水系双离子电池的研究进展与展望

doi:10.19799/j.cnki.2095-4239.2023.0614

储能科学与技术 ›› 2024, Vol. 13 ›› Issue (2): 462-479.doi: 10.19799/j.cnki.2095-4239.2023.0614

水系双离子电池的研究进展与展望

郭秀丽¹(), 周小龙¹, 邹才能²(), 唐永炳¹()

^1.中国科学院深圳先进技术研究院，先进储能技术研究中心，广东深圳 518055
^2.中国石油;深圳新能源研究院，广东深圳 518118

收稿日期:2023-09-11 修回日期:2023-09-28 出版日期:2024-02-28 发布日期:2024-03-01
通讯作者: 邹才能,唐永炳 E-mail:guo@siat.ac.cn;zcn@petrochina.com.cn;tangyb@siat.ac.cn
作者简介:郭秀丽（1992—），女，博士研究生，研究方向为水系二次电池的电极材料研发，E-mail：xl. guo@siat.ac.cn；
基金资助:
国家重点研发计划(2022YFB2402600);国家自然科学基金(52272054);广东省自然科学基金(2022A1515011365);深圳市科技规划项目(JSGG20211108092801002);深圳市工程实验室基金(XMHT20220106005);中国科学院科技服务网络计划(20201600200012)

Research progress and perspectives of aqueous dual-ions batteries

Xiuli GUO¹(), Xiaolong ZHOU¹, Caineng ZOU²(), Yongbing TANG¹()

^1.Shenzhen Institutes of Advanced Technology, Chinese Academy of Sciences, Shenzhen 518055, Guangdong, China
^2.Petro China Shenzhen New Energy Research Institute, Shenzhen 518118, Guangdong, China

Received:2023-09-11 Revised:2023-09-28 Online:2024-02-28 Published:2024-03-01
Contact: Caineng ZOU, Yongbing TANG E-mail:guo@siat.ac.cn;zcn@petrochina.com.cn;tangyb@siat.ac.cn

摘要/Abstract

摘要：

随着消费电子、电动汽车与规模储能产业的迅速发展，人们对电化学储能技术的安全高效提出了更高的要求。然而，锂离子电池（LIBs）存在的安全隐患问题制约了其在规模储能市场的应用。水系双离子电池（ADIBs）是一类以水系电解液作为离子传输介质且阴、阳离子均作为载流子同时参与电极电化学反应的新型储能技术，具有安全性能优异、功率密度高、绿色环保、性价比高等优势，在大规模储能领域具有潜在的应用前景。本综述从ADIBs的基本工作原理以及限制其发展的关键科学问题出发，归纳了近年来从电解液设计角度出发，拓宽电化学稳定电压窗口的几种常用方法，并总结了在正极和负极材料优化、储能机理研究方面取得的重要进展。最后，基于对ADIBs的理解，对其研究前景和未来研究方向进行了展望。本文将为水系储能电池研究的工作者提供参考，并为推动ADIBs的发展和促进高安全储能技术的进步发挥积极作用。

关键词: 水系, 双离子电池, 电解液, 正极材料, 负极材料

Abstract:

With the rapid development of consumer electronics, electric vehicles, and large-scale energy storage industry, high requirements for the safety and efficiency of electrochemical energy storage technology. However, safety hazards associated with lithium-ion batteries limit their application in the energy storage market. Aqueous dual-ion batteries (ADIBs) have emerged as a new energy storage device that uses an aqueous electrolyte as the ion transport medium. In ADIBs, anions and cations in the electrolyte act as carriers, simultaneously participating in the electrode electrochemical reaction. ADIBs show potential application prospects in large-scale energy storage owing to their remarkable advantages, such as excellent safety performance, high power density, eco-friendliness, and high cost-effectiveness. This review delves into the working principle of ADIBs and addresses key scientific issues limiting their further development. The authors summarize various strategies to broaden the electrochemical stable voltage window, focusing on recent advances in electrolyte design. Then, the important progress made in optimizing cathode and anode materials and their energy storage mechanisms are elaborated. Finally, based on the knowledge and understanding of ADIBs, future research prospects and directions are proposed. Therefore, this study aims to provide a valuable reference for researchers in aqueous energy storage technology. This review contributes to promoting the development of ADIBs and accelerating progress in high-safety energy storage.

