Energy Storage Science and Technology ›› 2023, Vol. 12 ›› Issue (5): 1392-1408.doi: 10.19799/j.cnki.2095-4239.2023.0254

• Special Issue on Key Materials and Recycling Technologies for Energy Storage Batteries • Previous Articles     Next Articles

Advances in the research of quantum dots anode for alkali metal ion batteries

Junlong ZHOU(), Lukang ZHAO, Zhaomeng LIU, Xuanwen GAO(), Wenbin LUO   

  1. School of Metallurgy, Northeastern University, Shenyang 110000, Liaoning, China
  • Received:2023-03-21 Revised:2023-04-22 Online:2023-05-05 Published:2023-05-29
  • Contact: Xuanwen GAO E-mail:2271862@stu.neu.edu.cn;gaoxuanwen@mail.neu.edu.cn

Abstract:

As an important component of alkali metal ion batteries, the anode has a huge impact on the performance of the batteries. Traditional anode such as graphene are difficult to meet the future demand for energy storage due to their low specific capacity. Therefore, it is crucial to find anode materials with high specific capacity, excellent cycling performance and stability performance. Quantum dots are widely used for compositing with anode due to their fine size and huge specific surface areas. This anode composite with quantum dot structure shows excellent electrochemical performance in alkali metal ion batteries. However, there is a lack of review and outlook on the research of quantum dots and their composites for the anode of alkali metal ion batteries. In this paper, six aspects of quantum dots, namely, metal oxide quantum dots, metal sulfide quantum dots, metal nitride quantum dots, carbon quantum dots, monolithic quantum dots and other types of quantum dots for alkali metal ion batteries are reviewed. They are focused on the mechanism of action and electrochemical properties of various types of quantum dots for composite materials. Quantum dot composite anode materials can effectively shorten the diffusion path of alkali metal ions, provide more active sites and have higher cycle stability, and are expected to become the most promising anode materials for alkali metal ion batteries. Besides, this paper analyze the problems of quantum dot anode composites, and also make an outlook on the future development of quantum dots and their composites in the field of batteries: ① Optimize quantum dots synthesis path; ② Clarify the mechanism of action of quantum dots; ③ Reduce side effect; ④ Select more suitable host materials.

Key words: alkali metal ion batteries, quantum dots, anode, composite materials, electrochemical performance

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