一种新型的脲类溶剂在锂空气电池中的应用

doi:10.12028/j.issn.2095-4239.2018.0069

储能科学与技术 ›› 2018, Vol. 7 ›› Issue (4): 667-673.doi: 10.12028/j.issn.2095-4239.2018.0069

一种新型的脲类溶剂在锂空气电池中的应用

任警, 黄志梅, 沈越, 黄云辉

华中科技大学材料科学与工程学院, 湖北武汉 430074

收稿日期:2018-04-28 修回日期:2018-05-03 出版日期:2018-07-01 发布日期:2018-05-10
通讯作者: 沈越,副教授,主要研究方向为锂空气电池、锂离子电池SOC、SOH实时监测以及纳米材料与器件,E-mail:shenyue1213@hust.edu.cn
作者简介:任警(1992-),男,硕士研究生,主要研究方向为锂空气电池,E-mail:maplerj@hust.edu.cn
基金资助:
国家自然科学基金项目（51602223和51632001）。

Achieving high performance lithium-O₂ battery by introducing a novel urea electrolyte

REN Jing, HUANG Zhimei, SHEN Yue, HUANG Yunhui

School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, Hubei, China

Received:2018-04-28 Revised:2018-05-03 Online:2018-07-01 Published:2018-05-10

摘要/Abstract

摘要： 在锂空气电池中，电解液对电池的充放电过程、放电产物的稳定性以及循环性能有着至关重要的影响。本文利用脲类溶剂1，3-二甲基-2-咪唑啉酮（DMI）作为新型的锂空气电池电解液，有效地增加了放电产物过氧化锂（Li₂O₂）的溶解度，促进其溶剂化，并改善Li₂O₂与正极之间的接触，使得电池性能得到有效提高。通过研究表明，相比较传统的醚类电解液四乙二醇二甲醚（TEGDME），DMI能将电池放电容量提升1.5倍，而充电过电位则降低了0.6 V，减少了高电位导致的副反应。同时，通过加入氧抑制剂，稳定溶剂中的氧自由基，减少放电中间产物对DMI的攻击，使得电池循环性能得到显著提高。

关键词: 锂空气电池, 电解液, 过氧化锂, 循环性能

Abstract: The development of rechargeable Li-O₂ battery (LOB) has encountered bottlenecks at this stage. One of the biggest challenges is to lower the oxidation potential of Li₂O₂, the insulating and insoluble discharge product. In this paper, 1, 3-Dimethyl-2-imidazolidinone (DMI) is first to be used as electrolyte in LOB, which can increase the solubility of lithium peroxide, promote its solvation, and improve the contact between Li₂O₂ and cathode, resulting in an improved battery performance. Compared to the traditional TEGDME electrolyte, DMI can increase the charge capacity by 1.5 times, while decrease the charge overpotential by 0.6 V, which suppress the side reaction caused by high potential. At the same time, by adding oxygen inhibitors, the oxygen radicals in the solvent are stabilized, the nucleophilic attack on the DMI by the discharge intermediate product is reduced, and the cycle performance of the battery is significantly improved.

Key words: lithium-O₂ battery, electrolyte, lithium peroxide, cycle performance

中图分类号:

TM911

任警, 黄志梅, 沈越, 黄云辉. 一种新型的脲类溶剂在锂空气电池中的应用[J]. 储能科学与技术, 2018, 7(4): 667-673.

REN Jing, HUANG Zhimei, SHEN Yue, HUANG Yunhui. Achieving high performance lithium-O₂ battery by introducing a novel urea electrolyte[J]. Energy Storage Science and Technology, 2018, 7(4): 667-673.

