锂离子电池基础科学问题（X）——全固态锂离子电池

doi:10.3969/j.issn.2095-4239.2014.04.012

摘要/Abstract

摘要： 商用锂离子电池由于采用含有易燃有机溶剂的液体电解质，存在着安全隐患。发展全固态锂离子电池是提升电池安全性的可行技术途径之一。目前全固态锂离子电池的应用还需要解决一些科学与技术问题，包括：开发能在宽温度范围使用，兼顾高电导率与电化学稳定性的固体电解质材料；减小电解质相与电极相界面间离子输运电阻的技术；适合全固态电池使用的正负极材料；相关材料与电池的设计与规模化制造技术。本文从固体电解质材料的研究开发进展，高通量计算用于固体电解质材料的筛选以及电极材料与固体电解质界面问题等方面进行了小结。

关键词: 储能, 全固态锂离子电池, 固体电解质, 高通量计算, 界面

Abstract: Commercial lithium ion batteries using flammable nonaqueous electrolytes have that hidden safety problems. All-solid-state lithium ion batteries is one of the possible technologic approaches to address this problem. For practical applications, some scientific and technological barriers need to be overcome, including exploring solid electrolyte material with high conductivity and electrochemical stability; decreasing interface ionic transport resistance between solid electrolyte and electrode phase; suitable anode and cathode materials for all-solid batteries; production technologies for materials；design and manufacturing of batteries. This paper summarizes briefly the status of solid electrolyte materials, efforts of high-throughput calculation on solid electrolyte materials and the interface issues between electrode material and solid electrolyte.

Key words: energy storage, all-solid-state lithium-ion battery, solid electrolyte, high-throughput calculation, interface

中图分类号:

O646.21

张舒, 王少飞, 凌仕刚, 高健, 吴娇杨, 肖睿娟, 李泓, 陈立泉. 锂离子电池基础科学问题（X）——全固态锂离子电池[J]. 储能科学与技术, 2014, 3(4): 376-394.

ZHANG Shu, WANG Shaofei, LING Shigang, GAO Jian, WU Jiaoyang, XIAO Ruijuan, LI Hong, CHEN Liquan. Fundamental scientific aspects of lithium ion batteries(X)—All-solid-state lithium-ion batteries[J]. Energy Storage Science and Technology, 2014, 3(4): 376-394.

参考文献

[1] Fenton D E,Parker J M,Wright P V. Complexes of alkali metal ions with poly (ethylene oxide)[J]. Polymer ,1973,14(11):589.
[2] Wright P V. Electrical conductivity in ionic complexes of poly(ethylene oxide)[J]. British Polymer Journal ,1975,7(5):319-327.
[3] Armnd M B,Chabagno J M,Duclot M J.Poly-ethers as solid electrolyter[C]//Lake Geneva:Fast Ion Transport in Solids Electrodes and Electrolytes,1979:131-136.
[4] Kamaya N,Homma K,Yamakawa Y, et al . A lithium superionic conductor[J]. Nature Materials ,2011,10(9):682-689.
[5] Brous J,Fankuchen I,Banks E. Rare earth titanates with a perovskite structure[J]. Acta Cryst. ,1953,6(1):67-70.
[6] Inaguma Yoshiyuki,Chen Liquan,Mitsuru Itoh. High ionic conductivity in lithium lanthanum titanate[J]. Solid State Communications ,1993,86(10):689-693.
[7] Fourquet J L,Duroy H,Crosnier-Lopez M P. Structural and microstructural studies of the series La 2/3- x Li 3 x □ 1/3-2 x TiO 3 [J]. Journal of Solid State Chemistry ,1996,127(2):283-294.
[8] Emery J,Buzare J Y,Bohnke O, et al . Lithium-7NMR and ionic conductivity studies of lanthanum[J]. Solid State Ionics ,1997,99(1-2):41-51.
[9] Bohnke O. The fast lithium-ion conducting oxides Li 3 x La 2/3- x TiO 3 from fundamentals to application[J]. Solid State Ionics ,2008,179(1-6):9-15.
[10] Shan YueJin,Chen Liquan,Inaguma Yoshiyuki, et al . Oxide cathode with perovskite structure for rechargeable lithium[J]. Journal of Power Sources ,1995,54(2):397-402.
