Research progress of manganese/vanadium-based oxide heterostructure cathodes for zinc-ion batteries

doi:10.19799/j.cnki.2095-4239.2023.0854

Abstract

Abstract:

Aqueous zinc-ion batteries (AZIBs) have significantly shown application potential in the field of electrochemical energy storage due to their high theoretical specific capacity, high safety, low cost, simple manufacturing process, and environmental friendliness. Manganese/vanadium-based oxides are considered to be efficient cathode materials for zinc-ion batteries owing to their rich valence states, excellent structure, and high specific capacity. However, their disadvantages such as poor intrinsic conductivity, slow diffusion kinetics of zinc ions, and dissolution and structural collapse in electrochemical processes limit their further development and practical application. An effective way to alleviate the above problems is to combine manganese/vanadium-based oxides with different functional components to construct heterostructures. These heterostructures can achieve versatility and a synergistic effect by virtue of the characteristics of each component; further, they have heterogeneous interfaces with significant physical and chemical properties, thus achieving efficient zinc storage performance. Based on these developments, this review summarizes the main challenges faced by manganese/vanadium-based oxide cathodes, and focuses on the types, characteristics, preparation methods, and enhancement mechanisms of zinc storage properties of manganese/vanadium-based oxide heterostructures that have been reported in recent years. Finally, this paper discusses the future development of heterogeneous materials for cathodes of aqueous zinc-ion batteries and provides new insights for the development of electrode materials for high-performance zinc-ion batteries.

Key words: aqueous zinc-ion batteries, manganese/vanadium-based oxides, heterogeneous structure, cathode materials

CLC Number:

TM 911

Wanrui LI, Wenjun LI, Xiaoqing WANG, Shengli LU, Xilian XU. Research progress of manganese/vanadium-based oxide heterostructure cathodes for zinc-ion batteries[J]. Energy Storage Science and Technology, 2024, 13(5): 1496-1515.

Figures/Tables 12

Fig. 1

Fig. 2

Table 1

Metal-doped manganese/vanadium-based oxide heterostructures and their zinc storage properties"

Cathodes	Voltage/V	Capacity (mAh/g@A/g)	Cycling performance (cycles@A/g)	Electrolyte	Ref.
Ag-V₂O₅	0.2~1.6	200@0.2, 96@1	80(700@3)	3 mol/L Zn(CF₃SO₃)₂	[76]
Ag-V₂O₅	0.2~1.6	426@0.1, 326.1@5	270(2000@5)	2 mol/L Zn(CF₃SO₃)₂	[77]
Al-VOH	0.2~1.6	380@0.05, 245@4	236.5(3000@4)	3 mol/L Zn(CF₃SO₃)₂	[78]
Mg-MnO₂	1.0~1.8	370@0.6, 172@6	95(10000@1.5)	2 mol/L ZnSO₄+0.1 mol/L MnSO₄	[79]
δ-Ca_0.25V₂O₅·nH₂O/ δ-Zn_0.25V₂O₅·nH₂O	0.6~1.6	340@0.2C, 289@1C	68(3000@80C)	1 mol/L ZnSO₄	[80]
FeVO	0.2~1.6	214.4@0.5, 201.6@3	221.6(650@1)	3 mol/L Zn(CF₃SO₃)₂	[81]
Li₃(V₆O₁₆)	0.3~1.8	350@0.1, 189.8@1	189.8(1000@1)	3 mol/L Zn(CF₃SO₃)₂	[82]
Na₆V₁₀O₂₈	0.2~1.9	279.5@0.1, 60@2	143(2000@2)	3 mol/L Zn(CF₃SO₃)₂	[74]
NH₄V₄O₁₀	0.4~1.4	361.6@1, 252.8@10	255.5(1000@10)	2 mol/L ZnSO₄	[83]
δ-Ni_0.25V₂O₅	0.3~1.7	402@0.2, 218.3@5	214(1200@5)	3 mol/L ZnSO₄	[84]
Mg_0.34V₂O₅·0.84H₂O	0.1~1.8	353@0.1, 264@1	84(2000@5)	3 mol/L Zn(CF₃SO₃)₂	[54]
Na_0.33V₂O₅	0.2~1.6	367.1@0.1, 96.4@2	218.4(1000@1)	3 mol/L Zn(CF₃SO₃)₂	[85]
Zn_0.3V₂O₅·1.5H₂O	0.3~1.6	426@0.2, 265.2@10	214(20000@10)	3 mol/L Zn(CF₃SO₃)₂	[86]
Cu_0.06MnO₂·1.7H₂O	0.8~1.9	493.3@0.1, 350@0.5	363.7(150@0.5)	2 mol/L ZnSO₄+0.1 mol/L MnSO₄	[87]
Bi_0.09MnO₂·1.5H₂O	0.8~1.9	175.5@0.1, 116.1@1	114.5(1100@1)	2 mol/L ZnSO₄+0.1 mol/L MnSO₄	[87]
Cu-Mn₃O₄	0.8~1.9	250@0.1, 45@1	110(900@0.6)	2 mol/L ZnSO₄+0.1 mol/L MnSO₄	[88]
KMgVOH	0.2~1.5	423@0.1, 318@4	222(2000@4)	3 mol/L Zn(CF₃SO₃)₂	[89]
Al_2.65V₆O₁₃·2.07H₂O	0.2~1.4	571.7@1, 205.7@5	183.5(2000@5)	3 mol/L Zn(CF₃SO₃)₂	[90]
AlMO	0.8~1.8	311.2@0.1, 145.2@5	125.3(15000@4)	2 mol/L ZnSO₄+0.1 mol/L MnSO₄	[91]
Na₆[V₁₀O₂₈]·nH₂O	0.2~1.5	228.5@0.1, 84.6@10	119.4(3000@10)	2 mol/L Zn(CF₃SO₃)₂	[92]
NaV₈O₂₀·xH₂O	0.4~1.4	417@0.1, 111@80	214(1600@10)	3 mol/L Zn(CF₃SO₃)₂	[93]
δ-K_0.49V₂O₅	0.3~1.5	361@0.2, 150@5	154(2000@5)	3 mol/L Zn(CF₃SO₃)₂	[94]
Ag_0.33V₂O₅	0.1~1.6	311@0.1, 107@5	144(500@2)	3 mol/L Zn(CF₃SO₃)₂	[95]
Cu_0.95V₂O₅	0.2~1.6	405@0.1, 195@5	200(1000@5)	3 mol/L Zn(CF₃SO₃)₂	[96]
HNaV₆O₁₆·4H₂O	0.2~1.6	444@0.5, 328@5	307(1000@5)	3 mol/L Zn(CF₃SO₃)₂	[97]

