applications [J]. Energy & Environmental Materials, 2023, 0: e12450. |
2 | 韩雨,曹盛玲,宁靖,王康丽,蒋凯,周敏. 聚合物改性锂金属电池界面策略研究 [J]. 储能科学与技术, 2023, 12(08):2491-2503. HAN Y, CAO S L, Ning J, Wang K L, Jiang K, Zhou M. Research on interfacial strategy of polymer-modified lithium-metal batteries [J]. Energy Storage Science and Technology, 2023, 12(08):2491-2503. |
3 | 杲齐新,赵景腾,李国兴. 锂离子电池快速充电研究进展 [J]. 储能科学与技术, 2023, 12(07):2166-2184. GAO Q X, ZHAO J T, Li G X. Advances in rapid charging of lithium-ion batteries [J]. Energy Storage Science and Technology, 2023, 12(07):2166-2184. |
4 | WU S, ZHANG X, WANG R, LI T. Progress and perspectives of liquid metal batteries [J]. Energy Storage Materials, 2023, 57: 205-227. |
5 | XU J, ZHANG J, POLLARD T P, LI Q, TAN S, HOU S, et al. Electrolyte design for Li-ion batteries under extreme operating conditions [J]. Nature, 2023, 614: 694–700. |
6 | WANG J, YANG K, SUN S, MA Q, YI G, CHEN X, et al. Advances in thermal‐related analysis techniques for solid‐state lithium batteries [J]. InfoMat, 2023. |
7 | 王怡,陈学兵,王愿习,郑杰允,刘啸嵩,李泓. 储能锂离子电池多层级失效机理及分析技术综述 [J]. 储能科学与技术, 2023, 12(07):2079-2094. WANG Y, CHEN X B, WANG W X, ZHENG J Y, LIU X S, LI H. A review of multilevel failure mechanisms and analysis techniques for lithium-ion batteries for energy storage [J]. Energy Storage Science and Technology, 2023, 12(07):2079-2094. |
8 | YUN F, LIU S, GAO M, BI X, ZHAO W, CHANG Z, et al. Investigation on step overcharge to self-heating behavior and mechanism analysis of lithium ion batteries [J]. Journal of Energy Chemistry, 2023, 79: 301-311. |
9 | OSMANI K, ALKHEDHER M, RAMADAN M, CHOI D S, LI L K B, Doranehgard M H, et al. Recent progress in the thermal management of lithium-ion batteries [J]. Journal of Cleaner Production, 2023, 389. |
10 | LIU Z F, JIANG Y J, HU Q M, GUO S T, YU L, LI Q, et al. Safer lithium-ion batteries from the separator aspect: development and future perspectives [J]. Energy & Environmental Materials, 2021, 4(3): 336-362. |
11 | 周伟东,黄秋,谢晓新,陈科君,李薇,邱介山. 固态锂电池聚合物电解质研究进展 [J]. 储能科学与技术, 2022, 11(06):1788-1805. ZHOU W D, HUANG Q, XIE X X, CHEN K J, LI W QIU J S. Advances in polymer electrolytes for solid-state lithium batteries [J]. Energy Storage Science and Technology, 2022, 11(06):1788-1805. |
12 | YANG Y F, WANG W K, MENG G L, ZHANG J P. Function-directed design of battery separators based on microporous polyolefin membranes [J]. Journal of Materials Chemistry A, 2022, 10(27): 14137-11470. |
13 | 沈馨,张睿,赵辰孜,武鹏,张羽彤,张俊东,范丽珍,刘全兵,陈爱兵,张强. 金属锂电池中力-电化学机制研究进展 [J]. 储能科学与技术, 2022, 11(09):2781-2797. SHEN X, ZHANG R, ZHAO C Z, WU P, ZHANG Y T, ZHANG J D, FAN L Z, LIU Q B, CHEN A B, ZHANG Q. Progress of force-electrochemical mechanism in lithium metal batteries [J]. Energy Storage Science and Technology, 2022, 11(09):2781-2797. |
