Review of high-temperature phase change heat storage material preparation and applications

doi:10.19799/j.cnki.2095-4239.2022.0521

Abstract

Abstract:

Faced with the demand for steam heating in the industrial field, we will vigorously develop high-temperature phase change heat storage technology, effectively adjust the peak and valley loads of power grids, effectively promote the replacement of electric energy, and help achieve the goal of "carbon peak and carbon neutrality." This article comprises a literature review of the principles and methods of phase change material optimization. High-temperature phase change materials are also classified. The latest research trends of high-temperature composite phase change materials are emphatically described, including metal foam/inorganic salt, graphite foam/inorganic salt, expanded graphite/inorganic salt, porous ceramic/inorganic salt, and porous clay mineral/inorganic salt composite phase change materials. Notably, high-temperature composite phase change materials can improve the low thermal conductivity and stability of inorganic salts and corrosion of sealing materials. Next, the preparation methods of high-temperature phase change materials are summarized; the advantages and disadvantages of the infiltration method, sol-gel method, and cold pressing sintering method in practical application are highlighted. In comparison, the cold pressing sintering method is the most cost-effective for preparing salt matrix composites. Finally, the application statuses of high-temperature composite phase change materials in industrial waste heat recovery, power peak regulation, and solar thermal power generation are discussed, providing a basis for studying the capacity allocation and economic evaluation methods of high-temperature phase change heat storage systems of the steam type under different scenarios. This review has a certain reference value for the development of high-temperature phase change heat storage technology.

Key words: high temperature heat storage, phase change material, preparation method, thermal storage device

CLC Number:

TK 02

Wei LIU, Zhenming LI, Mingyang LIU, Cenyu YANG, Chao MEI, Ying LI. Review of high-temperature phase change heat storage material preparation and applications[J]. Energy Storage Science and Technology, 2023, 12(2): 398-430.

Figures/Tables 22

Table 1

Thermophysical properties of inorganic salts of some high-temperature phase change materials[6-7, 17-21]"

化合物	熔化温度/℃	熔化热/(kJ/kg)	导热系数/[W/(m·K)]	比热容/[kJ/(kg·K)]
NaNO₃	306	182	0.5/—(液固)	—/1.1(液固)
KNO₃	334	266	—/0.5	—/0.953(液固)
NaOH	323	170	0.92/—(液固)	2.09/2.01(液固)
KOH	380	149.7	—/0.5(液固)	—
Na₂CO₃	854	275.7	—	—/2(液固)
K₂CO₃	897	235.8	—	—/2(液固)
96KNO₃-4KCl	320	150	—/0.5(液固)	—/1.21(液固)
60MgCl₂-20.4KCl-19.6NaCl	380	400	—	—/0.96(液固)
52MgCl₂-48NaCl	450	430	0.95/—(液固)	1/0.92(液固)
64MgCl₂-36KCl	470	388	0.83/—(液固)	0.96/0.84(液固)
48MgCl₂-27CaCl₂-25KCl	487	342	0.88/—(液固)	0.92/0.8(液固)
53BaCl₂-28KCl-19NaCl	542	221	0.86/—(液固)	0.8/0.63(液固)
44Li₂CO₃-56Na₂CO₃	496	370	2.09/—(液固)	2.09/1.8(液固)
39MgCl₂-61NaCl	435	351	0.81/—(液固)	0.96/0.8(液固)
22Li₂CO₃-16Na₂CO₃-62K₂CO₃	580	288	1.95/—(液固)	2.09/1.80(液固)
67CaCl₂-33NaCl	500	281	1.02/—(液固)	1/0.84(液固)
33LiF-67KF	442	618	3.98/—(液固)	1.63/1.34(液固)
12NaF-59KF-29LiF	454	590	4.50/—(液固)	1.55/1.34(液固)
20Li₂CO₃-60Na₂CO₃-20K₂CO₃	550	283	1.83/—(液固)	1.88/1.59(液固)
54KCl-46ZnCl₂	432	218	0.83/—(液固)	0.88/0.67(液固)
28KCl-19NaCl-53BaCl₂	542	221	0.86/—(液固)	0.80/0.63(液固)
48NaCl-52MgCl₂	450	430	0.95/—(液固)	1.00/0.92(液固)
47BaCl₂-24KCl-29CaCl	551	219	0.95/—(液固)	0.84/0.67(液固)
36KCl-64MgCl₂	470	388	0.83/—(液固)	0.96/0.84(液固)
33NaCl-67CaCl₂	500	281	1.02/—(液固)	1.00/0.84(液固)
37MgCl₂-63SrCl₂	535	239	1.05/—(液固)	0.80/0.67(液固)
47Li₂CO₃-53K₂CO₃	488	342	1.99/—(液固)	1.34/1.03(液固)
17NaF-21KF-62K₂CO₃	520	274	1.50/—(液固)	1.38/1.17(液固)
28Li₂CO₃-72K₂CO₃	498	263	1.85/—(液固)	1.80/1.46(液固)
51K₂CO₃-49Na₂CO₃	710	163	1.73/—(液固)	1.56/1.67(液固)
24KCl-47BaCl₂-29CaCl₂	551	219	0.95/—(液固)	0.84/0.67(液固)
32Li₂CO₃-35K₂CO₃-Na₂CO₃	397	276	2.02/—(液固)	1.63/1.67(液固)
61KCl-39MgCl₂	435	351	0.81/—(液固)	0.96/0.8(液固)
40KCl-23KF-37K₂CO₃	528	283	1.19/—(液固)	1.26/1(液固)
35Li₂CO₃-65K₂CO₃	505	344	1.89/—(液固)	1.76/1.34(液固)