[11] Zhao Y S,Daemen L L. Superionic conductivity in lithium-rich anti-perovskites[J]. J. Am. Chem. Soc .,2012,134(36):15042-15048.
[12] Reckeweg O,Blaschkowski B,Schleid T. Li 5 OCl 3 and Li 3 OCl:Two remarkably different lithium oxide chlorides[J]. Z. Anorg. Allg. Chem. ,2012,638(12-13):2081-2086.
[13] Emly A,Kioupakis E,Ven Van der A. Phase stability and transport mechanisms in antiperovskite Li 3 OCl and Li 3 OBr superionic conductors[J]. Chem. Mater. ,2013,25(23):4663-4670.
[14] Mouta R,Silva R X,Paschoal C W A. Tolerance factor for pyrochlores and related structures[J]. Acta Crystallogr B ,2013,69:439-445.
[15] Zhang Y,Zhao Y S,Chen C F. Ab initio study of the stabilities of and mechanism of superionic transport in lithium-rich antiperovskites[J]. Phys. Rev. B ,2013,87(13):134303 .
[16] Schroeder D J,Hubaud A A,Vaughey J T. Stability of the solid electrolyte Li 3 OBr to common battery solvents[J]. Mater. Res. Bull. ,2014,49:614-617.
[17] Weiss E,Hensel H,Kuhr H. Radiological and nuclear magnetic broad line resonance of lithium halide monohydrate[J]. Chem. Ber.-Recl. ,1969,102(2):632.
[18] Rudo K,Hartwig P,Weppner W. Ionic conductivities and phase-equilibria of the lithium iodide hydrates[J]. Rev. Chim. Miner. ,1980,17(4):420-429.
[19] Hartwig P,Rabenau A,Weppner W. Lithium hydroxide halides-phase-equilibria and ionic conductivities[J]. J. Less.-Common. Met. ,1981,78(2):227-233.
[20] Andersen N H,Kjems J K,Poulsen F W. Neutron-scattering studies of the ionic conductor LiI·D 2 O[J]. Phys. Scripta. ,1982,25(6):780-784.
[21] Nakamura O,Goodenough J B. Conductivity enhancement of lithium bromide monohydrate by Al 2 O 3 particles[J]. Solid State Ionics ,1982,7(2):119-123.
[22] Nakamura O,Goodenough J B. Fast lithium-ion transport in composites containing lithium bromide dihydrate[J]. Solid State Ionics ,1982,7(2):125-128.
[23] Barlage H,Jacobs H. Li 2 I(OH):A compound with one-dimensional infinite edge-sharing [Li 4/2 (OH) + ] pyramids[J]. Z. Anorg. Allg. Chem. ,1994,620(3):475-478.
[24] Barlage H,Jacobs H. Unusual coordination polyhedra around oxygen in Li 4 Cl(OH) 3 [J]. Z. Anorg. Allg. Chem. ,1994,620(3):471-474.
[25] Barlage H,Jacobs H. Li 2 Br(NH 2 ) - the 1st ternary alkali-metal amide halide[J]. Z. Anorg. Allg. Chem. ,1994,620(3):479-482.
[26] Eilbracht C,Kockelmann W,Hohlwein D, et al. Orientational disorder in perovskite like structures of Li 2 X(OD) (X=Cl, Br) and LiBr·D 2 O[J]. Physica B ,1997,234:48-50.
[27] Schwering G,Honnerscheid A,Wullen L V, et al . High lithium ionic conductivity in the lithium halide hydrates Li 3- n (OH n )Cl (0.83≤ n ≤2) and Li 3- n (OH n )Br (1≤ n ≤2) at ambient temperatures[J]. Chem. Phys. Chem. ,2003,4(4):343-348.
[28] Lars-Oven Hagman,Peder Kierkegaard. The crystal structure of NaMe 2 IV (PO 4 ) 3 ; Me IV =Ge, Ti, Zr[J]. Acta Chemica Scandinavica ,1968,22(6):1822-1832.
[29] Goodenough J B,Hong H Y P,Kafalas J A. Fast Na + -ion transport in skeleton structures[J]. Mater. Res. Bull. ,1976,11(2):203-220.
[30] Anantharamulu N,Koteswara R K,Rambabu G, et al . A wide-ranging review on nasicon type materials[J]. Journal of Materials Science ,2011,46(9):2821-2837.