14 | SU M M, HUANG G, WANG S Q, WANG Y J, WANG H H. High safety separators for rechargeable lithium batteries [J]. Science China-Chemistry, 2021, 64(7): 1131-1156. |
15 | SONG X H, YAO X, ZHANG F, ANG E H, RONG S G, ZHAO K, et al. Nanofiber membrane coated with lithiophilic polydopamine for lithium metal batteries [J]. Journal of Membrane Science, 2023, 685121951. |
16 | LI J Y, ZHANG Y Z, SHANG R, CHENG C, CHENG Y, XING J X, et al. Recent advances in lithium-ion battery separators with reversible/irreversible thermal shutdown capability [J]. Energy Storage Materials, 2021, 43: 143-157. |
17 | MA J, WU Y Y, JIANG H, YAO X, ZHANG F, HOU X L, et al. In Situ Directional Polymerization of Poly(1,3-dioxolane) Solid Electrolyte Induced by Cellulose Paper-Based Composite Separator for Lithium Metal Batteries [J]. Energy Storage Materials, 2023, 6(3): e12370. |
18 | LI J H, CAI Y F, WU H M, YU Z, YAN X Z, ZHANG Q H, et al. Polymers in lithium-ion and lithium metal batteries [J]. Advanced Energy Materials, 2021, 11(15): 2003239. |
19 | GEBERT F, KNOTT J, GORIN R, CHOU S L, DOU S X. Polymer electrolytes for sodium-ion batteries [J]. Energy Storage Materials, 2021, 36: 10-30. |
20 | LIN W, WANG F, WANG H, LI H, FAN Y, CHAN D, et al. Thermal-stable separators: Design principles and strategies towards safe lithium-ion battery operations [J]. ChemSusChem, 2022, 15: e202201464. |
21 | 邵素霞,朱振东,彭文,代娟,吴浩. 充放电过程液相锂离子浓度变化及机理研究 [J]. 储能科学与技术, 2021, 10(03):1187-1195. SHAO S X, ZHU Z D, PENG W, DAI J, WU H. Liquid-phase lithium ion concentration change and mechanism during charging and discharging [J]. Energy Storage Science and Technology, 2021, 10(03):1187-1195. |
22 | 刘如亮,高兴远,尹伟,杨乃涛. PVDF-HFP基凝胶固态电解质的合成与锂离子电池性能 [J]. 储能科学与技术, 2021, 10(06):2077-2081. LIU R L, XING G Y, YIN W, YANG N T. Synthesis of PVDF-HFP-based gel solid electrolyte and performance of lithium-ion battery [J]. Energy Storage Science and Technology, 2021, 10(06):2077-2081. |
23 | YUAN B, WEN K, CHEN D, LIU Y, DONG Y, FENG C, et al. Composite separators for robust high rate lithium ion batteries [J]. Advanced Functional Materials, 2021, 31(32): 2101420. |
24 | GAO X, SHENG L, YANG L, XIE X, LI D, GONG Y, et al. High-stability core-shell structured PAN/PVDF nanofiber separator with excellent lithium-ion transport property for lithium-based battery [J]. Journal of Colloid and Interface Science, 2023, 636: 317-327. |
25 | 安平. 聚酰亚胺锂离子电池隔膜的制备及其性能研究 [D]. 2015. AN P. Preparation of polyimide lithium-ion battery diaphragm and its performance research [D]. 2015. |
26 | KONG L Y, YAN Y R, QIU Z M, ZHOU Z Q, HU J Q. Robust fluorinated polyimide nanofibers membrane for high-performance lithium-ion batteries [J]. Journal of Membrane Science, 2018, 549: 321-331. |
27 | WU D, DONG N, WANG R, QI S, LIU B, WU D. In situ construction of high-safety and non-flammable polyimide "ceramic" lithium-ion battery separator via SiO2 nano-encapsulation [J]. Chemical Engineering Journal, 2021, 420: 129992. |
