Exploring the role of High Temperature Quenching in Structure and Performance of Mn-based layered cathode materials for sodium ion batteries

doi:10.19799/j.cnki.2095-4239.2024.0084

Abstract

Abstract:

As a typical class of cathode materials for sodium ion batteries, Mn-based layered cathodes have the advantages of high theoretical specific capacity, low cost and high thermal stability. However, these cathode materials have been shown to undergo structure distortion, Na⁺/vacancies ordering, and transition metal vacancy, leading to poor cyclic stability. Previous studies reported that suppressing transition metal vacancy can effectively improve the electrochemical performance of Mn-based layered cathodes. In this work, we investigated the role of high temperature liquid N₂ quenching in the structure and performance of Na_0.67Fe_1/3Co_1/3Mn_1/3O₂ (NFCMO) and Na_0.67Fe_1/3Co_1/3Mn_1/3O₂-Liquid N₂ (NFCMO-LN) cathode materials during sol-gel process. Compared with pristine NFCMO, the NFCMO-LN shows higher specific capacity and rate capability. The NFCMO and NFCMO-LN electrodes deliver 91.1 and 129.8 mAh g^-1 discharge capacity at 0.1 C in the initial cycle. Moreover, the capacity retention of NFCMO and NFCMO-LN are 100% and 90% after 100 cycles at 1C, respectively. In particular, NFCMO-LN can deliver a discharge capacity of 56.2 mAh g^-1 even at 10.0 C. The structural analysis demonstrates that liquid nitrogen quenching at high temperature can effectively suppress transition metal vacancy and increase structural stability. Our findings provide feasible strategies in structure design and electrochemical performance optimization of cathode materials for sodium ion batteries.

Key words: sodium ion battery, layered oxide, sodium manganate, lattice doping, quenching

CLC Number:

TQ 152

Shirong TAN, Wenji YIN, Cuihong ZENG, Xiaoqiong Li, Shuo YIN, Fangli JI, Sijiang HU, Hongqiang WANG, Qingyu LI. Exploring the role of High Temperature Quenching in Structure and Performance of Mn-based layered cathode materials for sodium ion batteries[J]. Energy Storage Science and Technology, doi: 10.19799/j.cnki.2095-4239.2024.0084.

Figures/Tables 6

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Table 1

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样品	Rs (ohm)	Rf (ohm)	Rct (ohm)
NFCMO首次循环之后	5.796	12.5	72.18
NFCMO-LN首次循环之后	6.616	16.15	94.07
NFCMO 100次循环之后	5.643	17.91	106.8
NFCMO-LN 100次循环之后	5.865	10.68	64.18

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