参考文献

[1] BRUCE P G, FREUNBERGER S A, HARDWICK L J, et al. Li-O₂ and Li-S batteries with high energy storage[J]. Nature Materials, 2012, 11(1):19.
[2] GIRISHKUMAR G, MCCLOSKEY B, LUNTZ A C, et al. Lithium-air battery:Promise and challenges[J]. The Journal of Physical Chemistry Letters, 2010, 1(14):2193-2203.
[3] HUMMELSHOJ J S, BLOMQVIST J, DATTA S, et al. Communications:Elementary oxygen electrode reactions in the aprotic Li-air battery[J]. The Journal of Chemical Physics, 2010, 132:71101.
[4] LAOIRE C O, MUKERJEE S, ABRAHAM K M, et al. Elucidating the mechanism of oxygen reduction for lithium-air battery applications[J]. The Journal of Physical Chemistry C, 2009, 113(46):20127-20134.
[5] OGASAWARA T, DÉbart A, HOLZAPFEL M, et al. Rechargeable Li₂O₂ electrode for lithium batteries[J]. Journal of the American Chemical Society, 2006, 128(4):1390-1393.
[6] LU Y C, GASTEIGER H A, PARENT M C, et al. The influence of catalysts on discharge and charge voltages of rechargeable Li-oxygen batteries[J]. Electrochemical and Solid-State Letters, 2010, 13(6):A69-A72.
[7] QIU F, HE P, JIANG J, et al. Ordered mesoporous TiC-C composites as cathode materials for Li-O₂ batteries[J]. Chemical Communications, 2016, 52(13):2713-2716.
[8] XU J J, WANG Z L, XU D, et al. Tailoring deposition and morphology of discharge products towards high-rate and long-life lithium-oxygen batteries[J]. Nature Communications, 2013, 4(9):2438.
[9] THOTIYL M M O, FREUNBERGER S A, PENG Z, et al. A stable cathode for the aprotic Li-O₂ battery[J]. Nature Materials, 2013, 12(11):1050-1056.
[10] XU K. Nonaqueous liquid electrolytes for lithium-based rechargeable batteries[J]. Chemical Reviews, 2004, 104(10):4303-4418.
[11] CHEN Y, FREUNBERGER S A, PENG Z, et al. Li-O₂ battery with a dimethylformamide electrolyte[J]. Journal of the American Chemical Society, 2012, 134(18):7952-7957.
[12] READ J. Characterization of the lithium-oxygen organic electrolyte battery[J]. Journal of the Electrochemical Society, 2002, 149(9):A1190-A1195.
[13] LAOIRE C O, MUKERJEE S, ABRAHAM K M, et al. Influence of nonaqueous solvents on the electrochemistry of oxygen in the rechargeable lithium-air battery[J]. The Journal of Physical Chemistry C, 2010, 114(19):9178-9186.
[14] ZHOU B, GUO L, ZHANG Y, et al. A high-performance Li-O₂ battery with a strongly solvating hexamethylphosphoramide electrolyte and a LiPON-protected lithium anode[J]. Advanced Materials, 2017, 29(30):doi:10.1002/adma.201701568.
[15] GAO X, JOVANOV Z P, CHEN Y, et al. Phenol-catalyzed discharge in the aprotic lithium-oxygen battery[J]. Angewandte Chemie International Edition, 2017, 56:6539-6543.
[16] AETUKURI N B, MCCLOSKEY B D, GARCIA J M, et al. Solvating additives drive solution-mediated electrochemistry and enhance toroid growth in non-aqueous Li-O₂ batteries[J]. Nature Chemistry, 2015, 7(1):50-56.
[17] ZHANG W, SHEN Y, SUN D, et al. Promoting Li₂O₂ oxidation via solvent-assisted redox shuttle process for low overpotential Li-O₂ battery[J]. Nano Energy, 2016, 30:43-51.
[18] JOHNSON L, LI C, LIU Z, et al. The role of LiO₂ solubility in O₂ reduction in aprotic solvents and its consequences for Li-O₂ batteries[J]. Nature Chemistry, 2014, 6(12):1091-1099.
[19] LIU R, LEI Y, YU W, et al. Achieving low overpotential lithium-oxygen batteries by exploiting a new electrolyte based on N,N-dimethylpropyleneurea[J]. ACS Energy Letter, 2017, 2(2):313-318.
[20] KWABI D G, BATCHO T P, AMANCHUKWU C V, et al. Chemical instability of dimethyl sulfoxide in lithium-air batteries[J]. The Journal of Physical Chemistry Letters, 2014, 5(16):2850-2856.
[21] SHARON D, AFRI M, NOKED M, et al. Oxidation of dimethyl sulfoxide solutions by electrochemical reduction of oxygen[J]. The Journal of Physical Chemistry Letters, 2013, 4(18):3115-3119.
[22] KHETAN A, LUNTZ A, VISWANATHAN V. Trade-offs in capacity and rechargeability in nonaqueous Li-O₂ batteries:Solution-driven growth versus nucleophilic stability[J]. The Journal of Physical Chemistry Letters, 2015, 6(7):1254-1259.
[23] YAMASHITA K I, TSUBOI M, ASANO M S, et al. Facile aromatic finkelstein iodination (AFI) reaction in 1, 3-dimethyl-2-imidazolidinone (DMI)[J]. Synthetic Communications, 2012, 42(2):170-175.

