Energy Storage Science and Technology ›› 2022, Vol. 11 ›› Issue (9): 2781-2797.doi: 10.19799/j.cnki.2095-4239.2022.0326

• Special Issue for the 10th Anniversary • Previous Articles     Next Articles

Recent advances in mechano-electrochemistry in lithium metal batteries

Xin SHEN1(), Rui ZHANG2, Chenzi ZHAO1, Peng WU3, Yutong ZHANG2, Jundong ZHANG1, Lizhen FAN4, Quanbing LIU5, Aibing CHEN6, Qiang ZHANG1()   

  1. 1.Beijing Key Laboratory of Green Chemical Reaction Engineering and Technology, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China
    2.Advanced Research Institute of Multidisciplinary Science, Beijing Institute of Technology, Beijing 100081, China
    3.Research & Development Center BMW, BMW China Services Ltd. , Beijing 101318, China
    4.Institute of Advanced Materials and Technology, University of Science and Technology Beijing, Beijing 100083, China
    5.School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006, Guangdong, China
    6.College of Chemical and Pharmaceutical Engineering, Hebei University of Science and Technology, Shijiazhuang 050018, Hebei, China
  • Received:2022-06-15 Revised:2022-06-22 Online:2022-09-05 Published:2022-08-30
  • Contact: Qiang ZHANG E-mail:shenx17@mails.tsinghua.edu.cn;zhang-qiang@mails.tsinghua.edu.cn

Abstract:

Lithium metal batteries are considered next-generation rechargeable batteries owing to their ultrahigh energy density. However, during the charging/discharging process, the conversion mechanism and dendritic morphology of lithium metal anodes lead to huge and uneven internal volume modifications. Thus, lithium metal batteries experience more serious mechano-electrochemical problems compared with lithium-ion batteries, including lithium dendrite growth, lithium dendrite fracture and pulverization, solid electrolyte interphase (SEI) rupture, and electrolyte/separator mechanical failure. This review introduces the mechanical properties of lithium metal first, including elasticity, plasticity, and viscosity. Especially, the size effect of electrodeposited lithium is highlighted. Next, recent advances in mechano-electrochemical mechanisms in working lithium metal batteries are summarized. For the liquid electrolyte environment, the stress-driven lithium dendrite growth mechanism, interfacial (lithium metal and SEI, electrode and separator, and lithium metal and current collector) interaction mechanism, and external pressure regulation mechanism are presented. For the solid electrolyte environment, the ion transport impact from the solid-solid contact and interaction between the bulk/grain boundaries/voids of electrolytes and lithium metal are presented. Finally, the mechano-electrochemical mechanism in lithium metal batteries is summarized and the future development direction is prospected.

Key words: lithium metal batteries, lithium metal anodes, lithium dendrites, mechanics, electrochemistry

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