水合盐相变储能材料的研究进展

doi:10.12028/j.issn.2095-4239.2017.0003

储能科学与技术 ›› 2017, Vol. 6 ›› Issue (4): 623-632.doi: 10.12028/j.issn.2095-4239.2017.0003

水合盐相变储能材料的研究进展

孟令然1,2，郭立江1，李晓禹1，王会1，陈胜利2，周园3，李建强1

1中国科学院过程工程研究所湿法冶金清洁生产技术国家工程实验室，中国科学院绿色过程与工程重点实验室，
北京 100190；2中国石油大学(北京)化学工程学院，重质油国家重点实验室，北京 102249；
3中国科学院青海盐湖研究所青海省盐湖资源化学重点实验室，青海西宁 810008

收稿日期:2017-01-11 修回日期:2017-04-18 出版日期:2017-07-01 发布日期:2017-05-04
通讯作者: 李建强，研究员，主要研究方向为相变储能材料与储能过程，E-mail：jqli@ipe.ac.cn。
作者简介:孟令然（1990—），女，硕士研究生，主要研究方向为水合盐相变储能材料，E-mail：lrmeng@ipe.ac.cn
基金资助:
国家重点研发计划“绿色建筑及建筑工业化”重点专项子课题（2016YFC0700905），江苏省生态建材与环保装备协同创新中心/盐城工学院“用于建筑节能的高效相变保温隔热材料”项目（YCXT201609），柴达木盐湖化工科学研究联合基金项目（U1407105）。

Salt hydrate based phase change materials for thermal energy storage—A review#br#

MENG Lingran1,2, GUO Lijiang1, LI Xiaoyu1, WANG Hui1, CHEN Shengli2, ZHOU Yuan3, LI Jianqiang1

1National Engineering Laboratory for Hydrometallurgical Cleaner Production Technology, Key Laboratory of Green Process and Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China;2State Key Laboratory of Heavy Oil Processing, College of Chemical Engineering, China University of Petroleum, Beijing 102249, China; 3Key Laboratory of Salt Lake Resources Chemistry of Qinghai Province, Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xi'ning 810008, Qinghai, China

Received:2017-01-11 Revised:2017-04-18 Online:2017-07-01 Published:2017-05-04

摘要/Abstract

摘要： 水合盐相变储能材料具有储热密度大、导热系数大、相变温度适中、低价易得等优点，具有较好的应用前景，成为近年来的研究热点。本文分析了水合盐相变储能材料的研究态势；详述了国内外对水合盐相变材料的热物性及应用探索方面的研究工作及进展；针对水合盐相变储能材料在应用过程中存在的过冷、相分离及对容器腐蚀性问题的特点，详述了解决这些问题的方法及进展；对水合盐相变材料的应用及发展前景进行了展望，认为对水合盐相变材料过冷、相分离及循环稳定性问题的研究和解决方法还需要加强。

关键词: 水合盐, 储能, 相变材料, 稳定性, 腐蚀性

Abstract: Salt hydrates based phase change materials (PCMs) have a number of advantages such as high energy density, high thermal conductivity, moderate phase transition temperature and low price, making the materials promising candidates for numerous potential applications and hence a hot research topic over the past decade. This paper reviews and analyses the state-of-the-art development of the salt hydrate based PCMs and summarizes the progress in the thermophysical properties and applications of the materials. Main challenges in the industrial uptake of the salt hydrates based PCMs are supercooling, phase separation and corrosion. The progress and methods in resolving these challenges are discussed. Finally, recommendations are given for further research and applications of the salt hydrates based PCM.

Key words: salt hydrate, heat storage, phase change materials, stability, corrosion

孟令然1,2，郭立江1，李晓禹1，王会1，陈胜利2，周园3，李建强1. 水合盐相变储能材料的研究进展[J]. 储能科学与技术, 2017, 6(4): 623-632.

MENG Lingran1,2, GUO Lijiang1, LI Xiaoyu1, WANG Hui1, CHEN Shengli2, ZHOU Yuan3, LI Jianqiang1. Salt hydrate based phase change materials for thermal energy storage—A review#br#[J]. Energy Storage Science and Technology, 2017, 6(4): 623-632.

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水合盐相变储能材料的研究进展

Salt hydrate based phase change materials for thermal energy storage—A review#br#

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