[31] Subramanian M A，Subramanian R，Clearfield A. Lithium ion conductors in the system AB(IV)₂(PO₄)₃(B = Ti, Zr and Hf)[J]. Solid State Ionics，1986，18-19（1）：562-569.
[32] Aono H,Sugimoto E. Ionic conductivity of the lithium titanium phosphate [Li l+ x M x Ti 2- x (PO 4 ) 3 , M=Al, Sc, Y and La] systems[J]. Journal of Electrochemical Society ,1989,136(2):590-591.
[33] Aono H,Sugimoto E. Ionic conductivity and sinter ability of lithium titanium phosphate system[J]. Solid State Ionics ,1990,40-41(1):38-42.
[34] Aono H,Sugimoto E. Electrical property and sinterability of LiTi 2 (PO 4 ) 3 mixed with lithium salt (Li 3 PO 4 or Li 3 BO 3 )[J]. Solid State Ionics ,1991,47(3-4):257-264.
[35] Fu Jie. Fast Li + ion conduction in Li 2 O-A1 2 O 3 -TiO 2 -SiO 2 -P 2 O 5 glass-ceramics[J]. Journal of the American Ceramic Society ,1997,80(7):1901-1903.
[36] Birke P,Salam F,Doring S, et al . A ﬁrst approach to a monolithic all solid state inorganic lithium[J]. Solid State Ionics ,1999,118(1-2):149-157.
[37] Kitaura Hirokazu,Zhou Haoshen. Electrochemical performance of solid-state lithium-air batteries using carbon nanotube catalyst in the air electrode[J]. Advanced Energy Materials ,2012,2(7):889-894.
[38] Ferg E,Gummow R J,Kock A D. Spinel anodes for lithium-ion batteries[J]. Journal of Electrochemical Society ,1994,141(11):147-150.
[39] Hong H Y P. Crystal structure and ionic conductivity of Li 14 Zn(GeO 4 ) 4 and other new Li + superionic conductors[J]. Mater. Res. Bull. ,1978,13(8):117-124.
[40] Bruce P G,West A R. The AC conductivity of polycrystalline LISICON, Li 2+ x ZnGeO 4 , and a model for intergranular constriction resistances[J]. Journal of Electrochemical Society ,1983,130(3): 662-669.
[41] Robertson A D,West A R,Ritchie A G. Solid state ionics-review of crystalline lithium-ion conductors suitable for high temperature battery applications[J]. Solid State Ionics ,1997,104(1-2):1-11.
[42] Bruce P G,West A R. Phase diagram of the LISICON, solid electrolyte system, Li 4 GeO 4 -Zn 2 GeO 4 [J]. Mater. Res. Bull. ,1980,3:379-385.
[43] Bruce P G,West A R,David W I F. Structure determination of LISICON solid solutions by powder neutron diffraction[J]. J. Solid State Chem .,1988,75:390-396.
[44] Koji Fujimura,Atsuto Seko,Yukinori Koyama, et al . Accelerated materials design of lithium superionic conductors based on first-principles calculations and machine learning algorithms[J]. Advanced Energy Materials ,2013,3(8):980-985.
[45] Sumathipala H H,Dissanayake M A K L,West A R. Novel Li-ion conductors and mixed conductors, Li 3+ x Si x Cr 1- x O 4 and a simple method for estimating Li + /e - transport numbers[J]. Journal of Electrochemical Society ,1995,142(7):2138-2143.
[46] Kanno R,Hata T,Kawamoto Y, et al . Synthesis of a new lithium ionic conductor, thio-LISICON-lithium germanium sulfide system[J]. Solid State Ionics ,2000,130(1-2):97-104.
[47] Murayama M,Kanno R,Irie M. Synthesis of new lithium ionic conductor thio-LISICON-lithium silicon sulfides system[J]. J. Solid State Chem .,2002,168(1):140-148.
[48] Kanno Ryoji,Murayama Masahiro. Lithium ionic conductor thio-LISICON:The Li 2 S-GeS 2 -P 2 S 5 system[J]. J. Electrochem. Soc. ,2001,148(7):A742.
[49] Mo Yifei,Shyue Ping Ong,Gerbrand Ceder. First principles study of the Li 10 GeP 2 S 12 lithium super ionic conductor material[J]. Chem. Mater. ,2012,24(1):15-17.
