Visualization analysis of composite electrolytes for lithium battery based on CiteSpace

doi:10.19799/j.cnki.2095-4239.2022.0120

Abstract

Abstract:

A solid electrolyte is an ideal electrolyte material with high energy density, high capacity, and high safety. Inorganic solid electrolytes have high ionic conductivity and mechanical properties; however, they exhibit high impedance and poor with contact electrode. Polymer solid electrolytes have good flexibility and machinability; however, their ionic conductivity does not satisfy application requirements. Organic-inorganic composite electrolytes possess the advantages of inorganic and polymer solid electrolytes; thus, these materials are suitable for a wide range of applications. However, the ionic conductivity and electrochemical stability of these materials are not satisfactory. Thus, in this study, we reviewed the last 30 years of literature on organic-inorganic composite electrolytes from the Web of Science Core Collection database. Relevant data were then visualized using CiteSpace. In addition, important nodes in composite electrolyte development process and recent research hotspots were analyzed. The results demonstrate that research interest in composite electrolyte is increasing exponentially. The latest research focuses on the gel state, single-ion conductor structures, and polycarbonate-based materials. Interface is the key to the study of composite electrolytes and has been the most observable key word over the past five years. We found that future development of composite electrolytes should focus on (1) material selection and structure design of semisolid composite electrolyte, (2) interface structures and transport mechanisms between different phases in the electrolyte, and (3) a stable and elastic SEI/CEI film was constructed between an electrolyte and electrode.

Key words: lithium ion battery, composite electrolyte, visual analysis, CiteSpace

CLC Number:

G 353.11

Sida HUO, Wendong XUE, Xinli LI, Yong LI. Visualization analysis of composite electrolytes for lithium battery based on CiteSpace[J]. Energy Storage Science and Technology, 2022, 11(7): 2103-2113.

