铌基低温电池关键材料研究进展

doi:10.19799/j.cnki.2095-4239.2023.0641

储能科学与技术 ›› 2024, Vol. 13 ›› Issue (1): 311-324.doi: 10.19799/j.cnki.2095-4239.2023.0641

铌基低温电池关键材料研究进展

戴雪娇¹(), 闫婕¹, 王管¹, 董浩天¹, 蒋丹枫¹, 魏泽威¹, 孟凡星², 刘松涛², 张海涛¹^,³()

^1.中国科学院过程工程研究所，北京 100190
^2.天津空间电源科技有限公司，天津 300392
^3.郑州中科新兴产业技术研究院，河南郑州 450003

收稿日期:2023-09-18 修回日期:2023-10-19 出版日期:2024-01-05 发布日期:2024-01-22
通讯作者: 张海涛 E-mail:daixuejiao@ipe.ac.cn;htzhang@ipe.ac.cn
作者简介:戴雪娇（1995—），女，硕士，工程师，研究方向为锂离子电池材料，E-mail：daixuejiao@ipe.ac.cn；
基金资助:
国家级变革性技术关键科学问题专项(SQ2019YFA070061)

Research progress of key materials for niobium-based low temperature batteries

Xuejiao DAI¹(), Jie YAN¹, Guan WANG¹, Haotian DONG¹, Danfeng JIANG¹, Zewei WEI¹, Fanxing MENG², Songtao LIU², Haitao ZHANG¹^,³()

^1.Institute of Process Engineering, China Academy of Sciences, Beijing 100190, China
^2.Tianjin Space Power Technology Co. Ltd. , Tianjin 300392, China
^3.Zhengzhou Zhongke Emerging Industry Technology Research Institute, Zhengzhou 450003, Henan, China

Received:2023-09-18 Revised:2023-10-19 Online:2024-01-05 Published:2024-01-22
Contact: Haitao ZHANG E-mail:daixuejiao@ipe.ac.cn;htzhang@ipe.ac.cn

摘要/Abstract

摘要：

社会科技的进步也推动了锂电池技术快速发展。锂离子电池的性能受温度影响较大，在低温条件下工作时其性能衰减严重，因此，提高锂离子电池的低温性能成为研究热点。本文综述了基于铌基电极材料的低温锂离子电池近年的研究进展以及影响其低温性能的因素，从电极材料和电解液两个方面总结了改善锂离子电池低温性能的方法。电极材料方面主要介绍了铌基材料的晶体结构和电化学性质、烧结对于铌基材料结构及性能的影响、铌基材料的修饰改性研究以及含铌氧化物低温电化学性能，结果说明了铌基材料独特的赝电容结构能促进离子和电子传导，异质原子的掺杂及其他材料的复合能够使其结构更加稳定，带隙变窄，载流子密度增加，使倍率性能得到提高，从而提高了材料的低温性能；电解液方面从溶剂、添加剂以及锂盐三方面介绍了匹配铌基负极的低温电解液的研究进展，提出采用多元溶剂体系与多种添加剂协同作用可以改善电解液对锂离子电池低温性能的影响，并且大部分线性羧酸酯类溶剂熔、沸点较低，蒸气压较大，能有效改善电池的低温性能。本综述可为设计在低温下具有优异性能的锂离子电池负极材料提供指导。

关键词: 锂离子电池, 铌基材料, 低温性能, 钛铌氧化物, 低温电解液

Abstract:

The progress of science and technology favors the rapid development of lithium-ion battery technology. The performances of lithium-ion battery are greatly affected by temperature, and they will be seriously attenuated at low temperature. Therefore, improving the low-temperature performance of lithium-ion battery is a research hotspot. Herein, the research progress of low-temperature lithium-ion batteries based on niobium-based electrode materials in recent years and the factors affecting their low-temperature performance are reviewed, and the methods to improve the low-temperature performance of lithium-ion batteries are summarized from the points of view of electrodes and electrolytes. As to electrode materials, the crystal structure and electrochemical properties of niobium-based materials, the influence of sintering on the structure and properties of niobium-based materials, the modification of niobium-based materials and the low-temperature electrochemical properties of niobium-containing oxides are mainly introduced. The results show that the unique pseudo-capacitance structure of niobium-based materials can promote ion and electron conduction, and the doping of heterogeneous atoms and the recombination of other materials can make its structure more stable, narrow the band gap, increase the carrier density, improve the rate performance, and thus improve the low-temperature performance of the materials. As to electrolytes, the research progress of low temperature electrolytes matched to niobium-based anode will be introduced from three aspects: solvent, additive and lithium salt. It is proposed that the synergistic effect of multi-solvent system and various additives can improve the influence of electrolyte on the low-temperature performance of lithium-ion batteries, and most linear carboxylate solvents can effectively improve the low-temperature performance of batteries because of their low melting point and high vapor pressure. This review may provide a guidance for designing anode materials of low-temperature lithium-ion batteries with excellent performance.

Key words: lithium-ion battery, niobium-based materials, low temperature performance, titanium niobium oxide, low temperature electrolyte

中图分类号:

O 614.51

戴雪娇, 闫婕, 王管, 董浩天, 蒋丹枫, 魏泽威, 孟凡星, 刘松涛, 张海涛. 铌基低温电池关键材料研究进展[J]. 储能科学与技术, 2024, 13(1): 311-324.

Xuejiao DAI, Jie YAN, Guan WANG, Haotian DONG, Danfeng JIANG, Zewei WEI, Fanxing MENG, Songtao LIU, Haitao ZHANG. Research progress of key materials for niobium-based low temperature batteries[J]. Energy Storage Science and Technology, 2024, 13(1): 311-324.

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修饰改性方法	合成方法	电极材料	电化学性能	参考文献
掺杂金属颗粒	球磨	Cu_0.02Ti_0.94Nb_2.04O₇	315 mAh/g @ 0.1 C	[39]
	球磨	Ru_0.01Ti_0.99Nb₂O₇	351 mAh/g @ 0.1 C	[40]
	溶剂热	Mo-TNO	190 mAh/g @ 10 C	[41]
复合碳基材料	溶剂热	TiNb₂O₇/CNT-KB	328 mAh/g @ 0.1 C	[42]
	溶剂热	TiNb₂O₇/C	200 mAh/g @ 30 C	[43]
	溶剂热	ACC@TNO	356 mAh/g @ 0.1 C	[44]
改变形貌	溶剂热	MS-TNO NS	349 mAh/g @ 1 C	[45]
改变形貌	溶剂热+静电纺丝	WS₂@TiNb₂O₇ HNs	660 mAh/g @ 2 C	[46]

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铌基低温电池关键材料研究进展

Research progress of key materials for niobium-based low temperature batteries

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