Table 1

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References 113

1	程珊珊. 基于电、煤锅炉联合供暖的弃风消纳策略研究[D]. 沈阳: 沈阳工业大学, 2020.
	CHENG S S. Research on wind power accommodation strategy of combined heating of electric and coal boilers[D]. Shenyang: Shenyang University of Technology, 2020.
2	JACOB R, BELUSKO M, INÉS FERNÁNDEZ A, et al. Embodied energy and cost of high temperature thermal energy storage systems for use with concentrated solar power plants[J]. Applied Energy, 2016, 180: 586-597.
3	YANG T Y, KING W P, MILJKOVIC N. Phase change material-based thermal energy storage[J]. Cell Reports Physical Science, 2021, 2(8): doi: 10.1016/j.xcrp.2021.100540.
4	HE F, SONG G P, HE X D, et al. Structural and phase change characteristics of inorganic microencapsulated core/shell Al-Si/Al₂O₃ micro-particles during thermal cycling[J]. Ceramics International, 2015, 41(9): 10689-10696.
5	ZHANG G C, LI J Q, CHEN Y F, et al. Encapsulation of copper-based phase change materials for high temperature thermal energy storage[J]. Solar Energy Materials and Solar Cells, 2014, 128: 131-137.
6	WEI G S, WANG G, XU C, et al. Selection principles and thermophysical properties of high temperature phase change materials for thermal energy storage: A review[J]. Renewable and Sustainable Energy Reviews, 2018, 81: 1771-1786.
7	KENISARIN M M. High-temperature phase change materials for thermal energy storage[J]. Renewable and Sustainable Energy Reviews, 2010, 14(3): 955-970.
8	KHARE S, DELL'AMICO M, KNIGHT C, et al. Selection of materials for high temperature latent heat energy storage[J]. Solar Energy Materials and Solar Cells, 2012, 107: 20-27.
9	LIU M, FERNÁNDEZ A I, SEGARRA M. Materials for phase change material at high temperature[M]//High Temperature Thermal Storage Systems Using Phase Change Materials. Amsterdam: Elsevier, 2018: 195-230.
10	ANSYS. The 21th anniversary celebration of materials selection software, Cambridge[EB/OL]. (2007-08-15)[2013-05-29].http://www.newmaker.com/.
11	MISHRA R K, VERMA K, MISHRA V, et al. A review on carbon-based phase change materials for thermal energy storage[J]. Journal of Energy Storage, 2022, 50: doi: 10.1016/j.est.2022.104166.
12	LIU M, OMARAA E S, QI J, et al. Review and characterisation of high-temperature phase change material candidates between 500 C and 700 ℃[J]. Renewable and Sustainable Energy Reviews, 2021, 150: doi: 10.1016/j.rser.2021.111528.
13	ZHONG L M, ZHANG X W, LUAN Y, et al. Preparation and thermal properties of porous heterogeneous composite phase change materials based on molten salts/expanded graphite[J]. Solar Energy, 2014, 107: 63-73.
14	TIAN H Q, WANG W L, DING J, et al. Thermal conductivities and characteristics of ternary eutectic chloride/expanded graphite thermal energy storage composites[J]. Applied Energy, 2015, 148: 87-92.
15	BAUER T, DRTE L, ULRIKE K, et al. Sodium nitrate for high temperature latent heat storage[C]//The 11 th International Conference on Thermal Energy Storage-Effstock. DLR, 2009.
16	HEIDENREICH G R, PAREKH M B. Thermal energy storage for organic Rankine cycle solar dynamic space power systems[J]. Proceedings of the Intersociety Energy Conversion Engineering Conference, 1986: 791-797.
17	CÁRDENAS B, LEÓN N. High temperature latent heat thermal energy storage: Phase change materials, design considerations and performance enhancement techniques[J]. Renewable and Sustainable Energy Reviews, 2013, 27: 724-737.
18	MARIANOWSKI L G, MARU H C. Latent heat thermal energy storage systems above 450 C[C]//12th Intersociety Energy Conversion Engineering Conference, 1977, 1: 555-566.
19	DULLES J F, Maru H C. Molten-salt thermal-energy storage systems[R]. CHO (Chicago Operations Office, Argonne, IL (United States)), 1977:1-129.
20	VERDIEV N N, ARBUKHANOVA P A, ISKENDEROV E G. NaF-NaBr-Na₂MoO₄ and KF-KCl-KBr ternary systems[J]. Russian Journal of Inorganic Chemistry, 2009, 54(1): 128-133.