Key words: aqueous, dual-ion batteries, electrolytes, cathode materials, anode materials

中图分类号:

TM 911

郭秀丽, 周小龙, 邹才能, 唐永炳. 水系双离子电池的研究进展与展望[J]. 储能科学与技术, 2024, 13(2): 462-479.

Xiuli GUO, Xiaolong ZHOU, Caineng ZOU, Yongbing TANG. Research progress and perspectives of aqueous dual-ions batteries[J]. Energy Storage Science and Technology, 2024, 13(2): 462-479.

图/表 9

图1

图2

图3

图4

图5

图6

图7

图8

图9

参考文献 95

1	LI W J, YU X Z, HU N, et al. Study on the relationship between fossil energy consumption and carbon emission in Sichuan Province[J]. Energy Reports, 2022, 8: 53-62.
2	LARCHER D, TARASCON J M. Towards greener and more sustainable batteries for electrical energy storage[J]. Nature Chemistry, 2015, 7: 19-29.
3	DUAN J, TANG X, DAI H F, et al. Building safe lithium-ion batteries for electric vehicles: A review[J]. Electrochemical Energy Reviews, 2020, 3(1): 1-42.
4	ZENG X L, LI J H, LIU L L. Solving spent lithium-ion battery problems in China: Opportunities and challenges[J]. Renewable and Sustainable Energy Reviews, 2015, 52: 1759-1767.
5	JU Z N, ZHAO Q, CHAO D L, et al. Energetic aqueous batteries[J]. Advanced Energy Materials, 2022, 12(27): 2201074.
6	ZHANG H, LIU X, QIN B S, et al. Electrochemical intercalation of anions in graphite for high-voltage aqueous zinc battery[J]. Journal of Power Sources, 2020, 449: 227594.
7	OU X W, GONG D C, HAN C J, et al. Advances and prospects of dual-ion batteries[J]. Advanced Energy Materials, 2021, 11(46): 2102498.
8	WU X Y, XU Y K, ZHANG C, et al. Reverse dual-ion battery via a ZnCl₂ water-in-salt electrolyte[J]. Journal of the American Chemical Society, 2019, 141(15): 6338-6344.
9	CHEN Y Q, KANG Y Q, ZHAO Y, et al. A review of lithium-ion battery safety concerns: The issues, strategies, and testing standards[J]. Journal of Energy Chemistry, 2021, 59: 83-99.
10	WANG Q S, JIANG L H, YU Y, et al. Progress of enhancing the safety of lithium ion battery from the electrolyte aspect[J]. Nano Energy, 2019, 55: 93-114.
11	ZHANG H, LIU X, LI H H, et al. Challenges and strategies for high-energy aqueous electrolyte rechargeable batteries[J]. Angewandte Chemie (International Ed in English), 2021, 60(2): 598-616.
12	CHEN C, LEE C S, TANG Y B. Fundamental understanding and optimization strategies for dual-ion batteries: A review[J]. Nano-Micro Letters, 2023, 15(1): 121.
13	KIM H, HONG J, PARK K Y, et al. Aqueous rechargeable Li and Na ion batteries[J]. Chemical Reviews, 2014, 114(23): 11788-11827.
14	PLACKE T, HECKMANN A, SCHMUCH R, et al. Perspective on performance, cost, and technical challenges for practical dual-ion batteries[J]. Joule, 2018, 2(12): 2528-2550.
15	CHAO D L, ZHOU W H, XIE F X, et al. Roadmap for advanced aqueous batteries: From design of materials to applications[J]. Science Advances, 2020, 6(21): eaba4098.
16	LIU J L, XU C H, CHEN Z, et al. Progress in aqueous rechargeable batteries[J]. Green Energy & Environment, 2018, 3(1): 20-41.
17	EFTEKHARI A. High-energy aqueous lithium batteries[J]. Advanced Energy Materials, 2018, 8(24): 1801156.