一种新型的脲类溶剂在锂空气电池中的应用

Achieving high performance lithium-O₂ battery by introducing a novel urea electrolyte

PDF

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	李海涛, 孔令丽, 张欣, 余传军, 王纪威, 徐琳. N/P设计对高镍NCM/Gr电芯性能的影响[J]. 储能科学与技术, 2022, 11(7): 2040-2045.
[2]	欧宇, 侯文会, 刘凯. 锂离子电池中的智能安全电解液研究进展[J]. 储能科学与技术, 2022, 11(6): 1772-1787.
[3]	房茂霖, 张英, 乔琳, 刘淑敏, 曹中琦, 张华民, 马相坤. 铁铬液流电池技术的研究进展[J]. 储能科学与技术, 2022, 11(5): 1358-1367.
[4]	方亮, 张凯, 周丽敏. 铝离子电池电解液的研究进展[J]. 储能科学与技术, 2022, 11(4): 1236-1245.
[5]	王心怡, 李维杰, 韩朝, 刘化鹍, 窦世学. 水系锌离子电池金属负极的挑战与优化策略[J]. 储能科学与技术, 2022, 11(4): 1211-1225.
[6]	陶影, 赵铃飞, 王云晓, 曹余良, 侴术雷. 基于双盐高浓度电解液的高稳定性钠金属负极[J]. 储能科学与技术, 2022, 11(4): 1103-1109.
[7]	岳博文, 佟佳欢, 刘玉文, 霍锋. 离子液体电解液的模拟计算方法及应用[J]. 储能科学与技术, 2022, 11(3): 897-911.
[8]	胡华坤, 李新丽, 薛文东, 蒋朋, 李勇. 基于CiteSpace的锂离子电池用低温电解液知识图谱分析[J]. 储能科学与技术, 2022, 11(1): 379-396.
[9]	王子璇, 李俊成, 李金东, 易娟, 石霖, 吴旭. 废磷酸铁锂正极材料资源化回收工艺[J]. 储能科学与技术, 2022, 11(1): 45-52.
[10]	姚祯, 王锐, 阳雪, 张琦, 刘庆华, 王保国, 缪平. 锌铁液流电池研究现状及展望[J]. 储能科学与技术, 2022, 11(1): 78-88.
[11]	刘范芬, 陈诚, 朱智渊, 张伟康, 吕正中. N/P比对磷酸铁锂电池性能的影响[J]. 储能科学与技术, 2021, 10(4): 1325-1329.
[12]	周琳, 杨佯, 胡勇胜. 合金电极失效机制：体积膨胀？电解液分解？[J]. 储能科学与技术, 2021, 10(3): 813-820.
[13]	衡永丽, 谷振一, 郭晋芝, 吴兴隆. Na₃V₂（PO₄）₃@C用作水系锌离子电池正极材料的研究[J]. 储能科学与技术, 2021, 10(3): 938-944.
[14]	池上森, 姜益栋, 王庆荣, 叶子威, 余凯, 马骏, 靳俊, 王军, 王朝阳, 温兆银, 邓永红. 液体电解液改性石榴石型固体电解质与锂负极的界面[J]. 储能科学与技术, 2021, 10(3): 914-924.
[15]	张晶晶, 崔孝玲, 赵冬妮, 杨莉, 王洁. 高浓度电解液对电极/电解液界面的影响[J]. 储能科学与技术, 2021, 10(1): 143-149.

一种新型的脲类溶剂在锂空气电池中的应用

Achieving high performance lithium-O2 battery by introducing a novel urea electrolyte

PDF

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

Achieving high performance lithium-O₂ battery by introducing a novel urea electrolyte