21	PETRI R, ONG E, MARTIN J. High temperature composite thermal energy storage (TES) systems for industrial applications[R]. Institute of Gas Technology, Chicago, IL (USA); Oak Ridge National Lab. TN (USA), 1986
22	MISRA A K. Fluoride salts and container materials for thermal energy storage applications in the temperature range 973-1400 K[C]//22nd Intersociety Energy Conversion Engineering Conference. August 10-14, 1987, Philadelphia, Pennsylvania. Reston, Virginia: AIAA, 1987: doi: 10.2514/6.1987-9226.
23	BIRCHENALL C E, TELKES M. Thermal storage in metals[J]. Sharing the Sun: Solar Technology in the Seventies, 1976, 8(8): 138-154.
24	RIECHMAN A F. Heat storage in eutectic alloys[J]. Metallurgical Transactions A, 1980, 11(8): 1415-1420.
25	ACHARD P. Heat Storage at 450 deg C in Aluminum-Magnesium Alloys[J]. Rational Utilization of Energy, 1981: 39-46.
26	WANG Z Y, WANG H, LI X B, et al. Aluminum and silicon based phase change materials for high capacity thermal energy storage[J]. Applied Thermal Engineering, 2015, 89: 204-208.
27	HUANG Z G, MEI S H, WU G Z. Prospect of metal phase change thermal energy storage technologies[J]. New Energy 1999(4): 1-5.
28	SUN J Q, ZHANG R Y, LIU Z P, et al. Thermal reliability test of Al-34%Mg-6%Zn alloy as latent heat storage material and corrosion of metal with respect to thermal cycling[J]. Energy Conversion and Management, 2007, 48(2): 619-624.
29	RODRÍGUEZ-ASEGUINOLAZA J, BLANCO-RODRÍGUEZ P, RISUEÑO E, et al. Thermodynamic study of the eutectic Mg₄₉-Zn₅₁ alloy used for thermal energy storage[J]. Journal of Thermal Analysis and Calorimetry, 2014, 117(1): 93-99.
30	BLANCO-RODRÍGUEZ P, RODRÍGUEZ-ASEGUINOLAZA J, RISUEÑO E, et al. Thermophysical characterization of Mg-51%Zn eutectic metal alloy: A phase change material for thermal energy storage in direct steam generation applications[J]. Energy, 2014, 72: 414-420.
31	CHEN H X, LI J J, LI Y Y, et al. Microstructure and phase transition kinetics of Mg-Ni-Zn alloy phase change thermal storage materials[J]. Journal of Alloys and Compounds, 2020, 829: doi: 10.1016/j.jallcom.2020.154574.
32	FANG D, CHENG X M, LI Y Y, et al. Microstructure and thermal characteristics of Mg-Sn alloys as phase change materials for thermal energy storage[J]. RSC Advances, 2016, 6(98): 96327-96333.
33	FANG D, SUN Z, LI Y Y, et al. Preparation, microstructure and thermal properties of MgBi alloys as phase change materials for thermal energy storage[J]. Applied Thermal Engineering, 2016, 92: 187-193.
34	SUN Z, LI L F, CHENG X M, et al. Thermal properties and the prospects of thermal energy storage of Mg-25%Cu-15%Zn eutectic alloy as phase change material[J]. Materials (Basel, Switzerland), 2021, 14(12): doi: 10.3390/ma14123296.
35	RISUEÑO E, DOPPIU S, RODRÍGUEZ-ASEGUINOLAZA J, et al. Experimental investigation of Mg-Zn-Al metal alloys for latent heat storage application[J]. Journal of Alloys and Compounds, 2016, 685: 724-732.
36	SABOL J C, MISIOLEK W Z, OZTEKIN A, et al. Characterization of intermediate phases formed between solid nickel and liquid zinc during use as an encapsulated phase change material in solar thermal energy storage systems[J]. Metallography, Microstructure, and Analysis, 2012, 1(5): 208-216.
37	ADINBERG R, ZVEGILSKY D, EPSTEIN M. Heat transfer efficient thermal energy storage for steam generation[J]. Energy Conversion and Management, 2010, 51(1): 9-15.
38	TAO Y B, HE Y L. A review of phase change material and performance enhancement method for latent heat storage system[J]. Renewable and Sustainable Energy Reviews, 2018, 93: 245-259.
39	ZHAO C Y, WU Z G. Heat transfer enhancement of high temperature thermal energy storage using metal foams and expanded graphite[J]. Solar Energy Materials and Solar Cells, 2011, 95(2): 636-643.
40	祁先进. 金属基相变复合蓄热材料的实验研究[D]. 昆明: 昆明理工大学, 2005.
	QI X J. Experimental study on composite heat storage material with metal and molten[D]. Kunming: Kunming University of Science and Technology, 2005.