28 | WANG Y, YIN C Q, SONG Z L, WANG Q L, LAN Y, LUO J P, et al. Application of PVDF organic particles coating on polyethylene separator for lithium ion batteries [J]. Materials, 2019, 12(19). |
29 | MOHAMMADI, BARTER L D. J., STOLOJAN V, CREAM C, SLADE R C. T. Electrospun polar-nanofiber pvdf separator for lithium–sulfur batteries with enhanced charge storage capacity and cycling durability [J]. Energy Advances, 2024. |
30 | RYU J, HAN D Y, HONG D, PARK S. A polymeric separator membrane with chemoresistance and high Li-ion flux for high-energy-density lithium metal batteries [J]. Energy Storage Materials, 2022, 45: 941-951. |
31 | RYOU M H, LEE D J, LEE J N, LEE Y M, PARKJ K, CHOI J W. Excellent cycle life of lithium-metal anodes in lithium-ion batteries with mussel-inspired polydopamine-coated separators [J]. Advanced Energy Materials, 2012, 2(6): 645-650. |
32 | RYOU M H, LEE Y M, PARK J K, CHOI J W. Mussel-inspired polydopamine-treated polyethylene separators for high-power li-ion batteries [J]. Advanced Materials, 2011, 23(27): 3066-3070. |
33 | LI M N, ZHANG Z J, YIN Y T, GUO W C, BAI Y G, ZHANG F, et al. Novel polyimide separator prepared with two porogens for safe lithium-ion batteries [J]. ACS Applied Materials & Interfaces, 2019, 12(3) : 3610-3616. |
34 | KANG S H, JANG J K, JEONG H Y, SO S, HONG S K, HONG Y T, et al. Polyacrylonitrile/phosphazene composite-based heat-resistant and flame-retardant separators for safe lithium-ion batteries [J]. ACS Applied Energy Materials, 2022, 5(2) : 2452-2461. |
35 | MENG F H, GAO J H, ZHANG M D, LI D W, LIU X Z. Enhanced safety performance of automotive lithium‐ion batteries with Al2O3‐coated non‐woven separator [J]. Batteries & Supercaps, 2020, 4(1) : 146-151. |
36 | SHI K, XU Z J, ZHENG D W, YANG Z H, ZHANG W X. Sandwich-like solid composite electrolytes employed as bifunctional separators for safe lithium metal batteries with excellent cycling performance [J]. Journal of Materials Chemistry A, 2022, 10(9): 4660-4670. |
37 | 刘卿. 溴系阻燃剂应用情况分析及展望 [J]. 天津化工, 2020, 34(04):3-5. LIU Q. Application analysis and prospect of brominated flame retardants [J]. Tianjin Chemical Industry, 2020, 34(04):3-5. |
38 | CHOU L Y, YE Y, LEE H K, HUANG W, XU R, GAO X, et al. Electrolyte-resistant dual materials for the synergistic safety enhancement of lithium-ion batteries [J]. Nano Lett, 2021, 21(5): 2074-2080. |
39 | 汤维. 聚丙烯材料无卤阻燃改性研究进展 [J]. 中国塑料, 2021, 35(01):136-149. TANG W. Research progress on halogen-free flame retardant modification of polypropylene materials [J]. China Plastics, 2021, 35(01):136-149. |
40 | LIAO C, MU X, HAN L, LI Z, ZHU Y, LU J, et al. A flame-retardant, high ionic-conductivity and eco-friendly separator prepared by papermaking method for high-performance and superior safety lithium-ion batteries [J]. Energy Storage Materials, 2022, 48: 123-132. |
