钙金属电池的研究进展

doi:10.12028/j.issn.2095-4239.2018.0150

储能科学与技术 ›› 2019, Vol. 8 ›› Issue (1): 26-31.doi: 10.12028/j.issn.2095-4239.2018.0150

钙金属电池的研究进展

杨武海^1,2, 赵井文², 王存国¹, 崔光磊²

1 青岛科技大学高分子科学与工程学院, 橡塑材料与工程教育部重点实验室, 山东青岛 266042;
2 中国科学院青岛生物能源与过程研究所, 山东青岛 266101

收稿日期:2018-08-14 修回日期:2018-09-09 出版日期:2019-01-01 发布日期:2018-09-10
通讯作者: 崔光磊,研究员,主要研究方向为电化学能源材料,E-mail:cuigl@qibebt.ac.cn;王存国,副教授,主要研究方向为耐高(低)温电池特种电解液的研究,E-mail:cgwang789@qq.com;赵井文,副研究员,主要研究方向为电化学能源材料,E-mail:zhaojw@qibebt.ac.cn。
作者简介:杨武海(1992-),男,硕士研究生,主要研究方向为电化学能源材料,E-mail:834522149@qq.com
基金资助:
国家自然科学基金项目（21601195，51625204，21671196），青岛市应用基础研究计划（17-1-1-30-jch），青岛市太阳能与储能技术重点实验室资助。

Research progress of calcium battery

YANG Wuhai^1,2, ZHAO Jingwen², WANG Cunguo¹, CUI Guanglei²

1 Key Lab of Rubber and Plastics, Ministry of Education;School of Polymer Science and Engineering, Qingdao University of Science and Technology, Qingdao 266042, Shandong, China;
2 Qingdao Institute of Biomass Energy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao 266101, Shandong, China

Received:2018-08-14 Revised:2018-09-09 Online:2019-01-01 Published:2018-09-10

摘要/Abstract

摘要： 多价电池的发展为解决目前锂离子电池安全性差、成本高及能量密度低的瓶颈提供了机会。相比于锌和镁，钙不仅储量大，而且氧化还原电势（-2.87 V）及密度更低；然而，钙金属电池相比其它多价电池得到的关注依然较少，主要原因在于非质子电解液中钙金属表面形成的钝化层无法有效传导Ca²⁺，进而导致相应的沉积过程难以实现；同时，稳定的储钙电极材料的研究也成为钙金属电池进一步发展的另一挑战。本文对金属钙及其合金负极在不同电解液中的电化学行为、嵌入类型（普鲁士蓝类、氧化钒等）及转换类型（钙氧电池、钙硫电池）等所涉及到的钙金属电池正极材料的研究进展进行详细综述。

关键词: 多价电池, 钙金属电池, 电解液, 正极材料

Abstract: The development of multivalent batteries is promising for resolving lithium batteries' bottlenecks, such as safety issue, high cost and limited energy density. Calcium (Ca) is more abundant, and has lower standard reduction potential (-2.87 V) and density than zinc and magnesium. However, Ca-based battery gets less attention than other multivalent batteries, which is mainly due to the limitation of Ca²⁺ transport through the solid electrolyte interphase (passivation layer formed at the interface between Ca anode and organic electrolyte), and thus the inefficient stripping/plating processes. Meanwhile, another challenge in this field concerns the development of Ca²⁺-storage electrode materials and in-depth understanding of the ingress process is required. Here, we introduce recent research progress on the electrochemical behavior of metallic Ca and its alloys in various electrolytes, as well as the intercalation (Prussian blue analogs, vanadium oxides, etc.) and conversion (Ca-sulfur batteries, Ca-oxygen batteries) cathode materials.

Key words: multivalent batteries, calcium batteries, electrolytes, cathode materials

中图分类号:

TQ911

杨武海, 赵井文, 王存国, 崔光磊. 钙金属电池的研究进展[J]. 储能科学与技术, 2019, 8(1): 26-31.

YANG Wuhai, ZHAO Jingwen, WANG Cunguo, CUI Guanglei. Research progress of calcium battery[J]. Energy Storage Science and Technology, 2019, 8(1): 26-31.

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钙金属电池的研究进展

Research progress of calcium battery

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