Advancements in the modification of high-voltage Ni-rich ternary cathode material LiNi0.8Co0.1Mn0.1O2 for lithium-ion batteries

doi:10.19799/j.cnki.2095-4239.2024.0432

Abstract

Abstract:

With the increasing global demand for energy, the development and utilization of new energy sources have become pressing challenges. To address energy concerns, lithium-ion batteries have seen rapid advancements over the past few decades and are now widely used in electronic devices and vehicle power supplies. The high-nickel ternary cathode material LiNi_0.8Co_0.1Mn_0.1O₂ (NCM811) is considered one of the most promising cathode materials for next-generation lithium-ion batteries due to its high energy density and cost-effectiveness. Increasing the operating voltage can significantly enhance the energy density of this electrode material. However, under high voltage, the structural stability of NCM811 is compromised due to issues such as cation mixing, crack formation and propagation, lattice oxygen release, side reactions, and lattice distortion caused by electrolyte contact. These factors lead to irreversible phase transitions, severe capacity degradation, and a sharp decline in cycling performance, hindering the large-scale application of high-voltage NCM811. This paper reviews the latest research on modification strategies for NCM811 under high voltage. It begins with an overview of the failure mechanisms of NCM811 at high voltage, followed by a discussion on how element doping, surface coating, and composite modification strategies impact its electrochemical performance and the mechanisms by which these modifications improve stability. Finally, the paper explores future directions for NCM811 improvement strategies, proposing feasible, application-oriented solutions for various modification approaches.

Key words: LiNi_0.8Co_0.1Mn_0.1O₂, cathode material, element doping, surface coating, composite modification strategy

CLC Number:

TM 911

Boyu LIU, Qing PANG, Tengfei WANG, Hongyu WANG. Advancements in the modification of high-voltage Ni-rich ternary cathode material LiNi_0.8Co_0.1Mn_0.1O₂ for lithium-ion batteries[J]. Energy Storage Science and Technology, 2024, 13(11): 3784-3795.

Figures/Tables 8

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Table 1

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References 59

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掺杂元素	主要作用	放电比容量/(mAh/g)	循环次数	容量保持率	电压范围(vs. Li/Li⁺)/V	参考文献
Mg	增加锂离子扩散通道	226.1	350	81%	3.0～4.5	[29]
Ti	增大晶格常数	196(0.5 C)	100	84%	2.8～4.6	[30]
Nb	抑制阳离子混排	222.3	100	92.3%	2.8～4.6	[31]
Al	抑制阳离子混排	174	100	86.6%	3.0～4.3	[32]
Mo	抑制阳离子混排	202.4(0.2 C)	200	94.4%	2.7～4.3	[33]
Fe	抑制阳离子混排	211.4	500	77.5%	2.7-4.5	[34]
La&Al	强化体相结构	192.7	100	97.2%	3.0～4.4	[36]
In&Sn	抑制阳离子混排	202	100	90%	2.7～4.5	[37]

包覆层	主要作用	放电比容量/(mAh/g)	循环次数	容量保持率	电压范围(vs. Li/Li⁺)/V	参考文献
FePO₄	提高电导率	218.8	100	97%	2.7～4.5	[40]
LaFeO₃	保护正极	215.4	80	64.6%	3.0～4.5	[41]
La _x Ca_1-_x [TM]O_3-_x	提高电导率	225	1000	88.3%	2.7～4.5	[42]
LBO	提高离子导电率	207.8	100	82.1%	2.7～4.5	[43]
LMNCO	提高离子电导率	230.8	500	83.4%	2.7～4.6	[44]
LiF	抑制结构退化	223	100	85%	3.0～4.6	[45]
LiAlF₄	提高电导率	206	100	95.7%	2.7～4.5	[46]

复合方式	主要作用	放电比容量/(mAh/g)	循环次数	容量保持率	电压范围(vs. Li/Li⁺)/V	参考文献
Co氧化物层和Ti掺杂	提高电导率	121(20 C)	400	92%	2.7～4.7	[52]
Sr基涂层和体掺杂	抑制晶格氧缺失	295.4	100	82.3%	2.7～4.5	[53]
La₂Ni_0.5Li_0.5O₄涂层和La³⁺掺杂	抑制副反应	229(0.2 C)	200	90.1%	2.7～4.7	[54]
Sb-Sb₂O₃	提高离子导电率	196	100	89.3%	2.75～4.4	[55]
梯度掺杂Nb，LiNbO₃包覆	稳定晶体结构	214.8	300	85.1%	3.0～4.4	[56]
Li₂SnO₃包覆，Sn⁴⁺梯度掺杂	稳定结构	218.4	200	86.5%	3.0～4.5	[57]

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Advancements in the modification of high-voltage Ni-rich ternary cathode material LiNi_0.8Co_0.1Mn_0.1O₂ for lithium-ion batteries

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