41	ZHANG P, XIAO X, MENG Z N, et al. Heat transfer characteristics of a molten-salt thermal energy storage unit with and without heat transfer enhancement[J]. Applied Energy, 2015, 137: 758-772.
42	SINGH D, KIM T, ZHAO W H, et al. Development of graphite foam infiltrated with MgCl₂ for a latent heat based thermal energy storage (LHTES) system[J]. Renewable Energy, 2016, 94: 660-667.
43	LAFDI K, MESALHY O, ELGAFY A. Graphite foams infiltrated with phase change materials as alternative materials for space and terrestrial thermal energy storage applications[J]. Carbon, 2008, 46(1): 159-168.
44	ZHAO W H, FRANCE D M, YU W H, et al. Phase change material with graphite foam for applications in high-temperature latent heat storage systems of concentrated solar power plants[J]. Renewable Energy, 2014, 69: 134-146.
45	PY X, OLIVES R, MAURAN S. Paraffin/porous-graphite-matrix composite as a high and constant power thermal storage material[J]. International Journal of Heat and Mass Transfer, 2001, 44(14): 2727-2737.
46	REN Y X, XU C, YUAN M D, et al. Ca(NO₃)₂-NaNO₃/expanded graphite composite as a novel shape-stable phase change material for mid- to high-temperature thermal energy storage[J]. Energy Conversion and Management, 2018, 163: 50-58.
47	TIAN H Q, WANG W L, DING J, et al. Preparation of binary eutectic chloride/expanded graphite as high-temperature thermal energy storage materials[J]. Solar Energy Materials and Solar Cells, 2016, 149: 187-194.
48	LIU J W, WANG Q H, LING Z Y, et al. A novel process for preparing molten salt/expanded graphite composite phase change blocks with good uniformity and small volume expansion[J]. Solar Energy Materials and Solar Cells, 2017, 169: 280-286.
49	ZHAO Y J, WANG R Z, WANG L W, et al. Development of highly conductive KNO₃/NaNO₃ composite for TES (thermal energy storage)[J]. Energy, 2014, 70: 272-277.
50	XU T, LI Y T, CHEN J Y, et al. Preparation and thermal energy storage properties of LiNO₃-KCl-NaNO₃/expanded graphite composite phase change material[J]. Solar Energy Materials and Solar Cells, 2017, 169: 215-221.
51	PETRI R, ONG E, MARIANOWSKI L. High temperature composite thermal storage systems for industrial applications[R]. Institute of Gas Technology, Chicago, IL (USA); Oak Ridge National Lab. TN (USA), 1985.
52	GOKON N, NAKANO D, INUTA S, et al. High-temperature carbonate/MgO composite materials as thermal storage media for double-walled solar reformer tubes[J]. Solar Energy, 2008, 82(12): 1145-1153.
53	YE F, GE Z W, DING Y L, et al. Multi-walled carbon nanotubes added to Na₂CO₃/MgO composites for thermal energy storage[J]. Particuology, 2014, 15: 56-60.
54	GE Z W, YE F, CAO H, et al. Carbonate-salt-based composite materials for medium-and high-temperature thermal energy storage[J]. Particuology, 2014, 15: 77-81.
55	JIANG Z, JIANG F, LI C, et al. A form stable composite phase change material for thermal energy storage applications over 700 ℃[J]. Applied Sciences, 2019, 9(5): doi: 10.3390/app9050814.
56	SANG L X, LI F, XU Y W. Form-stable ternary carbonates/MgO composite material for high temperature thermal energy storage[J]. Solar Energy, 2019, 180: 1-7.
57	JIANG Y F, SUN Y P, LI S A. Performance of novel Na₂SO₄-NaCl-ceramic composites as high temperature phase change materials for solar power plants (Part II)[J]. Solar Energy Materials and Solar Cells, 2019, 194: 285-294.
58	JIANG Y F, SUN Y P, JACOB R D, et al. Novel Na₂SO₄-NaCl-ceramic composites as high temperature phase change materials for solar thermal power plants (Part I)[J]. Solar Energy Materials and Solar Cells, 2018, 178: 74-83.
59	ZHOU W B, LI R G, ZHOU W, et al. Fabrication of Al₂O₃-NaCl composite heat storage materials by one-step synthesis method[J]. Journal of Wuhan University of Technology-Mater Sci Ed, 2016, 31(5): 950-954.
60	QIAN T T, LI J H, MIN X, et al. Radial-like mesoporous silica sphere: A promising new candidate of supporting material for storage of low-, middle-, and high-temperature heat[J]. Energy, 2016, 112: 1074-1083.