41 | YEON D Y, LEE Y J, RYOU M H, LEE Y M. New flame-retardant composite separators based on metal hydroxides for lithium-ion batteries [J]. Electrochimica Acta, 2015, 157: 282-289. |
42 | STALIN S, CHODHURY S, ZHANG K H, ARCHER L A. Multifunctional cross-linked polymeric membranes for safe, high-performance lithium batteries [J]. Chemistry of Materials, 2018, 30(6) : 2058-2066. |
43 | YU B C, PARK K, JANG J H, GOODENOUGH J B. Cellulose-Based Porous Membrane for Suppressing Li Dendrite Formation in Lithium–Sulfur Battery [J]. ACS Energy Letters, 2016, 1(3): 633-637. |
44 | ZHAO Q, WANG R, HU X, WANG Y, LU G, YANG Z, et al. Functionalized 12 μm polyethylene separator to realize dendrite-free lithium deposition toward highly stable lithium-metal batteries [J]. Advanced Science, 2022, 9(13): e2102215. |
45 | LIANG J, CHEN Q, LIAO X, YAO P, ZHU B, LV G, et al. A nano-shield design for separators to resist dendrite formation in lithium-metal batteries [J]. Angewandte Chemie International Edition, 2020, 59(16): 6561-6566. |
46 | GUO Y, WU Q, LIU L W, LI G H, YANG L J, WANG X Z, et al. Thermally conductive aln-network shield for separators to achieve dendrite-free plating and fast Li-ion transport toward durable and high-rate lithium-metal anodes [J]. 2022, 9(18) : 2200411. |
47 | CHO J, SIN W K, G K A, KIN D W. Ultrathin coating of nitrogen and sulfur co-doped graphene nanosheets on polymer separator for suppressing dendritic lithium growth in lithium metal batteries [J]. ECS Meeting Abstracts, 2016, MA2016-03(2) : 1028. |
48 | CHEN X, ZHANG R Y, ZHAO R R, QI X Q, LIK J, SUN Q, et al. A "dendrite-eating" separator for high-areal-capacity lithium-metal batteries [J]. 2020, 31: 181-186. |
49 | HAO X, ZHU J, JIANG X, WU H, QIAO J, SUN W, et al. Ultrastrong polyoxyzole nanofiber membranes for dendrite-proof and heat-resistant battery separators [J]. Nano Lett, 2016, 16(5): 2981-2987. |
50 | JI Y, YUAN B, ZHANG J, LIU Z, ZHONG S, LIU J, et al. A single‐layer piezoelectric composite separator for durable operation of Li metal anode at high rates [J]. Energy & Environmental Materials, 2022, 0: e12510. |
51 | ZHANG Y C, WANG Z H, XIANG H F, SHI P C, WANG H H. A thin inorganic composite separator for lithium-ion batteries [J]. Journal of Membrane Science, 509 (2016) 19-26. |
52 | YAN J, LIU F Q, GAO J, ZHOU W, HUO H, ZHOU J J, et al. Low‐cost regulating lithium deposition behaviors by transition metal oxide coating on separator [J]. Advanced Functional Materials, 2021, 31(16): 2007255. |
53 | ZHANG XJ, ZHOU L, HU K P, GAO D D, TANG S, HE L, et al. Uniform lithium deposition regulated by lithiophilic Mo3N2/mon heterojunction nanobelts interlayer for stable lithium metal batteries [J]. 2023, 476: 146612. |
54 | DING L Y, YYE X Y, ZHANG X H, CHEN Y M, LIU J J, SHI Z Q, et al. A polyimine aerogel separator with electron cloud design to boost Li-ion transport for stable Li metal batteries [J]. 2023, 120(51) : e2314264120. |