Table 1

Fig. 3

Fig. 4

Table 2

The reported manganese/vanadium-based oxide/carbon materials heterostructure cathodes and their zinc storage properties"

Cathodes	Voltage/V	Capacity (mAh/g@A/g)	Cycling performance (cycles@A/g)	Electrolyte	Ref.
VOH-rG	0.2～1.6	466@0.1, 190@20	267(5000@10)	2 mol/L Zn(CF₃SO₃)₂	[98]
δ-MnO₂-C NA/CC	0.8～1.8	346.7@0.5, 187.8@4	147(50000@4)	2 mol/L ZnSO₄+0.1 mol/L MnSO₄	[99]
$α$ -V₂O₅@C	0.3～1.9	448@0.15, 170@10	176(1500@10)	3 mol/L Zn(CF₃SO₃)₂	[100]
Cu_0.26V₂O₅@C	0.3～1.6	330@0.2, 163.8@2	175(500@2)	3 mol/L Zn(CF₃SO₃)₂	[101]
Ni_0.006Ca_0.0045VO₂@C	0.3～1.8	433.8@0.1, 158.8@5	74(4000@5)	2 mol/L ZnSO₄	[102]
VO₂@C	0.2～1.4	281@0.2, 202@5	195(1000@5)	3 mol/L Zn(CF₃SO₃)₂	[103]
Mn₃O₄@HCFs	0.9～1.85	215.8@0.3, 115.7@2	225(1300@0.4)	2 mol/L ZnSO₄+0.15 mol/L MnSO₄	[104]
MnO₂@CNTs/CNHs	1.0～1.9	343@0.3, 191.3@3	162.3(500@3)	2 mol/L ZnSO₄+0.1 mol/L MnSO₄	[105]
NiMn₂O₄@C	1.0～1.85	139.7@0.05, 98.5@1.2	128.8(850@0.4)	2 mol/L ZnSO₄+0.15 mol/L MnSO₄	[106]
B-V₂O₃@C	0.2～1.4	422@0.2, 349@2.5	84(2000@5)	2 mol/L Zn(CF₃SO₃)₂	[107]
V₂O₃@C	0.3～1.5	350@0.1, 250@2	161(4000@5)	3 mol/L Zn(CF₃SO₃)₂	[108]
V₂O₃-C	0.2～1.8	415@0.1, 349@1	260(100@0.1)	3 mol/L Zn(CF₃SO₃)₂	[109]
H-VO₂@CC	0.1～1.3	350@0.1, 192@4	150(4500@4)	3 mol/L Zn(CF₃SO₃)₂	[110]
V₂O₅@void@V₂O₅@CFs	0.1～1.8	499@0.5, 387@16	455(100@4)	3 mol/L Zn(CF₃SO₃)₂	[111]
V₂O₅@CFC	0.005～2.0	293@0.05, 91@4	154(1000@0.5)	2 mol/L ZnSO₄+0.1 mol/L MnSO₄	[112]
MnO@C	0.3～1.8	456@0.05, 160@2	128(2000@2)	2 mol/L ZnSO₄+0.2 mol/L MnSO₄	[113]
MnO@C	0.8～1.8	210@0.1, 111@1	120.2(4500@1)	3 mol/L ZnSO₄+0.1 mol/L MnSO₄	[114]
V₂O₅@CNT	0.2～1.7	312@1, 232@10	261(2000@1)	1 mol/L ZnSO₄	[115]
α-MnO₂@CNT	1.0～1.8	308.5@0.97C, 69.5@97.4C	163(1000@32.5C)	2 mol/L ZnSO₄+0.2 mol/L MnSO₄	[116]
Zn _x MnO₂@CNTs	0.8～1.8	400@0.1, 148@3	300(100@1)	3 mol/L ZnSO₄+0.1 mol/L MnSO₄	[55]
CNTs@Mn₃O₄	0.8～1.8	310@0.1, 116@2	123(500@1)	3 mol/L ZnSO₄+0.1 mol/L MnSO₄	[117]
CuV₂O₆@RCNTs	0.3～1.5	353@0.1, 121.5@5	174.7(1400@5)	3 mol/L Zn(CF₃SO₃)₂	[118]
KV₃O₈·0.75H₂O@SWCNT	0.3～1.3	379@0.1, 206@5	200(10000@5)	4 mol/L Zn(CF₃SO₃)₂	[119]