61	NOTTER W, LECHNER T, GROß U, et al. Thermophysical properties of the composite ceramic-salt system (SiO₂/Na₂SO₄)[J]. Thermochimica Acta, 1993, 218: 455-463.
62	李爱菊, 王毅. 无机盐/陶瓷基复合蓄热材料高温稳定性的研究[J]. 材料导报, 2011, 25(12): 78-81.
	LI A J, WANG Y. Study on the high temperature stability of salt/ceramic composite heat storage material[J]. Materials Review, 2011, 25(12): 78-81.
63	吴建锋, 李剑, 徐晓虹, 等. NaCl/SiC泡沫陶瓷高温复合相变蓄热材料[J]. 武汉理工大学学报, 2009, 31(17): 70-73.
	WU J F, LI J, XU X H, et al. Preparation of molten salts/ceramic-foam composites by melt infiltration method as energy storagy materials at high temperature[J]. Journal of Wuhan University of Technology, 2009, 31(17): 70-73.
64	LI Y, GUO B, HUANG G F, et al. Characterization and thermal performance of nitrate mixture/SiC ceramic honeycomb composite phase change materials for thermal energy storage[J]. Applied Thermal Engineering, 2015, 81: 193-197.
65	XU G Z, LENG G H, YANG C Y, et al. Sodium nitrate - Diatomite composite materials for thermal energy storage[J]. Solar Energy, 2017, 146: 494-502.
66	DENG Y, LI J H, NIAN HONGEN. Expanded vermiculite: A promising natural encapsulation material of LiNO₃, NaNO₃, and KNO₃ phase change materials for medium-temperature thermal energy storage[J]. Advanced Engineering Materials, 2018, 20(8): doi: 10.1002/adem.201800135.
67	LENG G H, QIAO G, JIANG Z, et al. Micro encapsulated & form-stable phase change materials for high temperature thermal energy storage[J]. Applied Energy, 2018, 217: 212-220.
68	QIAN T T, LI J H, MIN X, et al. Diatomite: A promising natural candidate as carrier material for low, middle and high temperature phase change material[J]. Energy Conversion and Management, 2015, 98: 34-45.
69	QIN Y, LENG G H, YU X, et al. Sodium sulfate-diatomite composite materials for high temperature thermal energy storage[J]. Powder Technology, 2015, 282: 37-42.
70	DENG Y, LI J H, QIAN T T, et al. Preparation and characterization of KNO₃/diatomite shape-stabilized composite phase change material for high temperature thermal energy storage[J]. Journal of Materials Science & Technology, 2017, 33(2): 198-203.
71	LIU R P, ZHANG F, SU W M, et al. Impregnation of porous mullite with Na₂SO₄ phase change material for thermal energy storage[J]. Solar Energy Materials and Solar Cells, 2015, 134: 268-274.
72	LV P Z, LIU C Z, RAO Z H. Review on clay mineral-based form-stable phase change materials: Preparation, characterization and applications[J]. Renewable and Sustainable Energy Reviews, 2017, 68: 707-726.
73	LI R G, ZHU J Q, ZHOU W B, et al. Thermal compatibility of Sodium Nitrate/Expanded Perlite composite phase change materials[J]. Applied Thermal Engineering, 2016, 103: 452-458.
74	LI R G, ZHU J Q, ZHOU W B, et al. Thermal properties of sodium nitrate-expanded vermiculite form-stable composite phase change materials[J]. Materials & Design, 2016, 104: 190-196.
75	顾华志, 韩藏娟, 张美杰, 等. 高温相变蓄热材料的封装研究及应用展望[J]. 耐火材料, 2021, 55(6): 528-532, 538.
	GU H Z, HAN C J, ZHANG M J, et al. Package research and application of high-temperature phase change heat storage materials[J]. Refractories, 2021, 55(6): 528-532, 538.
76	JIANG F, ZHANG L L, SHE X H, et al. Skeleton materials for shape-stabilization of high temperature salts based phase change materials: A critical review[J]. Renewable and Sustainable Energy Reviews, 2020, 119: doi: 10.1016/j.rser.2019.109539.
77	PINCEMIN S, OLIVES R, PY X, et al. Highly conductive composites made of phase change materials and graphite for thermal storage[J]. Solar Energy Materials and Solar Cells, 2008, 92(6): 603-613.
78	SINGH D, YU W H, ZHAO W H, et al. Development and prototype testing of MgCl₂/graphite foam latent heat thermal energy storage system[J]. Solar Energy, 2018, 159: 270-282.
79	WU Z G, ZHAO C Y. Experimental investigations of porous materials in high temperature thermal energy storage systems[J]. Solar Energy, 2011, 85(7): 1371-1380.