55 | JIANG Z, WANG S, CHEN X, YANG W, YAO X, HU X, et al. Tape-casting Li0.34La0.56TiO3 ceramic electrolyte films permit high energy density of lithium-metal batteries [J]. Advanced Materials, 2020, 32(6): e1906221. |
56 | WANG L J, WANG Z H, SUN Y, LIANG X, XIANG H F. Sb2O3 modified PVDF-CTFE electrospun fibrous membrane as a safe lithium ion battery separator [J]. Journal of Membrane Science 572 (2019) 512–519. |
57 | ZHONG G B, WANG Y, WANG C, WANG Z H, GUO S, WANG L J, et al. An AlOOH-coated polyimide electrospun fibrous membrane as a high-safety lithium-ion battery separator [J]. Ionics, 25 (2019) 2677–2684. |
58 | YANG J, WANG C Y, WANG C C, CHEN K H, MOU C Y, WU H L. Advanced nanoporous separators for stable lithium metal electrodeposition at ultra-high current densities in liquid electrolytes [J]. Journal of Materials Chemistry A, 2020, 8(10): 5095-5104. |
59 | TAN L W, SUN Y, WEI C L, TAO Y, TIAN Y, AN Y L, et al. Design of robust, lithiophilic, and flexible inorganic-polymer protective layer by separator engineering enables dendrite-free lithium metal batteries with LiNi0.8Mn0.1Co0.1O2 cathode [J]. 2021, 17(13) : 2007717. |
60 | LIN G, JIA K, BAI Z X, LIU C C, LIU S N, HUANG Y M, et al. Metal‐organic framework sandwiching porous super‐engineering polymeric membranes as anionphilic separators for dendrite‐free lithium metal batteries [J]. Advanced Functional Materials, 2022. |
[1] | 申小雨, 尹丛勃. 基于卷积Fastformer的锂离子电池健康状态估计[J]. 储能科学与技术, 2024, 13(3): 990-999. |
[2] | 胡大林, 任潘利, 张昌明, 杨明阳, 卢周广. Al-Y-Zr原位共掺杂提高4.53 V钴酸锂正极材料的循环性能[J]. 储能科学与技术, 2024, 13(3): 742-748. |
[3] | 张稚国, 李华清, 王莉, 何向明. 锂离子电池塑料-金属复合集流体的特性及制备研究进展[J]. 储能科学与技术, 2024, 13(3): 749-758. |
[4] | 刘剑, 于立博, 吴振兴, 牟介刚. 基于风冷的锂离子电池充放电设备热特性影响研究[J]. 储能科学与技术, 2024, 13(3): 914-923. |
[5] | 武美玲, 牛磊, 李世友, 赵冬妮. 正极预锂化添加剂用于锂离子电池的研究进展[J]. 储能科学与技术, 2024, 13(3): 759-769. |
[6] | 孙明明. 有机无机复合锂离子电池固态电解质专利分析[J]. 储能科学与技术, 2024, 13(3): 1096-1105. |
[7] | 宋元明, 刘亚杰, 金光, 周星, 黄旭程. 锂离子电池/超级电容器混合储能系统能量管理方法综述[J]. 储能科学与技术, 2024, 13(2): 652-668. |
[8] | 李校磊, 高健, 周伟东, 李泓. COMSOL Multiphysics在锂离子电池中的应用[J]. 储能科学与技术, 2024, 13(2): 546-567. |
[9] | 彭可, 张志成, 胡有章, 张旭辉, 周稼辉, 李彬. 基于有限元的热力耦合场匣钵运动分析与优化[J]. 储能科学与技术, 2024, 13(2): 634-642. |
[10] | 雷旗开, 余胤, 彭鹏, 陈满, 金凯强, 王青松. 隔热材料布局方式对280 Ah磷酸铁锂电池热失控传播抑制效果的影响[J]. 储能科学与技术, 2024, 13(2): 495-502. |
[11] | 李珂, 郝奕帆, 方振华, 王静, 张松通, 祝夏雨, 邱景义, 明海. 高功率化学电源体系发展及军事应用分析[J]. 储能科学与技术, 2024, 13(2): 436-461. |
[12] | 段双明, 张胜利. 基于自适应多层RLS的锂离子电池参数辨识[J]. 储能科学与技术, 2024, 13(2): 712-720. |
[13] | 杜文, 王君雷, 徐运飞, 李世龙, 王昆. 火焰喷雾热解法生产锂离子电池高镍三元正极材料的技术经济分析[J]. 储能科学与技术, 2024, 13(1): 345-357. |
[14] | 梁宏毅, 陈锋, 甘友毅, 邵丹. 动力锂电池三元正极低温性能研究[J]. 储能科学与技术, 2024, 13(1): 293-298. |
[15] | 肖也, 徐磊, 闫崇, 黄佳琦. 锂电池用参比电极的设计与应用[J]. 储能科学与技术, 2024, 13(1): 82-91. |
阅读次数 | ||||||
全文 |
|
|||||
摘要 |
|
|||||