MnO₂@MNH-CNT	1.0～1.8	236@0.4, 108@1.6	140(100@0.4)	1 mol/L ZnSO₄	[120]
V₂O₅@CNT	0.2～1.6	375@0.5, 279@10	168.5(500@10)	2 mol/L ZnSO₄	[121]
ZnMn₂O₄@CNT	0.4～1.8	220.3@0.1, 136.5@1	74.7(2000@3)	1 mol/L ZnSO₄+0.1 mol/L MnSO₄	[122]
α-MnO₂@CNT HMs	1.0～1.85	296@0.2, 80@3	82.9(10000@3)	2 mol/L ZnSO₄+0.1 mol/L MnSO₄	[123]
α-V₂O₅@CNT	0.2～1.8	480@0.5, 353@15	158(1000@30)	3 mol/L Zn(CF₃SO₃)₂	[124]
S-ZnMn₂O₄/CNTs	0.8～1.8	175.1@0.5, 128.4@1	91.7(800@1.5)	2 mol/L ZnSO₄+0.2 mol/L MnSO₄	[125]
RGO@VO₂	0.3～1.3	276@0.1, 120@35	240(1000@4)	3 mol/L Zn(CF₃SO₃)₂	[126]
CuV₂O₆@RGO	0.3～1.6	427@0.1, 241@5	285(200@2)	3 mol/L Zn(CF₃SO₃)₂	[127]
MnO₂@G	1.0～1.9	317@0.1, 112@7.5	186(2000@2)	2 mol/L ZnSO₄+0.1 mol/L MnSO₄	[128]
β-MnO₂@GO	1.05～1.8	312.4@0.25C, 94.9@10C	129.6(2000@4C)	3 mol/L ZnSO₄+0.2 mol/L MnSO₄	[129]
γ-MnO₂@G	0.8～1.8	301@0.5, 95.8@10	64(300@1)	2 mol/L ZnSO₄+0.4 mol/L MnSO₄	[130]
MnO₂@rGO	1.0～1.9	332.2@0.3, 172.3@6	165.4(500@6)	2 mol/L ZnSO₄+0.1 mol/L MnSO₄	[131]
Na/MnO₂@GCF	1.0～1.8	381.8@0.1, 94.8@3	188(1000@1)	2 mol/L ZnSO₄+0.1 mol/L MnSO₄	[132]
P-MnO_2-_x @VMG	1.0～1.8	302.8@0.5, 150.1@10	185.8(1000@2)	2 mol/L ZnSO₄+0.2 mol/L MnSO₄	[133]
ZnMn₂O₄@NG	0.8～1.8	221@0.1, 110@1	74(2500@1)	1 mol/L ZnSO₄+0.05 mol/L MnSO₄	[134]
rGO@HM-ZnMn₂O₄	0.8～1.8	188@0.3, 59@2	72.7(650@1)	1 mol/L ZnSO₄+0.05 mol/L MnSO₄	[135]
δ-Na _x V₂O₅·nH₂O@G	0.2～1.6	433.5@0.1, 244.1@5	215(1000@2)	3 mol/L Zn(CF₃SO₃)₂	[66]
H₁₁Al₂V₆O_23.2@G	0.4～1.4	305.4@1, 180.6@10	131.7(400@2)	2 mol/L ZnSO₄	[136]
Na_1.1V₃O_7.9@rGO	0.4～1.4	220@0.3, 72@2	84.8(500@1)	1 mol/L Zn(CF₃SO₃)₂	[137]
O_d-VO₂@rG	0.2～1.4	376@0.1, 116@20	186(5000@10)	2 mol/L Zn(CF₃SO₃)₂	[138]
O_v-PVO@G	0.2～1.6	583.1@0.2, 372.3@20	448.3(3000@10)	3 mol/L Zn(CF₃SO₃)₂	[139]
V₂O₅@EGO	0.2～1.6	462@0.2, 334@5	187(3000@5)	3 mol/L Zn(CF₃SO₃)₂	[140]
V₂O₅/VG/CC	0.2～1.6	370@0.2, 216@50	278(5000@2)	3 mol/L ZnSO₄	[141]
Na₅V₁₂O₃₂@G	0.2～1.6	220@0.3, 104.2@5	105(4400@5)	2 mol/L Zn(CF₃SO₃)₂	[142]
VO₂(B)/GO	0.3～1.7	423@0.5, 371@3	227(2750@15)	3 mol/L Zn(CF₃SO₃)₂	[143]