18	ZHANG H, GUO G L, ADENUSI H, et al. Advances and issues in developing intercalation graphite cathodes for aqueous batteries[J]. Materials Today, 2022, 53: 162-172.
19	WANG S F, GUAN Y, GAN F Q, et al. Charge carriers for aqueous dual-ion batteries[J]. ChemSusChem, 2023, 16(4): e202201373.
20	BORODIN O, SELF J, PERSSON K A, et al. Uncharted waters: Super-concentrated electrolytes[J]. Joule, 2020, 4(1): 69-100.
21	SUO L M, BORODIN O, GAO T, et al. "Water-in-salt" electrolyte enables high-voltage aqueous lithium-ion chemistries[J]. Science, 2015, 350(6263): 938-943.
22	KONDO Y, MIYAHARA Y, FUKUTSUKA T, et al. Electrochemical intercalation of bis(fluorosulfonyl)amide anions into graphite from aqueous solutions[J]. Electrochemistry Communications, 2019, 100: 26-29.
23	ZHU Y P, YIN J, EMWAS A H, et al. An aqueous Mg²⁺-based dual-ion battery with high power density[J]. Advanced Functional Materials, 2021, 31(50): 2107523.
24	ALI ZAFAR Z, ABBAS G, SILHAVIK M, et al. Reversible anion intercalation into graphite from aluminum perchlorate "water‐in‐salt" electrolyte[J]. Electrochimica Acta, 2022, 404: 139754.
25	ALI ZAFAR Z, ABBAS G, KNIZEK K, et al. Chaotropic anion based "water-in-salt" electrolyte realizes a high voltage Zn-graphite dual-ion battery[J]. Journal of Materials Chemistry A, 2022, 10(4): 2064-2074.
26	CLARISZA A, BEZABH H K, JIANG S K, et al. Highly concentrated salt electrolyte for a highly stable aqueous dual-ion zinc battery[J]. ACS Applied Materials & Interfaces, 2022, 14(32): 36644-36655.
27	LI H, KURIHARA T, YANG D Y, et al. A novel aqueous dual-ion battery using concentrated bisalt electrolyte[J]. Energy Storage Materials, 2021, 38: 454-461.
28	RODRÍGUEZ-PÉREZ I A, ZHANG L, WROGEMANN J M, et al. Enabling natural graphite in high-voltage aqueous graphite \|\| Zn metal dual-ion batteries[J]. Advanced Energy Materials, 2020, 10(41): 2001256.
29	HUANG Z D, HOU Y, WANG T R, et al. Manipulating anion intercalation enables a high-voltage aqueous dual ion battery[J]. Nature Communications, 2021, 12: 3106.
30	PUTTASWAMY R, MONDAL C, MONDAL D, et al. An account on the deep eutectic solvents-based electrolytes for rechargeable batteries and supercapacitors[J]. Sustainable Materials and Technologies, 2022, 33: e00477.
31	SMITH E L, ABBOTT A P, RYDER K S. Deep eutectic solvents (DESs) and their applications[J]. Chemical Reviews, 2014, 114(21): 11060-11082.
32	WU J X, LIANG Q H, YU X L, et al. Deep eutectic solvents for boosting electrochemical energy storage and conversion: A review and perspective[J]. Advanced Functional Materials, 2021, 31(22): 2011102.
33	KIM K I, GUO Q B, TANG L T, et al. Reversible insertion of Mg-Cl superhalides in graphite as a cathode for aqueous dual-ion batteries[J]. Angewandte Chemie (International Ed in English), 2020, 59(45): 19924-19928.
34	SCHMUELLING G, PLACKE T, KLOEPSCH R, et al. X-ray diffraction studies of the electrochemical intercalation of bis(trifluoromethanesulfonyl)imide anions into graphite for dual-ion cells[J]. Journal of Power Sources, 2013, 239: 563-571.