Figures/Tables 9

Fig. 1

Fig. 2

Fig. 3

Table 1

Fig. 4

Table 2

Fig. 5

Fig. 6

Fig. 7

References 52

1	刘英军, 刘亚奇, 张华良, 等. 我国储能政策分析与建议[J]. 储能科学与技术, 2021, 10(4): 1463-1473.
	LIU Y J, LIU Y Q, ZHANG H L, et al. Energy storage policy analysis and suggestions in China[J]. Energy Storage Science and Technology, 2021, 10(4): 1463-1473.
2	ZHAI H W, XU P Y, NING M Q, et al. A flexible solid composite electrolyte with vertically aligned and connected ion-conducting nanoparticles for lithium batteries[J]. Nano Letters, 2017, 17(5): 3182-3187.
3	许卓, 郑莉莉, 陈兵, 等. 固态电池复合电解质研究综述[J]. 储能科学与技术, 2021, 10(6): 2117-2126.
	XU Z, ZHENG L L, CHEN B, et al. Overview of research on composite electrolytes for solid-state batteries[J]. Energy Storage Science and Technology, 2021, 10(6): 2117-2126.
4	TALEB O, BARZYCKI D C, POLANCO C G, et al. Assessing effective medium theories for conduction through lamellar composites[J]. International Journal of Heat and Mass Transfer, 2022, 188: 122631.
5	BLATT M P, HALLINAN D T. Polymer blend electrolytes for batteries and beyond[J]. Industrial & Engineering Chemistry Research, 2021, 60(48): 17303-17327.
6	GAO H C, GUO B K, SONG J, et al. A composite gel-polymer/glass-fiber electrolyte for sodium-ion batteries[J]. Advanced Energy Materials, 2015, 5(9): 1402235.
7	WIECZOREK W, FLORJANCZYK Z, STEVENS J R. Composite polyether based solid electrolytes[J]. Electrochimica Acta, 1995, 40(13/14): 2251-2258.
8	HALLINAN D T, BALSARA N P. Polymer electrolytes[J]. Annual Review of Materials Research, 2013, 43: 503-525.
9	CHEN C M. CiteSpace II: Detecting and visualizing emerging trends and transient patterns in scientific literature[J]. Journal of the American Society for Information Science and Technology, 2006, 57(3): 359-377.
10	CHEN C M. Searching for intellectual turning points: Progressive knowledge domain visualization[J]. Proceedings of the National Academy of Sciences, 2004, 101(s1): 5303-5310.
11	陈丽萍, 冯金奎, 田园, 等. 基于文献计量学的锂二次电池研究知识图谱分析[J]. 储能科学与技术, 2021, 10(3): 1196-1205.
	CHEN L P, FENG J K, TIAN Y, et al. Knowledge mapping analysis of lithium secondary batteries research based on bibliometrics[J]. Energy Storage Science and Technology, 2021, 10(3): 1196-1205.
12	CHEN C M, SONG M. Visualizing a field of research: A methodology of systematic scientometric reviews[J]. PLoS One, 2019, 14(10): e0223994.
13	胡华坤, 李新丽, 薛文东, 等. 基于CiteSpace的锂离子电池用低温电解液知识图谱分析[J]. 储能科学与技术, 2022, 11(1): 379-396.
	HU H K, LI X L, XUE W D, et al. Knowledge map analysis of a low-temperature electrolyte for lithium-ion battery based on CiteSpace[J]. Energy Storage Science and Technology, 2022, 11(1): 379-396.
14	赵晏强, 李印结, 吴跃伟, 等. 基于文献计量和关键词的锂离子电池正极材料的研究进展[J]. 材料导报, 2014, 28(3): 140-145.
	ZHAO Y Q, LI Y J, WU Y W, et al. Research progress of cathode materials for lithium-ion battery based on literature metrology and keywords[J]. Materials Review, 2014, 28(3): 140-145.
15	SHIRAKAWA H, LOUIS E J, MACDIARMID A G, et al. Synthesis of electrically conducting organic polymers: Halogen derivatives of polyacetylene, (CH) X[J]. Journal of the Chemical Society, Chemical Communications, 1977(16): 578.
16	WRIGHT P V. Developments in polymer electrolytes for lithium batteries[J]. MRS Bulletin, 2002, 27(8): 597-602.
17	WRIGHT P V. Polymer electrolytes—the early days[J]. Electrochimica Acta, 1998, 43(10/11): 1137-1143.
18	FENTON D E, PARKER J M, WRIGHT P V. Complexes of alkali metal ions with poly(ethylene oxide)[J]. Polymer, 1973, 14(11): 589.
19	YAMAMOTO O. Solid oxide fuel cells: Fundamental aspects and prospects[J]. Electrochimica Acta, 2000, 45(15/16): 2423-2435.
20	YANG X G, LIU T, GAO Y, et al. Asymmetric temperature modulation for extreme fast charging of lithium-ion batteries[J]. Joule, 2019, 3(12): 3002-3019.
21	LOPEZ J, MACKANIC D G, CUI Y, et al. Designing polymers for advanced battery chemistries[J]. Nature Reviews Materials, 2019, 4(5): 312-330.
22	TARASCON J M, ARMAND M. Issues and challenges facing rechargeable lithium batteries[J]. Nature, 2001, 414(6861): 359-367.
23	WANG X E, ZHU H J, GREENE G W, et al. Enhancement of ion dynamics in organic ionic plastic crystal/PVDF composite electrolytes prepared by co-electrospinning[J]. Journal of Materials Chemistry A, 2016, 4(25): 9873-9880.
24	ZHOU Y D, WANG X E, ZHU H J, et al. Ternary lithium-salt organic ionic plastic crystal polymer composite electrolytes for high voltage, all-solid-state batteries[J]. Energy Storage Materials, 2018, 15: 407-414.
25	CROCE F, PERSI L, SCROSATI B, et al. Role of the ceramic fillers in enhancing the transport properties of composite polymer electrolytes[J]. Electrochimica Acta, 2001, 46(16): 2457-2461.
26	CROCE F, D' EPIFANIO A, HASSOUN J, et al. A novel concept for the synthesis of an improved LiFePO₄ lithium battery cathode[J]. Electrochemical and Solid-State Letters, 2002, 5(3): A47.
27	ZHOU Y D, WANG X E, ZHU H J, et al. N-ethyl-N-methylpyrrolidinium bis(fluorosulfonyl)imide-electrospun polyvinylidene fluoride composite electrolytes: Characterization and lithium cell studies[J]. Physical Chemistry Chemical Physics, 2017, 19(3): 2225-2234.