[50] Thangadurai V,Kaack H,Weppner W J F. Novel fast lithium ion conduction in garnet-type Li 5 La 3 M 2 O 12 (M=Nb, Ta)[J]. Journal of the American Ceramic Society ,2004,86(3):437-440.
[51] Cussen Edmund J. The structure of lithium garnets:Cation disorder and clustering in a new family of fast Li + conductors[J]. Chem. Commun. ,2006,37(15):412.
[52] Wullen L V,Echelmeyer T,Meyer H W,Wilmer D. The mechanism of Li-ion transport in the garnet Li 5 La 3 Nb 2 O 12 [J]. Physical Chemistry Chemical Physics ,2007,9(25):3298-3303.
[53] Thangadurai Venkataraman,Weppner Werner. Li 6 ALa 2 Nb 2 O 12 (A=Ca, Sr, Ba):A new class of fast lithium ion conductors with garnet-like structure[J]. Journal of the American Ceramic Society ,2005,88(2):411-418.
[54] Thangadurai V,Weppner W. Li 6 ALa 2 Ta 2 O 12 (A=Sr, Ba):Novel garnet-like oxides for fast lithium ion conduction[J]. Adv. Funct. Mater. ,2005,15(1):107-112.
[55] Thangadurai V,Weppner W. Effect of sintering on the ionic conductivity of garnet-related structure Li 5 La 3 Nb 2 O 12 and In-and K-doped Li 5 La 3 Nb 2 O 12 [J]. J. Solid State Chem. ,2006,179(4):974-984.
[56] Murugan R,Thangadurai V,Weppner W. Fast lithium ion conduction in garnet-type Li 7 La 3 Zr 2 O 12 [J]. Angewandte Chemie ,2007,46(41):7778-7781.
[57] Awaka Junji,Kijima Norihito,Hayakawa Hiroshi, et al . Synthesis and structure analysis of tetragonal Li 7 La 3 Zr 2 O 12 with the garnet-related type structure[J]. J. Solid State Chem. ,2009,182(8):2046-2052.
[58] Geiger C A,Alekseev E,Lazic B, et al . Crystal chemistry and stability of "Li 7 La 3 Zr 2 O 12 " garnet:A fast lithium-ion conductor[J]. Inorganic Chemistry ,2011,50(3):1089-1097.
[59] Boukamp B A,Huggins R A. Lithium ion conductivity in lithium nitride[J]. Physics Letters A ,1976,58(4):231-233.
[60] Hartwing P,Weppner W,Wichelhaus W. Fast ionic lithium conduction in solid lithium nitride chloride[J]. Mater. Res. Bull. ,1979,14(4):49349-49358.
[61] Jia Yongzhong,Yang Jinxian. Study of the lithium solid electrolytes based on lithium nitride chloride Li 9 N 2 Cl 3 [J] . Solid State Ionics ,1997,96:113-117.
[62] Jing Yan(景燕),Jia Yongzhong(贾永忠),Ma Peihua(马培华). Synthesis and characterization of the solid state electrolyte Li 9- nx M x N 2 Cl 3 (M=Na, Mg, Al)[J]. Chinese Journal of Inorganic Chemistry (无机化学学报),2000,16(6):921-927.
[63] Hatake S,Kuwano J,Miyamori M, et al . New lithium-ion conducting compounds 3Li 3 N-MI (M =Li, Na, K, Rb) and their application to solid-state lithium-ion cells[J]. Journal of Power Sources ,1997,68(2):416-420.
[64] Kulkarni A R,Maiti H S,Paul A. Fast ion conducting lithium glasses Review[J]. Bulletin of Materials Science ,1984,6(2):201-221.
[65] Bates J B,Dudney N J,Gruzalski G R, et al . Fabrication and characterization of amorphous lithium electrolyte thin films and rechargeable thin-film batteries[J]. Journal of Power Sources ,1993,43(1-3):103-110.
[66] Dudney N J,Neudecker B J. Solid state thin-film lithium battery systems[J]. Current Opinion in Solid State and Materials Science ,1999,4(5):479-482.
[67] Mercier R,Malugani J P,Fahys B. Superionic conduction in Li 2 S- P 2 S 5 -LiI glasses[J]. Solid State Ionics ,1981,5:663-666.
