储能科学与技术 ›› 2025, Vol. 14 ›› Issue (10): 3990-3995.doi: 10.19799/j.cnki.2095-4239.2025.0599

• 储能测试与评价 • 上一篇    下一篇

锂离子电池表面形变影响因素分析及在热失控预警中的应用

郭翠静(), 褚永金, 刘庆   

  1. 中国电力科学研究院有限公司,北京 100192
  • 收稿日期:2025-06-29 修回日期:2025-07-30 出版日期:2025-10-28 发布日期:2025-10-20
  • 通讯作者: 郭翠静 E-mail:guocuijing@epri.sgcc.com.cn
  • 作者简介:郭翠静(1983—),女,硕士,高级工程师,研究方向为储能技术,E-mail:guocuijing@epri.sgcc.com.cn
  • 基金资助:
    国家电网公司科技项目锂离子电池储能系统全寿命周期应用安全技术(5108-202218280A-2-85-XG)

Analysis of factors affecting surface deformation of lithium-ion battery and its application in thermal runaway early warning

Cuijing GUO(), Yongjin CHU, Qing LIU   

  1. China Electric Power Research Institute, Beijing 100192, China
  • Received:2025-06-29 Revised:2025-07-30 Online:2025-10-28 Published:2025-10-20
  • Contact: Cuijing GUO E-mail:guocuijing@epri.sgcc.com.cn

摘要:

储能是新型电力系统的重要组成部分,在实现碳达峰碳中和过程中扮演重要角色。锂离子电池在电、热、机械等内外部诱因影响下遭遇极端滥用,可能引发电站的燃烧或爆炸。长期以来,基于电池温度、气体、内阻、电压特征的锂离子电池储能安全预警技术研究受到广泛关注。本工作搭建了电池过充热失控多参量测试平台,研究方壳磷酸铁锂电池单体过充热失控过程中电压、温度与形变变化特征。结果表明:方壳磷酸铁锂电池单体大面较侧面更早探测到形变发生,由于试验中夹具的使用限制最后变形量大面小于侧面;方壳磷酸铁锂电池单体上侧传感器能够更早地发生变化;方壳磷酸铁锂电池单体形变监测相较于温度监测预警时间提前100 s,在防范储能电站事故发生及故障规模扩大方面发挥一定作用,同时为储能电池故障处理预留更多的时间。该方法为储能用锂离子电池的安全预警提供了一种新的方向,为后期储能工程应用提供了更进一步的技术支撑。

关键词: 储能, 锂离子电池, 安全预警, 表面形变

Abstract:

Energy storage is an important part of the new power system and plays an important role in achieving carbon peak and carbon neutrality. Lithium-ion may cause the power station to burn or explode when they encounter extreme abuse under the influence of internal and external triggers such as electricity, heat, and mechanics. For a long time, research on safety early warning technology for lithium-ion battery energy storage based on battery temperature, gas, internal resistance, and voltage characteristics has been widely concerned. This paper constructs a multiparameter test platform for overcharge thermal runaway of batteries and studies the voltage, temperature, and deformation change characteristics of prismatic lithium iron phosphate battery cells during the process ofcharge thermal runaway. The results show that the large surface of the prismatic lithium iron phosphate battery cell detects deformation earlier than the side surface because of the use of fixtures in experiment, and the final deformation amount of the large surface is less than that of the side surface. The upper surface sensor of the prismatic lithium iron phosphate battery cell can change. The deformation monitoring of the prismatic lithium iron phosphate battery cell is 100 seconds ahead of the temperature monitoring, which plays a certain role in preventing the occurrence of and the expansion of fault scale in energy storage power stations, and also reserves more time for the fault handling of energy storage batteries. This method provides a new direction for the safety early of lithium-ion batteries for energy storage and further technical support for the later application of energy storage projects.

Key words: energy storage, lithium-ion battery, safety warning, surface deformation

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