28	CROCE F, APPETECCHI G B, PERSI L, et al. Nanocomposite polymer electrolytes for lithium batteries[J]. Nature, 1998, 394(6692): 456-458.
29	ZHONG Y, XIA X H, DENG S J, et al. Popcorn inspired porous macrocellular carbon: Rapid puffing fabrication from rice and its applications in lithium-sulfur batteries[J]. Advanced Energy Materials, 2018, 8(1): 1701110.
30	APPETECCHI G B, CROCE F, PERSI L, et al. Transport and interfacial properties of composite polymer electrolytes[J]. Electrochimica Acta, 2000, 45(8/9): 1481-1490.
31	APPETECCHI G B, SCACCIA S, PASSERINI S. Investigation on the stability of the lithium-polymer electrolyte interface[J]. Journal of the Electrochemical Society, 2000, 147(12): 4448.
32	STEPHAN A M, NAHM K S. Review on composite polymer electrolytes for lithium batteries[J]. Polymer, 2006, 47(16): 5952-5964.
33	STEPHAN A M. Review on gel polymer electrolytes for lithium batteries[J]. European Polymer Journal, 2006, 42(1):21-42.
34	SURIYAKUMAR S, GOPI S, KATHIRESAN M, et al. Metal organic framework laden poly(ethylene oxide) based composite electrolytes for all-solid-state Li-S and Li-metal polymer batteries[J]. Electrochimica Acta, 2018, 285: 355-364.
35	ISMAIL I, NODA A, NISHIMOTO A, et al. XPS study of lithium surface after contact with lithium-salt doped polymer electrolytes[J]. Electrochimica Acta, 2001, 46(10/11): 1595-1603.
36	CHRISTIE A M, LILLEY S J, STAUNTON E, et al. Increasing the conductivity of crystalline polymer electrolytes[J]. Nature, 2005, 433(7021): 50-53.
37	KIMURA K, YAJIMA M, TOMINAGA Y. A highly-concentrated poly(ethylene carbonate)‍-based electrolyte for all-solid-state Li battery working at room temperature[J]. Electrochemistry Communications, 2016, 66: 46-48.
38	TAO X Y, LIU Y Y, LIU W, et al. Solid-state lithium-sulfur batteries operated at 37 ℃ with composites of nanostructured Li₇La₃Zr₂O₁₂/carbon foam and polymer[J]. Nano Letters, 2017, 17(5): 2967-2972.
39	WAN Z P, LEI D N, YANG W, et al. Low resistance-integrated all-solid-state battery achieved by Li₇La₃Zr₂O₁₂ nanowire upgrading polyethylene oxide (PEO) composite electrolyte and PEO cathode binder[J]. Advanced Functional Materials, 2019, 29(1): 1805301.
40	FU K K, GONG Y H, DAI J Q, et al. Flexible, solid-state, ion-conducting membrane with 3D garnet nanofiber networks for lithium batteries[J]. Proceedings of the National Academy of Sciences of the United States of America, 2016, 113(26): 7094-7099.
41	LIU W, LEE S W, LIN D C, et al. Enhancing ionic conductivity in composite polymer electrolytes with well-aligned ceramic nanowires[J]. Nature Energy, 2017, 2: 17035.
42	ZHANG J F, MA C, LIU J T, et al. Solid polymer electrolyte membranes based on organic/inorganic nanocomposites with star-shaped structure for high performance lithium ion battery[J]. Journal of Membrane Science, 2016, 509: 138-148.
43	ONISHI K, MATSUMOTO M, NAKACHO Y, et al. Synthesis of aluminate polymer complexes as single-ionic solid electrolytes[J]. Chemistry of Materials, 1996, 8(2): 469-472.
44	KALITA M, BUKAT M, CIOSEK M, et al. Effect of calixpyrrole in PEO-LiBF₄ polymer electrolytes[J]. Electrochimica Acta, 2005, 50(19): 3942-3948.
45	PLEWA A, CHYLIŃSKI F, KALITA M, et al. Influence of macromolecular additives on transport properties of lithium organic electrolytes[J]. Journal of Power Sources, 2006, 159(1): 431-437.
46	ZHANG J J, ZANG X, WEN H J, et al. High-voltage and free-standing poly(propylene carbonate)/Li_6.75La₃Zr_1.75Ta_0.25O₁₂ composite solid electrolyte for wide temperature range and flexible solid lithium ion battery[J]. Journal of Materials Chemistry A, 2017, 5(10): 4940-4948.
47	ZHANG X K, XIE J, SHI F F, et al. Vertically aligned and continuous nanoscale ceramic-polymer interfaces in composite solid polymer electrolytes for enhanced ionic conductivity[J]. Nano Letters, 2018, 18(6): 3829-3838.
48	HOROWITZ Y, LIFSHITZ M, GREENBAUM A, et al. Review—polymer/ceramic interface barriers: The fundamental challenge for advancing composite solid electrolytes for Li-ion batteries[J]. Journal of the Electrochemical Society, 2020, 167(16): 160514.
49	WANG Y, ZANELOTTI C J, WANG X E, et al. Solid-state rigid-rod polymer composite electrolytes with nanocrystalline lithium ion pathways[J]. Nature Materials, 2021, 20(9): 1255-1263.
50	ZHAO Y R, WU C, PENG G, et al. A new solid polymer electrolyte incorporating Li₁₀GeP₂S₁₂ into a polyethylene oxide matrix for all-solid-state lithium batteries[J]. Journal of Power Sources, 2016, 301: 47-53.
51	CHEN B, HUANG Z, CHEN X T, et al. A new composite solid electrolyte PEO/Li₁₀GeP₂S₁₂/SN for all-solid-state lithium battery[J]. Electrochimica Acta, 2016, 210: 905-914.
52	HUO H Y, CHEN Y, LUO J, et al. Rational design of hierarchical "ceramic-in-polymer" and "polymer-in-ceramic" electrolytes for dendrite-free solid-state batteries[J]. Advanced Energy Materials, 2019, 9(17): 1804004.