Table 2

Fig. 5

Table 3

The reported manganese/vanadium-based oxide/conductive polymer heterostructure cathodes and their electrochemical properties"

Cathodes	Voltage/V	Capacity (mAh/g @A/g)	Cycling performance (cycles@A/g)	Electrolyte	Ref.
V₂O₅@PEDOT	0.2~1.4	370.5@0.5, 175@50	310.1(1000@5)	3 mol/L Zn(CF₃SO₃)₂	[151]
O_d-V₂O₅@PEDOT	0.3~1.6	449@0.2, 358@10	318(6000@10)	3 mol/L Zn(CF₃SO₃)₂	[152]
NH₄V₃O₈@PEDOT	0.4~1.6	356.8@0.05, 163.6@10	160.6(5000@10)	3 mol/L ZnCF₃SO₃	[153]
VO@PEDOT	0.3~1.4	390@0.3, 100@20	170(1000@5)	3 mol/L ZnSO₄	[56]
V₂O₅@PEDOT/CC	0.2~1.6	360@0.1, 232@20	223.6(1000@5)	2.5 mol/L Zn(CF₃SO₃)₂	[154]
Na_0.76V₆O₁₅@PEDOT	0.3~1.5	355@0.05, 165@4	168(2600@4)	3 mol/L ZnSO₄+3 mol/L Zn(CF₃SO₃)₂	[155]
(NH₄)₂V₆O₁₆·1.5H₂O@PEDOT	0.2~1.8	344@0.5, 155@20	209(1000@10)	2.5 mol/L Zn(CF₃SO₃)₂	[150]
V₂O₅@PPy	0.3~1.6	441@0.1, 291@5	304(2000@5)	3 mol/L Zn(CF₃SO₃)₂	[156]
Mn₂O₃@PPy	0.8~1.8	337.9@0.1, 77.6@3.2	73.5(3000@3)	3 mol/L ZnSO₄+0.5 mol/L MnSO₄	[144]
MnO₂/Mn₂O₃@PPy	1.0~1.85	289.8@0.2, 199.8@3	253(1000@1)	2 mol/L ZnSO₄+0.2 mol/L MnSO₄	[146]
Fe/α-MnO₂@PPy	0.8~1.9	270@0.1, 73@1	280(100@0.1)	2 mol/L ZnSO₄+0.1 mol/L MnSO₄	[157]
β-MnO₂@PPy	0.8~1.8	361.8@0.2, 69.9@1.5	361.8(160@0.2)	2 mol/L ZnSO₄+0.1 mol/L MnSO₄	[158]
MnO _x @PPy	0.4~1.9	302@0.15, 159.9@3	113.7(1000@6)	2 mol/L ZnSO₄+0.1 mol/L MnSO₄	[159]
V₂O₅·nH₂O@PPy	0.2~1.5	383@0.1, 281@2	203(2000@4)	3 mol/L Zn(CF₃SO₃)₂	[160]
V₂O₅@PPy	0.3~1.5	374@0.2, 241@5	220(2000@10)	3 mol/L Zn(CF₃SO₃)₂	[149]
PANI@MnO₂/CC	0.8~1.8	286@0.5, 177@4	158(9000@4)	2 mol/L ZnSO₄+0.1 mol/L MnSO₄	[161]
MnO₂@PANI	1.0~1.8	280@0.2, 110@3	125(5000@2)	2 mol/L ZnSO₄+0.1 mol/L MnSO₄	[24]
MnVO@PANI	0.3~1.6	462@0.1, 290@5	246.5(10000@5)	3 mol/L Zn(CF₃SO₃)₂	[162]
Mg/PANI/V₂O₅·nH₂O	0.2~1.6	424@0.5, 158@6	78(1000@10)	3 mol/L Zn(CF₃SO₃)₂	[163]
V₂O₅·H₂O@PANI	0.4~1.6	346@0.3, 186@5	223(800@3)	3 mol/L Zn(TfO)₂+6 mol/L LiTFSI	[64]
V₂O_5-_x @PANI	0.4~1.6	283@1, 234@16	201(1000@1)	2 mol/L ZnSO₄	[145]
SP@PDA-d-δ-MnO₂	1.0~1.8	483@0.2, 80.3@2	73.3(500@1)	2 mol/L ZnSO₄	[164]
VO-DP	0.2~1.6	473@0.05, 144@10	117.5(15000@10)	2 mol/L Zn(OTF)₂	[165]