80	何镐东, 杨林, 曹建新. 黄磷渣与硫酸钠-氯化钠制备高温复合相变储能材料[J/OL]. 无机盐工业. [2022-07-24]. https://doi.org/10.19964/j.issn.1006-4990.2022-0140.
	HE H D, YANG L, CAO J X. Preparation of high temperature composite phase change energy storage materials by yellow phosphorus slag and Na₂SO₄-NaCl[J/OL]. Inorganic Chemicals Industry. [2022-07-24]. https://doi.org/10.19964/j.issn.1006-4990. 2022-0140.
81	刘汉昌, 朱桂花, 吕硕, 等. 相变介质组成对粉煤灰基高温定形复合相变材料蓄热性能的影响[J]. 硅酸盐通报, 2022, 41(2): 597-606.
	LIU H C, ZHU G H, LYU S, et al. Influence of phase change medium composition on heat storage performance of fly ash-based high-temperature shaped composite phase change materials[J]. Bulletin of the Chinese Ceramic Society, 2022, 41(2): 597-606.
82	韩金鹏, 朱桂花, 吕硕, 等. 相变介质粒径对粉煤灰基高温定形复合相变材料蓄热性能的影响[J]. 煤炭转化, 2019, 42(1): 78-86.
	HAN J P, ZHU G H, LYU S, et al. Effects of particle size of phase change medium on thermal storage performance of fly ash-based high temperature formstable composite phase change material[J]. Coal Conversion, 2019, 42(1): 78-86.
83	焦勇. Al-Si/Al₂O₃高温复合相变蓄热材料的制备与性能研究[D]. 西安: 西安建筑科技大学, 2012.
	JIAO Y. Study on preparation and properties of Al-Si/Al₂O₃high temperature phase change heat storage materials[D]. Xi'an: Xi'an University of Architecture and Technology, 2012.
84	王建宏. 粉煤灰基高温复合相变蓄热材料的制备与性能研究[D]. 西安: 西安建筑科技大学, 2013.
	WANG J H. Study on preparation and properties of high temperature fly ash base phase change heat storage composite materials[D]. Xi'an: Xi'an University of Architecture and Technology, 2013.
85	HAN C J, GU H Z, ZHANG M J, et al. Preparation and characterization of a heat storage ceramic with Al-12 wt% Si as the phase change material[J]. Ceramics International, 2020, 46(18): 28042-28052.
86	GUO Q, WANG T. Preparation and characterization of sodium sulfate/silica composite as a shape-stabilized phase change material by Sol-gel method[J]. Chinese Journal of Chemical Engineering, 2014, 22(3): 360-364.
87	LAI C C, LIN S M, CHU Y D, et al. Tunable endothermic plateau for enhancing thermal energy storage obtained using binary metal alloy particles[J]. Nano Energy, 2016, 25: 218-224.
88	ORTEGA-FERNÁNDEZ I, RODRÍGUEZ-ASEGUINOLAZA J. Thermal energy storage for waste heat recovery in the steelworks: The case study of the REslag project[J]. Applied Energy, 2019, 237: 708-719.
89	YU Q H, JIANG Z, CONG L, et al. A novel low-temperature fabrication approach of composite phase change materials for high temperature thermal energy storage[J]. Applied Energy, 2019, 237: 367-377.
90	DAL MAGRO F, MENEGHETTI A, NARDIN G, et al. Enhancing energy recovery in the steel industry: Matching continuous charge with off-gas variability smoothing[J]. Energy Conversion and Management, 2015, 104: 78-89.
91	DAL MAGRO F, BENASCIUTTI D, NARDIN G. Thermal stress analysis of PCM containers for temperature smoothing of waste gas[J]. Applied Thermal Engineering, 2016, 106: 1010-1022.
92	DAL MAGRO F, SAVINO S, MENEGHETTI A, et al. Coupling waste heat extraction by phase change materials with superheated steam generation in the steel industry[J]. Energy, 2017, 137: 1107-1118.
93	ANDERSSON O, RYDELL L, ALGOTSSON T. Efficient usage of waste heat by applying a seasonal energy storage (BTES) at ITT Water & Wastewater AB, Emmaboda, Sweden[J]. Proceedings of Effstock, 2009: 14-17.
94	KOIDE H, KURNIAWAN A, TAKAHASHI T, et al. Performance analysis of packed bed latent heat storage system for high-temperature thermal energy storage using pellets composed of micro-encapsulated phase change material[J]. Energy, 2022, 238: doi: 10.1016/j.energy.2021.121746.
95	WANG X, LIU J, ZHANG Y P, et al. Experimental research on a kind of novel high temperature phase change storage heater[J]. Energy Conversion and Management, 2006, 47(15/16): 2211-2222.
96	李传, 司艳阳, 冷光辉, 等. 高温复合相变材料储热电暖器的储热性能[J]. 储能科学与技术, 2017, 6(4): 739-747.
	LI C, SI Y Y, LENG G H, et al. Charging behavior of an electrical storage heater using a high temperature composite phase change material[J]. Energy Storage Science and Technology, 2017, 6(4): 739-747.