[68] Pardel A,Ribes M. Electrical properties of lithium conductive silicon sulfide glasses prepared by twin roller quenching[J]. Solid State Ionics ,1986,18-19(1):351-355.
[69] Hayashi A. Preparation and characterization of glass materials for all-solid-state lithium secondary batteries[J]. Journal of the Ceramic Society of Japan ,2007,115(2):110-117.
[70] Hayashi A,Tatsumisago M,Minami T. Structural investigation of 95(0.6Li 2 S-0.4SiS 2 )5Li 4 SiO 4 oxysulfide glass by using X-ray photoelectron spectroscopy[J]. Journal of American Ceramic Society ,1998,81(5):1305-1309.
[71] Minami T,Hayashi A,Tatsumisago M. Preparation and characterization of lithium ion-conducting oxysulfide glasses[J]. Solid State Ionics ,2000,136:1015-1023.
[72] Tatsumisago M,Hama S,Hayashi A, et al . New lithium ion conducting glass-ceramics prepared from mechanochemical Li 2 S-P 2 S 5 glasses[J]. Solid State Ionics ,2002,154-155:635-640.
[73] Liang C C. Conduction characteristics of the lithium iodide-aluminum oxide solid electrolytes[J]. J. Electrochem. Soc. ,1973,120(10):1289-1292.
[74] Maier J. Space-charge regions in solid two-phase systems and their conduction contribution-1. Conductance enhancement in the system ionic conductor-inert phase and application on AgCl-Al 2 O 3 and AgCl-SiO 2 [J]. J. Phys. Chem. Solids ,1985,46(3):309-320.
[75] Maier J. Ionic conduction in space charge regions[J]. Progress in Solid State Chemistry ,1995,23(3):171-263.
[76] Debierre J M,Knauth P,Albinet G. Enhanced conductivity in ionic conductor-insulator composites:Experiments and numerical model[J]. Appl. Phys. Lett. ,1997,71(10):1335.
[77] Knauth P. Ionic conductor composites:Theory and materials[J]. Journal of Electro Ceramics ,2000,5(2):111-125.
[78] Croce F,Appetecchi G B,Persi L, et al . Nanocomposite polymer electrolytes for lithium batteries[J]. Nature ,1998,394(6692):456-458.
[79] Bruno Scrosati,Juergen Garche. Lithium batteries:Status, prospects and future[J]. Journal of Power Sources ,2010,195(9):2419-2430.
[80] Meyer W H. Polymer electrolytes for lithium-ion batteries[J]. Adv. Mater. ,1998,10(6):439.
[81] Lightfoot P,Mehta M A,Bruce P G. Crystal-structure of the polymer electrolyte poly (ethylene oxide) 3 LICF 3 SO 3 [J]. Science ,1993,262(5135):883-885.
[82] Abraham K M,Alamgir M. Li + -conductive solid polymer electrolytes with liquid-like conductivity[J]. J. Electrochem. Soc. ,1990,137(5):1657.
[83] Gadjourova Z,Andreev Y G,Tunstall D P, et al . Ionic conductivity in crystalline polymer electrolytes[J]. Nature ,2001,412(6846):520-523.
[84] Armand M. The history of polymer electrolytes[J]. Solid State Ionics ,1994,69(3-4):309-319.
[85] Murata K,Izuchi S,Yoshihisa Y. An overview of the research and development of solid polymer electrolyte batteries[J]. Electrochim. Acta ,2000,45(8-9):1501-1508.
[86] Cui Zhenyu,Xu Youyi,Zhu Liping, et al . Preparation of PVDF/PEO-PPO-PEO blend microporous membranes for lithium ion batteries via thermally induced phase separation process[J]. J. Membrane Sci. ,2008,325(2):957-963.
[87] Pan Chunyue,Zhang Qian,Feng Qing, et al . Effect of catalyst on structure of (PEO) 8 LiClO 4 -SiO 2 composite polymer electrolyte films[J]. Journal of Central South University of Technology ,2008,15(4):438-442.
[88] Mahdi Ghelichi,Nader Taheri Qazvini,Seyed Hassan Jafari, et al . Conformational, thermal, and ionic conductivity behavior of PEO in PEO/PMMA miscible blend:Investigating the effect of lithium salt[J]. Journal of Applied Polymer Science ,2013,129(4):1868-1874.
