生物质衍生碳材料在全钒液流电池电极方面的应用

doi:10.19799/j.cnki.2095-4239.2021.0666

摘要/Abstract

摘要：

电极是全钒液流电池的重要组成部分，是电解液中不同价态钒离子发生电化学反应的场所。理想的液流电池电极需要同时具备电导率高、比表面积大、润湿性好、耐腐蚀、成本低廉的特性，而目前的材料往往不能兼顾。生物质衍生碳材料具有独特的多孔结构，且含有丰富的氧官能团和氮、磷、硫等元素，可以为电化学反应提供更多的活性位点，被广泛应用于电极材料中。本文回顾了生物质衍生碳材料作为电极或电极催化剂，在全钒液流电池中的应用和研究进展，重点讨论了材料的制备方法、结构组成及其电化学性能，有利于加深人们对电极“构-效关系”的理解，以期设计出更好的电极材料，提高全钒液流电池的性能，降低成本，推进全钒液流电池产业化的发展。

关键词: 生物质衍生碳材料, 生物质, 全钒液流电池, 电极改性, 储能技术

Abstract:

Electrode is a vital component of all vanadium flow batteries and the place where the redox reaction occurs. High conductivity, big specific surface area, superior wettability, corrosion resistance, and low cost are all characteristics of an ideal flow battery electrode. Carbon compounds generated from biomass have a porous structure and are high in oxygen functional groups, as well as nitrogen, phosphorus, sulfur, and other elements. They are widely employed in electrode materials by providing active sites on surface. In this research, we review the application and research progress of biomass-derived carbon materials as electrodes or electrode catalysts in all vanadium flow batteries. The materials' structure, composition, and electrochemical characteristics are examined in detail. It will aid in the improved design of electrode materials, as well as the performance, cost reduction, and industrialization of VFB.

Key words: biomass-derived carbon materials, biomass, flow battery, electrode modification, energy storage

中图分类号:

TK 02

姚祯, 张琦, 王锐, 刘庆华, 王保国, 缪平. 生物质衍生碳材料在全钒液流电池电极方面的应用[J]. 储能科学与技术, 2022, 11(7): 2083-2091.

Zhen YAO, Qi ZHANG, Rui WANG, Qinghua LIU, Baoguo WANG, Ping MIAO. Application of biomass derived carbon materials in all vanadium flow battery electrodes[J]. Energy Storage Science and Technology, 2022, 11(7): 2083-2091.