97	ZHAO B, LI C, JIN Y, et al. Heat transfer performance of thermal energy storage components containing composite phase change materials[J]. IET Renewable Power Generation, 2016, 10(10): 1515-1522.
98	JIANG Y F, LIU M, SUN Y P. Review on the development of high temperature phase change material composites for solar thermal energy storage[J]. Solar Energy Materials and Solar Cells, 2019, 203: doi: 10.1016/j.solmat.2019.110164.
99	ZANGANEH G, COMMERFORD M, HASELBACHER A, et al. Stabilization of the outflow temperature of a packed-bed thermal energy storage by combining rocks with phase change materials[J]. Applied Thermal Engineering, 2014, 70(1): 316-320.
100	MATHUR A, KASETTY R, OXLEY J, et al. Using encapsulated phase change salts for concentrated solar power plant[J]. Energy Procedia, 2014, 49: 908-915.
101	STEINMANN W D, TAMME R. Latent heat storage for solar steam systems[J]. Journal of Solar Energy Engineering, 2008, 130(1): doi: 10.1115/1.2804624.
102	ZHANG H L, BAEYENS J, DEGRÈVE J, et al. Latent heat storage with tubular-encapsulated phase change materials (PCMs)[J]. Energy, 2014, 76: 66-72.
103	陈举飞. 铝基高温相变储热材料的储热性能与实际应用研究[D]. 长沙: 中南大学, 2013.
	CHEN J F. The research on heat storage performance and practical application of aluminum-based high temperature phase change thermal storage material[D]. Changsha: Central South University, 2013.
104	MEHRPOOYA M, GHORBANI B, SADEGHZADEH M. Hybrid solar parabolic dish power plant and high-temperature phase change material energy storage system[J]. International Journal of Energy Research, 2019, 43(10): 5405-5420.
105	LI C, LI Q, DING Y L. Investigation on the thermal performance of a high temperature packed bed thermal energy storage system containing carbonate salt based composite phase change materials[J]. Applied Energy, 2019, 247: 374-388.
106	张永学, 王梓熙, 鲁博辉, 等. 雪花型翅片提高相变储热单元储/放热性能[J]. 储能科学与技术, 2022, 11(2): 521-530.
	ZHANG Y X, WANG Z X, LU B H, et al. Enhancement of charging and discharging performance of a latent-heat thermal-energy storage unit using snowflake-shaped fins[J]. Energy Storage Science and Technology, 2022, 11(2): 521-530.
107	金光, 肖安汝, 刘梦云. 相变储能强化传热技术的研究进展[J]. 储能科学与技术, 2019, 8(6): 1107-1115.
	JIN G, XIAO A R, LIU M Y. Research progress on heat transfer enhancement technology of phase change energy storage[J]. Energy Storage Science and Technology, 2019, 8(6): 1107-1115.
108	王倩蓉, 李正贵, 卢昌燊, 等. 翅片式相变储能器内赤藻糖醇蓄热性能研究[J]. 热能动力工程, 2021, 36(2): 49-56.
	WANG Q R, LI Z G, LU C S, et al. Study on the thermal storage performance of erythritol in a fin type phase change energy storage device[J]. Journal of Engineering for Thermal Energy and Power, 2021, 36(2): 49-56.
109	陈东明. 管壳式蓄热器与复合相变材料的强化传热特性研究[D]. 青岛: 青岛科技大学, 2022.
	CHEN D M. Study on the enhanced heat transfer characteristics of shell-and-tube latent heat exchanger and composite phase change material[D]. Qingdao: Qingdao University of Science & Technology, 2022.
110	李亚强. 热电厂高温相变蓄热装置蓄放热特性的研究[D]. 吉林: 东北电力大学, 2022.
	LI Y Q. Study on heat storage and release characteristics of high temperature phase change heat storage device in heating and power plent[D]. Jilin: Northeast Dianli University, 2022.
111	陈园园. 新型相变蓄热换热器的设计与传热特性分析[D]. 郑州: 华北水利水电大学, 2020.
	CHEN Y Y. Design and analysis of heat transfer performance of a new phase change heat storage exchanger(PCHSE)[D]. Zhengzhou: North China University of Water Resources and Electric Power, 2020.
112	侯普民, 茅靳丰, 刘蓉蓉, 等. 环形相变单元的蓄热装置设计及运行特性[J]. 制冷学报, 2018, 39(1): 98-107.
	HOU P M, MAO J F, LIU R R, et al. Design and operating characteristics of heat storage device for annular unit[J]. Journal of Refrigeration, 2018, 39(1): 98-107.
113	SEDDEGH S, WANG X L, HENDERSON A D. A comparative study of thermal behaviour of a horizontal and vertical shell-and-tube energy storage using phase change materials[J]. Applied Thermal Engineering, 2016, 93: 348-358.