研究机构	发文数量	中介中心性
Chinese Acad Sci	176	0.40
Univ Malaya	154	0.20
Univ Chinese Acad Sci	103	0.02
Forschungszentrum Julich	76	0.10
Univ Sulaimani	73	0.01
Tsinghua Univ	68	0.10
Univ Toronto	63	0.06
Huazhong Univ Sci & Technol	61	0.05
Seoul Natl Univ	57	0.08

被引作者	被引频次	中介中心性	主要贡献与研究	近五年研究动态
Armand M	1534	0.04	“摇椅式”电池	全固态电池、单离子导体、新型导电材料^[27]
Croce F	1391	0.05	纳米填料复合电解质^[28]	无机纳米颗粒对电极和电解质的调控^[29]
Scrosati B	971	0.01	复合电解质纳米结构设计、锂-空气电池的开发	聚合物电解质、纤维电极、界面
Appetecchi G B	876	0.03	复合电解质传导机理与界面问题^[30-31]、离子液体	离子液体电解质、全固态电解质
Tarascon J M	867	0.03	纳米结构电解质、电极	固态电解质
Stephan A M	825	0.02	复合电解质^[32]、凝胶聚合物电解质^[33]	复合电解质^[34]、添加剂
Watanabe M	821	0.03	离子液体电解质的应用、复合电解质界面接触^[35]	固态电解质、第一性原理计算
Bruce P G	792	0.03	复合电解质有机相改性^[36]、快充、高容量锂电池的开发	全固态电池、检测技术

