Properties of three-dimensional NZSPO/PAN-［PEO-NATFST］ sodium-battery-composite solid electrolyte

doi:10.19799/j.cnki.2095-4239.2021.0045

Abstract

Abstract:

The fast ionic conductive inorganic particles of Na₃Zr₂Si₂PO₁₂ (NZSPO) were introduced into polypropylene fine (PAN) nanofibers and used to form the three-dimensional fiber network-reinforced bicontinuous solid electrolyte composites of NZSPO/PAN-[PEO-NaTFST] via the electrospinning method. When the mass ration of NZSPO∶PAN was regulated at 2∶1, a maximum ionic conductivity at room temperature arrived at 3.38×10^-5 s/cm, and its electrochemical stability window can be expanded to 4.4 V. Na₃V₂(PO₄)₃ and metal Na were adopted as the cathode and anode to assemble an all solid-state sodium-on battery. The reversible capacity of the first cycle was 109.7 mA·h·g^-1, which can be maintained at 84.5 mA·h·g^-1 after 200 cycles with a high coulomb efficiency near 100% at 0.1 C. Differential scanning calorimetry curves confirmed that the NZSPO-PAN composite fiber can inhibit the crystallization of PEO polymer and accelerate the process of ion transport kinetics at low temperatures.

Key words: composite solid electrolyte, electrochemical performance, sodium ion battery, NZSPO/PAN-[PEO-NaTFST]

CLC Number:

TM 912

Dangling LIU, Shimin WANG, Zhihui GAO, Lufu XU, Shubiao XIA, Hong GUO. Properties of three-dimensional NZSPO/PAN-［PEO-NATFST］ sodium-battery-composite solid electrolyte[J]. Energy Storage Science and Technology, 2021, 10(3): 931-937.

Figures/Tables 8

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