锂离子电池电解液痕量水污染的超声表象

doi:10.19799/j.cnki.2095-4239.2022.0599

储能科学与技术 ›› 2022, Vol. 11 ›› Issue (12): 4030-4037.doi: 10.19799/j.cnki.2095-4239.2022.0599

锂离子电池电解液痕量水污染的超声表象

谢宏¹(), 黄锴², 杜进桥¹, 韩艳², 沈越²()

^1.深圳供电局有限公司，广东深圳 518000
^2.华中科技大学材料科学与工程学院，湖北武汉 430074

收稿日期:2022-10-18 修回日期:2022-10-31 出版日期:2022-12-05 发布日期:2022-12-29
通讯作者: 沈越 E-mail:xiehong@sz.csg.cn;shenyue1213@hust.edu.cn
作者简介:谢宏（1967—），男，高级工程师，研究方向为中低压配电网规划、电网储能技术，E-mail：xiehong@sz.csg.cn；
基金资助:
南方电网重点科技项目(090000KK52220011)

Studies on ultrasonic appearance of trace water contamination in lithium-ion battery electrolyte

Hong XIE¹(), Kai HUANG², Jinqiao DU¹, Yan HAN², Yue SHEN²()

^1.Shenzhen Power Supply Co. , Ltd. , Shenzhen 518000, Guangdong, China
^2.School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, Hubei, China

Received:2022-10-18 Revised:2022-10-31 Online:2022-12-05 Published:2022-12-29
Contact: Yue SHEN E-mail:xiehong@sz.csg.cn;shenyue1213@hust.edu.cn

摘要/Abstract

摘要：

锂离子电池电解液痕量水污染是导致电池产气和快速失效的重要原因，而过去对痕量水污染电芯缺乏无损检测分析技术。本工作基于超声无损成像技术对微量产气副反应的敏感性，对不同水含量电解液商用NCM523/AG软包电池化成、静置、循环过程中的产气行为进行了超声透射扫描成像，并结合EIS/SEM和充放电特性对其老化和失效机制进行了分析。结果表明痕量水的存在会造成电解液的损耗，加速气体生成，增加界面阻抗和极化电压，造成库仑效率降低和可逆容量衰减，加快电池失效过程。本研究对电池生产过程质量控制以及使用过程的失效机理分析具有指导意义。

关键词: 超声无损成像, 痕量水, 锂离子电池

Abstract:

Trace water contamination in the electrolyte is an important cause for gassing and rapid failure of lithium-ion batteries. However, there is lack of nondestructive techniques to detect trace water in cells. In this study, based on the sensitivity of ultrasonic nondestructive imaging technique to trace gassing side reactions, ultrasonic transmission scanning imaging was performed to analyze the gassing behavior of commercial NCM523/AG pouch cells with different water contents during formation, storing, and cycling. Using electrochemical impedance spectroscopy, scanning electronic microscopy, and charge/discharge characterization, the aging and failure mechanisms were analyzed. The results show that the presence of trace water causes consumption of electrolyte, accelerates gas generation, and increases interfacial impedance and polarization voltage. These characteristics can further cause the reduction of coulomb efficiency and capacity decay, thus accelerating battery failure. This study has guiding significance for quality control in the battery production process and failure mechanism analysis during battery usage.

Key words: ultrasonic nondestructive imaging, trace water, lithium-ion battery

中图分类号:

TK 02

谢宏, 黄锴, 杜进桥, 韩艳, 沈越. 锂离子电池电解液痕量水污染的超声表象[J]. 储能科学与技术, 2022, 11(12): 4030-4037.

Hong XIE, Kai HUANG, Jinqiao DU, Yan HAN, Yue SHEN. Studies on ultrasonic appearance of trace water contamination in lithium-ion battery electrolyte[J]. Energy Storage Science and Technology, 2022, 11(12): 4030-4037.

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参考文献 14

1	WANG Q S, JIANG L H, YU Y, et al. Progress of enhancing the safety of lithium ion battery from the electrolyte aspect[J]. Nano Energy, 2019, 55: 93-114.
2	FAN X, WANG C. High-voltage liquid electrolytes for Li batteries: Progress and perspectives[J]. Chemical Society Reviews, 2021, 50(8):10486-10566.
3	CHEN Z, LIU C, SUN G, et al. Electrochemical degradation mechanism and thermal behaviors of the stored LiNi_0.5Co_0.2Mn_0.3O₂ cathode materials[J]. ACS Applied Materials & Interfaces, 2018, 10(30): 25454-25464.
4	HEIDER U, OESTEN R, JUNGNITZ M. Challenge in manufacturing electrolyte solutions for lithium and lithium ion batteries quality control and minimizing contamination level[J]. Journal of Power Sources, 1999, 81/82: 119-122.
5	AURBACH D, WEISSMAN I, ZABAN A, et al. On the role of water contamination in rechargeable Li batteries[J]. Electrochimica Acta, 1999, 45(7): 1135-1140.
6	杨春巍, 吴伯荣, 吴锋, 等. 量子化学方法在锂离子电池电解液研究中的应用[J]. 化学通报, 2010, 73(10): 868-871.
	YANG C W, WU B R, WU F, et al. Application of quantum chemistry method in study of Li-ion battery electrolyte[J]. Chemistry, 2010, 73(10): 868-871.
7	邓哲, 黄震宇, 刘磊, 等. 超声技术在锂离子电池表征中的应用[J]. 储能科学与技术, 2019, 8(6): 1033-1039.
	DENG Z, HUANG Z Y, LIU L, et al. Applications of ultrasound technique in characterization of lithium-ion batteries[J]. Energy Storage Science and Technology, 2019, 8(6): 1033-1039.
8	DENG Z, HUANG Z Y, SHEN Y, et al. Ultrasonic scanning to observe wetting and “unwetting” in Li-ion pouch cells[J]. Joule, 2020, 4(9): 2017-2029.
9	HUO H Y, HUANG K, LUO W, et al. Evaluating interfacial stability in solid-state pouch cells via ultrasonic imaging[J]. ACS Energy Letters, 2022, 7(2): 650-658.
10	DENG Z, LIN X, HUANG Z Y, et al. Imaging techniques: Recent progress on advanced imaging techniques for lithium-ion batteries[J]. Advanced Energy Materials, 2021, 11(2): doi:10.1002/aenm. 20200 0806.
11	GUMMOW R J, THACKERAY M M. An investigation of spinel-related and orthorhombic LiMnO₂ cathodes for rechargeable lithium batteries[J]. Journal of the Electrochemical Society, 1994, 141(5): 1178-1182.
12	ZHUANG G V, ROSS P N. Analysis of the chemical composition of the passive film on Li-ion battery anodes using attentuated total reflection infrared spectroscopy[J]. Electrochemical and Solid-State Letters, 2003, 6(7): A136.
13	AURBACH D. Review of selected electrode-solution interactions which determine the performance of Li and Li ion batteries[J]. Journal of Power Sources, 2000, 89(2): 206-218.
14	XU K, VON C A. Interfacing electrolytes with electrodes in Li ion batteries[J]. Journal of Materials Chemistry, 2011, 21(27): 9849.

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锂离子电池电解液痕量水污染的超声表象

Studies on ultrasonic appearance of trace water contamination in lithium-ion battery electrolyte

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