[1]	Han ZHENG, Peipei LAI, Xiaohua TIAN, Zhuo SUN, Zhejuan ZHANG. Performance of large-scale silicon particles coated with multistage carbon as anode materials for lithium-ion batteries [J]. Energy Storage Science and Technology, 2023, 12(1): 23-34.
[2]	Lexian DONG, Qun ZHENG, Yue HUANG, Zhipeng TIAN, Jianping LIU, Chao WANG, Bo LIANG, Libin LEI. Research progress on cutting-edge technology of tubular solid oxide fuel cells [J]. Energy Storage Science and Technology, 2023, 12(1): 131-138.
[3]	Rongyang WEI, Tian MAO, Han GAO, Jianren PENG, Jian YANG. Health state estimation of lithium ion battery based on TWP-SVR [J]. Energy Storage Science and Technology, 2022, 11(8): 2585-2599.
[4]	Hang YU, Ying ZHANG, Chaohang XU, Sihan YU. Research progress of thermal runaway prevention and control technology for lithium battery energy storage systems [J]. Energy Storage Science and Technology, 2022, 11(8): 2653-2663.
[5]	Haitao LI, Lingli KONG, Xin ZHANG, Chuanjun YU, Jiwei WANG, Lin XU. The effects of N/P design on the performances of Ni-rich NCM/Gr lithium ion battery [J]. Energy Storage Science and Technology, 2022, 11(7): 2040-2045.
[6]	XIN Yaoda, LI Na, YANG Le, SONG Weili, SUN Lei, CHEN Haosen, FANG Daining. Integrated sensing technology for lithium ion battery [J]. Energy Storage Science and Technology, 2022, 11(6): 1834-1846.
[7]	Biao MA, Chunjing LIN, Lei LIU, Xiaole MA, Tianyi MA, Shiqiang LIU. Venting characteristics and flammability limit of thermal runaway gas of lithium ion battery [J]. Energy Storage Science and Technology, 2022, 11(5): 1592-1600.
[8]	Luyu GAN, Rusong CHEN, Hongyi PAN, Siyuan WU, Xiqian YU, Hong LI. Multiscale research strategy of lithium ion battery safety issue： Experimental and simulation methods [J]. Energy Storage Science and Technology, 2022, 11(3): 852-865.
[9]	Pengchao HUANG, Jiaqiang E. State estimation of lithium-ion battery based on dual adaptive Kalman filter [J]. Energy Storage Science and Technology, 2022, 11(2): 660-666.
[10]	Zhuo XU, Xichao LI, Longzhou JIA, Bing CHEN, Zuoqiang DAI, Lili ZHENG. Effect of overcharge cycle on capacity attenuation and safety of lithium-ion batteries [J]. Energy Storage Science and Technology, 2022, 11(12): 3978-3986.
[11]	Xiaohan LI, Lei SUN, Yong MA, Dongliang GUO, Peng XIAO, Jianjun LIU, Peng WU, Zhihang ZHANG, Xuebing HAN. Energy state estimation of lithium-ion batteries based on sage-husa EKF algorithm [J]. Energy Storage Science and Technology, 2022, 11(11): 3603-3612.
[12]	Yong LUO, Zhenyu ZHOU, Futao SHEN, Huan HUANG, Xiaobin QIU, yongyong WENG. Electrothermal coupling modeling of battery pack considering time-varying parameters [J]. Energy Storage Science and Technology, 2022, 11(10): 3180-3190.
[13]	Shanshan MA, Tingting FANG, Liuqian YANG, Shuwan HU. Application of chromatography-mass spectrometry in study of lithium ion battery [J]. Energy Storage Science and Technology, 2022, 11(1): 60-65.
[14]	Jinhui GAO, Yinglong CHEN, Fanhui MENG, Meichao DING, Li WANG, Gang XU, Xiangming HE. Research on in-situ optical microscopic observation in lithium-ion batteries [J]. Energy Storage Science and Technology, 2022, 11(1): 53-59.
[15]	Huakun HU, Xinli LI, Wendong XUE, Peng JIANG, Yong LI. Knowledge map analysis of a low-temperature electrolyte for lithium-ion battery based on CiteSpace [J]. Energy Storage Science and Technology, 2022, 11(1): 379-396.