[89] Wieczorek W,Such K,Wycislik H, et al . Modifications of crystalline-structure of PEO polymer electrolytes with ceramic additives[J]. Solid State Ionics ,1989,36(3-4):255-257.
[90] Croce F,Curini R,Martinelli A, et al . Physical and chemical properties of nano composite polymer electrolytes[J]. Journal of Physical Chemistry B ,1999,103(48):10632-10638.
[91] Quartarone E,Mustarelli P,Magistris A. PEO-based composite polymer electrolytes[J]. Solid State Ionics ,1998,110(1-2):1-14.
[92] Li Q,Sun H Y,Takeda Y, et al . Interface properties between a lithium metal electrode and a poly (ethylene oxide) based composite polymer electrolyte[J]. Journal of Power Sources ,2001,94(2):201-205.
[93] Anurova N A,Blatov V A. Analysis of ion-migration paths in inorganic frameworks by means of tilings and voronoi-dirichlet partition:A comparison[J]. Acta Crystallographica Section B : Structural Science ,2009,65:426-434.
[94] Nuspl G,Takeuchi T,Weiss A, et al . Lithium ion migration pathways in LiTi 2 (PO 4 ) 3 and related materials[J]. Journal of Applied Physics ,1999,86(10):5484-5491.
[95] Filso M O,Turner M J,Gibbs G V, et al . Visualizing lithium-ion migration pathways in battery materials[J]. Chemistry-A European Journal ,2013,19(46):15535-15544.
[96] Brown I D. Recent developments in the methods and applications of the bond valence model[J]. Chemical Reviews ,2009,109(12):6858-6866.
[97] Blatov V A,Shevchenko A P. Analysis of voids in crystal structures:The methods of 'dual' crystal chemistry[J]. Acta Crystallographica Section A ,2003,59:34-44.
[98] Adams S,Rao R P. High power lithium ion battery materials by computational design[J]. Phys. Status Solid A ,2011,208(8):1746-1753.
[99] Gao J,Chu G,He M, et al . Screening possible solid electrolytes by calculating the conduction pathways using bond valence method[J]. Sci. China-Phys. Mech. Astron. ,2014,doi:10.1007/s11433-014-5511-4.
[100] Dissanayake M A K L,Bandara L R A K,Karaliyadda L H, et al . Thermal and electrical properties of solid polymer electrolyte PEO 9 Mg(ClO 4 ) 2 incorporating nano-porous Al 2 O 3 filler[J]. Solid State Ionics ,2006,177(3-4):343-346.
[101] Shannon R D,Taylor B E,English A D, et al . New Li solid electrolytes[J]. Electrochimica Acta ,1977,22(7):783-796.
[102] Shimura T,Tokiwa Y,Iwahara H. Protonic conduction in lanthanum strontium aluminate and lanthanum mobate-based oxides at elevated temperatures[J]. Solid State Ionics ,2002,154:653-658.
[103] Rao R P,Reddy M V,Adams S, et al . Preparation and mobile ion transport studies of Ta and Nb doped Li 6 Zr 2 O 7 Li-fast ion conductors[J]. Materials Science and Engineering B : Advanced Functional Solid-State Materials ,2012,177(1):100-105.
[104] Pantyukhina M I,Zelyutin G V,Batalov N N, et al . Effect of substituting 6Li for 7Li on ionic conductivity of α-Li 3 BO 3 [J]. Russian Journal of Electrochemistry ,2000,36(7):792-795.
[105] Pantyukhina M I,Obrosov V P,Stepanov A P, et al . Study of ion transport in Li 2 ZrO 3 solid electrolytes with different lithium isotope ratios[J]. Crystallography Reports ,2004,49(4):676-679.
[106] Liu J,Xu J Y,Lin Y, et al . All-solid-state lithium ion battery:Research and industrial prospects[J]. Acta Chimica Sinica ,2013,71(6):869-878.
[107] Yamamoto K,Iriyama Y,Asaka T, et al . Direct observation of lithium-ion movement around an in-situ-formed-negative-electrode/ solid-state-electrolyte interface during initial charge-discharge reaction[J]. Electrochemistry Communications ,2012,20:113-116.
[108] Yamada H,Oga Y,Saruwatari I, et al . Local structure and ionic conduction at interfaces of electrode and solid electrolytes[J]. J. Electrochem. Soc. ,2012,159(4):A380-A385.