图/表 5

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参考文献 31

1	YANG Z G, ZHANG J L, KINTNER-MEYER M C W, et al. Electrochemical energy storage for green grid[J]. Chemical Reviews, 2011, 111(5): 3577-3613.
2	贾志军, 宋士强, 王保国. 液流电池储能技术研究现状与展望[J]. 储能科学与技术, 2012, 1(1): 50-57.
	JIA Z J, SONG S Q, WANG B G. Acritical review on redox flow batteries for electrical energy storage applications[J]. Energy Storage Science and Technology, 2012, 1(1): 50-57.
3	SKYLLAS-KAZACOS M, RYCHCIK M, ROBINS R G, et al. New all-vanadium redox flow cell[J]. Journal of the Electrochemical Society, 1986, 133(5): 1057-1058.
4	FORNER-CUENCA A, BRUSHETT F R. Engineering porous electrodes for next-generation redox flow batteries: Recent progress and opportunities[J]. Current Opinion in Electrochemistry, 2019, 18: 113-122.
5	王新伟, 刘丽梅, 王双印, 等. 聚丙烯腈基炭毡电极改性处理及电化学性能研究[J]. 化工新型材料, 2016, 44(5): 145-147.
	WANG X W, LIU L M, WANG S Y, et al. Study on the modification and electrochemical property of PAN-carbon felt electrode[J]. New Chemical Materials, 2016, 44(5): 145-147.
6	王刚, 陈金伟, 朱世富, 等. 全钒氧化还原液流电池碳素类电极的活化[J]. 化学进展, 2015, 27(10): 1343-1355.
	WANG G, CHEN J W, ZHU S F, et al. Activation of carbon electrodes for all-vanadium redox flow battery[J]. Progress in Chemistry, 2015, 27(10): 1343-1355.
7	陈瑞芳, 周科. 全钒液流电池用聚丙烯腈炭毡改性研究[J]. 东方汽轮机, 2018(2): 69-72.
	CHEN R F, ZHOU K. Study on modification of PAN-graphite felt for all vanadium redox flow battery[J]. Dongfang Turbine, 2018(2): 69-72.
8	EIFERT L, BANERJEE R, JUSYS Z, et al. Characterization of carbon felt electrodes for vanadium redox flow batteries: Impact of treatment methods[J]. Journal of the Electrochemical Society, 2018, 165(11): A2577-A2586.
9	KIM K J, PARK M S, KIM Y J, et al. A technology review of electrodes and reaction mechanisms in vanadium redox flow batteries[J]. Journal of Materials Chemistry A, 2015, 3(33): 16913-16933.
10	HUONG LE T X, BECHELANY M, CRETIN M. Carbon felt based-electrodes for energy and environmental applications: A review[J]. Carbon, 2017, 122: 564-591.
11	HE Z X, LV Y R, ZHANG T A, et al. Electrode materials for vanadium redox flow batteries: Intrinsic treatment and introducing catalyst[J]. Chemical Engineering Journal, 2022, 427: doi:10. 1016/j.cej.2021.131680.
12	ISIKGOR F H, BECER C R. Lignocellulosic biomass: A sustainable platform for the production of bio-based chemicals and polymers[J]. Polymer Chemistry, 2015, 6(25): 4497-4559.
13	赵广震. 生物质衍生多孔碳材料的制备及其超级电容储能性能研究[D]. 吉林: 东北电力大学, 2020.
	ZHAO G Z. Preparation and supercapacitive storage properties of biomass derived porous carbon materials[D]. Jilin: Northeast Dianli University, 2020.
14	PARK M, RYU J, KIM Y, et al. Corn protein-derived nitrogen-doped carbon materials with oxygen-rich functional groups: A highly efficient electrocatalyst for all-vanadium redox flow batteries[J]. Energy Environ Sci, 2014, 7(11): 3727-3735.
15	LEE H J, KIM H. Graphite felt coated with dopamine-derived nitrogen-doped carbon as a positive electrode for a vanadium redox flow battery[J]. Journal of the Electrochemical Society, 2015, 162(8): A1675-A1681.
16	JEONG K I, SONG S A, KIM S S. Glucose-based carbon-coating layer on carbon felt electrodes of vanadium redox flow batteries[J]. Composites Part B: Engineering, 2019, 175: doi:10.1016/j.compositesb. 2019.107072.
17	DENG Q, TIAN Y, DING P, et al. Porous lamellar carbon assembled from Bacillus mycoides as high-performance electrode materials for vanadium redox flow batteries[J]. Journal of Power Sources, 2020, 450: doi:10.1016/j.jpowsour.2019.227633.
18	JIANG Y Q, CHENG G, HE Z X, et al. Biomass-derived porous graphitic carbon with excellent electrocatalytic performances for vanadium redox reactions[J]. Journal of the Electrochemical Society, 2019, 166(16): A3918-A3926.
19	LIU J, WANG Z A, WU X W, et al. Porous carbon derived from disposable shaddock peel as an excellent catalyst toward VO₂ ⁺/VO₂ ⁺ couple for vanadium redox battery[J]. Journal of Power Sources, 2015, 299: 301-308.
20	ULAGANATHAN M, JAIN A, ARAVINDAN V, et al. Bio-mass derived mesoporous carbon as superior electrode in all vanadium redox flow battery with multicouple reactions[J]. Journal of Power Sources, 2015, 274: 846-850.
21	MAHARJAN M, BHATTARAI A, ULAGANATHAN M, et al. High surface area bio-waste based carbon as a superior electrode for vanadium redox flow battery[J]. Journal of Power Sources, 2017, 362: 50-56.
22	MAHANTA V, RAJA M, KOTHANDARAMAN R. Activated carbon from sugarcane bagasse as a potential positive electrode catalyst for vanadium redox flow battery[J]. Materials Letters, 2019, 247: 63-66.
23	ABBAS A, ENG X E, EE N, et al. Development of reduced graphene oxide from biowaste as an electrode material for vanadium redox flow battery[J]. Journal of Energy Storage, 2021, 41: doi:10.1016/j.est.2021.102848.
24	MAHARJAN M, WAI N, VEKSHA A, et al. Sal wood sawdust derived highly mesoporous carbon as prospective electrode material for vanadium redox flow batteries[J]. Journal of Electroanalytical Chemistry, 2019, 834: 94-100.
25	JIANG Y Q, DU M C, CHENG G, et al. Nanostructured N-doped carbon materials derived from expandable biomass with superior electrocatalytic performance towards V²⁺/V³⁺ redox reaction for vanadium redox flow battery[J]. Journal of Energy Chemistry, 2021, 59: 706-714.
26	LV Y R, LI Y H, HAN C, et al. Application of porous biomass carbon materials in vanadium redox flow battery[J]. Journal of Colloid and Interface Science, 2020, 566: 434-443.
27	CHENG D X, TIAN M R, WANG B Y, et al. One-step activation of high-graphitization N-doped porous biomass carbon as advanced catalyst for vanadium redox flow battery[J]. Journal of Colloid and Interface Science, 2020, 572: 216-226.
28	HE Z X, CHENG G, JIANG Y Q, et al. Novel 2D porous carbon nanosheet derived from biomass: Ultrahigh porosity and excellent performances toward V²⁺/V³⁺ redox reaction for vanadium redox flow battery[J]. International Journal of Hydrogen Energy, 2020, 45(7): 3959-3970.
29	ZHANG Z H, ZHAO T S, BAI B F, et al. A highly active biomass-derived electrode for all vanadium redox flow batteries[J]. Electrochimica Acta, 2017, 248: 197-205.
30	RIBADENEYRA M C, GROGAN L, AU H, et al. Lignin-derived electrospun freestanding carbons as alternative electrodes for redox flow batteries[J]. Carbon, 2020, 157: 847-856.
31	LEE M E, JANG D, LEE S, et al. Silk protein-derived carbon fabric as an electrode with high electro-catalytic activity for all-vanadium redox flow batteries[J]. Applied Surface Science, 2021, 567: doi:10.1016/j.apsusc.2021.150810.

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