Table 3

Fig. 6

Table 4

Fig. 7

Fig. 8

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Cathodes	Voltage/V	Capacity (mAh/g@A/g)	Cycling performance (cycles@A/g)	Electrolyte	Ref.
VO₂@V₂O₅	0.2~1.6	435.4@0.2, 167.5@10	126.8(1500@10)	3 mol/L Zn(CF₃SO₃)₂	[168]
VO₂@V₂O₅	0.2~1.6	401@0.1, 178@5	167(2000@5)	2 mol/L ZnSO₄	[169]
V₃O₇@V₆O₁₃	0.2~1.4	445@0.1, 376@2	259(1000@1)	3 mol/L Zn(CF₃SO₃)₂	[166]
V₂O₅@NaV₆O₁₅	0.4~1.4	399@0.1, 275.8@1	164(2000@5)	3 mol/L ZnSO₄	[170]
V₂O₅@NaV₆O₁₅	0.2~1.8	390@0.3, 253.8@5	264(3000@5)	2 mol/L Zn(CF₃SO₃)₂	[171]
Al₂O₃@(NH₄)₂V₄O₉	0.2~1.6	269@0.5, 200@5	173(3000@5)	3 mol/L Zn(CF₃SO₃)₂	[172]
(NH₄)₂Co₂V₁₀O₂₈·16H₂O/ (NH₄)₂V₁₀O₂₅·8H₂O	0.2~1.8	367.7@0.1, 214@1	201.3(1000@1)	3 mol/L ZnSO₄	[173]
Zn₃V₃O₈@ZnO@NC	0.2~1.6	216.3@0.5, 183@3	120.5(2000@5)	3 mol/L Zn(CF₃SO₃)₂	[174]
ZnMn₂O₄@Mn₂O₃	0.8~1.9	82.6@0.5, 42.1@3.2	111.9(300@0.5)	1 mol/L ZnSO₄	[175]
ZnMn₂O₄@MnOOH	0.8~1.85	336.7@0.1, 98.5@5	81.9(1000@1)	2 mol/L ZnSO₄+0.2 mol/L MnSO₄	[176]
CeO₂/MnO _x @C	0.8~1.8	365@0.05, 70@2	130(800@0.5)	3 mol/L Zn(CF₃SO₃)₂+0.1 mol/L MnSO₄	[177]
Sn _x MnO₂@SnO₂	0.8~1.8	316.1@0.3, 179.4@2	153.4(2000@2)	2 mol/L ZnSO₄+0.1 mol/L MnSO₄	[178]
ZnMn₂O₄@Mn₂O₃	0.8~1.8	247.4@0.1, 120.2@5	108(2000@3)	2 mol/L Zn(CF₃SO₃)₂+0.1 mol/L MnSO₄	[167]
V₂O₃/V₃O₅/Zn₂VO₄@NC	0.2~1.5	358@0.2, 95.8@5	100.1(3000@5)	2 mol/L ZnSO₄	[179]

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