[109] Woo J H,Trevey J E,Cavanagh A S, et al . Nanoscale interface modification of LiCoO 2 by Al 2 O 3 atomic layer deposition for solid-state Li batteries[J]. Journal of the Electrochemical Society ,2012,159(7):A1120-A1124.
[110] Tan J J,Tiwari A. Synthesis of cubic phase Li 7 La 3 Zr 2 O 12 electrolyte for solid-state lithium-ion batteries[J]. Electrochemical and Solid State Letters ,2012,15(3):A37-A39.
[111] Shin B R,Jung Y S. All-solid-state rechargeable lithium batteries using LiTi 2 (PS 4 ) 3 cathode with Li 2 S-P 2 S 5 solid electrolyte[J]. Journal of the Electrochemical Society ,2014,161(1):A154-A159.
[112] Santhanagopalan D,Qian D,McGilvray T, et al . Interface limited lithium transport in solid-state batteries[J]. Journal of Physical Chemistry Letters ,2014,5(2):298-303.
[113] Sakuda A,Nakamoto N,Kitaura H, et al . All-solid-state lithium secondary batteries with metal-sulfide-coated LiCoO 2 prepared by thermal decomposition of dithiocarbamato complexes[J]. Journal of Materials Chemistry ,2012,22(30):15247-15254.
[114] Sagane F,Ikeda K,Okita K, et al . Effects of current densities on the lithium plating morphology at a lithium phosphorus oxynitride glass electrolyte/copper thin film interface[J]. Journal of Power Sources ,2013,233:34-42.
[115] Ruzmetov D,Oleshko V P,Haney P M, et al . Electrolyte stability determines scaling limits for solid-state 3D Li ion batteries[J]. Nano Letters ,2012,12(1):505-515.
[116] Ohtomo T,Hayashi A, Tatsumisago M, et al . All-solid-state lithium secondary batteries using the 75Li 2 S.25P 2 S 5 glass and the 70Li 2 S.30P 2 S 5 glass-ceramic as solid electrolytes[J]. Journal of Power Sources ,2013,233:231-235.
[117] Ohtomo T,Hayashi A,Tatsumisago M, et al . All-solid-state batteries with Li 2 O-Li 2 S-P 2 S 5 glass electrolytes synthesized by two-step mechanical milling[J]. Journal of Solid State Electrochemistry ,2013,17(10):2551-2557.
[118] Ohta S,Komagata S,Seki J, et al . All-solid-state lithium ion battery using garnet-type oxide and Li 3 BO 3 solid electrolytes fabricated by screen-printing[J]. Journal of Power Sources ,2013,238:53-59.
[119] Noh S,Kim J,Eom M, et al. Surface modification of LiCoO 2 with Li 3 x La 2/3- x TiO 3 for all-solid-state lithium ion batteries using Li 2 S-P 2 S 5 glass-ceramic[J]. Ceramics International ,2013,39(7):8453-8460.
[120] Liu Jin,Xu Junyi,Lin Yue, et al . All-solid-state lithium ion battery:Research and industrial prospects[J]. Acta Chimica Sinica ,2013,71(6):869.
[121] Chiku M,Tsujiwaki W,Higuchi E, et al . Determination of the rate-determining step in the electrochemical oxidation of Li metal at the Li negative electrode/Li 2 S-P 2 S 5 solid electrolyte interface[J]. Journal of Power Sources ,2013,244:675-682.
[122] Amiki Y,Sagane F,Yamamoto K, et al . Electrochemical properties of an all-solid-state lithium-ion battery with an in-situ formed electrode material grown from a lithium conductive glass ceramics sheet[J]. Journal of Power Sources ,2013,241:583-591.
[123] Aldiss M I. Multi-layered polymer electrolytes towards interfacial stability in lithium ion batteries[J]. Journal of Power Sources ,2001,94(2):219-224.
[124] Xu Xiaoxiong(许晓雄),Qiu Zhijun(邱志军),Guan Yibiao(官亦标),Huang Zhen(黄祯),Jin Yi(金翼). All-solid-state lithium-ion batteries:State-of-the-artdevelopment and perspective[J]. Energy Storage Science and Technology (储能科学与技术),2013,2(4):331-341.