材料	过冷度/℃	材料	过冷度/℃	材料	过冷度/℃
NaF-22CaF₂-13MgF₂	15～30	CaF₂-50MgF₂	3～20	KCaF₃	20～30
NaF-40MgF₂-20CaF₂	40～60	KF-69MgF₂	20	KMgF₃	20～30
NaF-20MgF₂-16KF	20～30	NaF-60MgF₂	70～80	MgF₂-40CeF₃	7～20
NaF-23MgF₂	60～80	NaMgF₃	30～120	KF-61CaF₂	30～40

金属及金属合金	熔化温度/℃	熔化热/(kJ/kg)
Zn	419	112
Al	661	388
96Zn-4Al	381	138
86.4Al-9.4Si-4.2Sb	471	471
59Al-33Mg-6Zn	443	310
65.35Al-34.65Mg	497	285
60.8Al-33.2Cu-6Mg	506	365
64.6Al-28Cu-5.2Si-2.2Mg	507	374
68.5Al-26.5Cu-5Si	525	364
Mg	648	365
46.3Mg-53.7Zn	341	185
86Si-12Al	576	560
56Si-44Mg	946	757
49Zn-45Cu-6Mg	703	176
49.1Cu-46.3Al-4.6Si	571	406
83.14Al-11.7Si-5.16Mg	555	485
64.1Al-28Mg-5.2Si-2.2Cu	507	374
66.92Al-33.08Cu	548	372

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