35	MEISTER P, SIOZIOS V, REITER J, et al. Dual-ion cells based on the electrochemical intercalation of asymmetric fluorosulfonyl-(trifluoromethanesulfonyl) imide anions into graphite[J]. Electrochimica Acta, 2014, 130: 625-633.
36	KIM K I, TANG L T, MIRABEDINI P, et al. [LiCl₂]^– superhalide: A new charge carrier for graphite cathode of dual-ion batteries[J]. Advanced Functional Materials, 2022, 32(23): 2112709.
37	WROGEMANN J M, KÜNNE S, HECKMANN A, et al. Development of safe and sustainable dual-ion batteries through hybrid aqueous/nonaqueous electrolytes[J]. Advanced Energy Materials, 2020, 10(8): 1902709.
39	KIM K I, TANG L T, MURATLI J M, et al. A Graphite∥PTCDI aqueous dual-ion battery[J]. ChemSusChem, 2022, 15(5): e202102394.
40	WANG Z F, LI H F, TANG Z J, et al. Hydrogel electrolytes for flexible aqueous energy storage devices[J]. Advanced Functional Materials, 2018, 28(48): 1804560.
41	CAI S Y, CHU X Y, LIU C, et al. Water-salt oligomers enable supersoluble electrolytes for high-performance aqueous batteries[J]. Advanced Materials, 2021, 33(13): e2007470.
42	LI L W, ZHANG L S, GUO W B, et al. High-performance dual-ion Zn batteries enabled by a polyzwitterionic hydrogel electrolyte with regulated anion/cation transport and suppressed Zn dendrite growth[J]. Journal of Materials Chemistry A, 2021, 9(43): 24325-24335.
43	ZHU J J, XU Y T, FU Y J, et al. Hybrid aqueous/nonaqueous water-in-bisalt electrolyte enables safe dual ion batteries[J]. Small, 2020, 16(17): e1905838.
44	RÜDORFF W, HOFMANN U. Über graphitsalze[J]. Zeitschrift Für Anorganische Und Allgemeine Chemie, 1938, 238(1): 1-50.
45	WESSBECHER SKAF D, EDWARDS J K. Electrochemical graphite intercalation with nitric acid solutions[J]. Synthetic Metals, 1992, 46(2): 137-145.
46	NOEL M, SANTHANAM R, FRANCISCA FLORA M. Comparison of fluoride intercalation/de-intercalation processes on graphite electrodes in aqueous and aqueous methanolic HF media[J]. Journal of Power Sources, 1995, 56(2): 125-131.
47	SHPIGEL N, MALCHIK F, LEVI M D, et al. New aqueous energy storage devices comprising graphite cathodes, MXene anodes and concentrated sulfuric acid solutions[J]. Energy Storage Materials, 2020, 32: 1-10.
48	SEEL J A, DAHN J R. Electrochemical intercalation of PF₆ into graphite[J]. Journal of the Electrochemical Society, 2000, 147(3): 892.
49	ZHOU X L, LIU Q R, JIANG C L, et al. Strategies towards low-cost dual-ion batteries with high performance[J]. Angewandte Chemie (International Ed in English), 2020, 59(10): 3802-3832.
50	YANG H, SHI X Y, DENG T, et al. Carbon-based dual-ion battery with enhanced capacity and cycling stability[J]. ChemElectroChem, 2018, 5(23): 3612-3618.
51	GUO Q B, KIM K I, JIANG H, et al. A high-potential anion-insertion carbon cathode for aqueous zinc dual-ion battery[J]. Advanced Functional Materials, 2020, 30(38): 2002825.
52	LU Y, CHEN J. Prospects of organic electrode materials for practical lithium batteries[J]. Nature Reviews Chemistry, 2020, 4: 127-142.
53	XU Y, ZHOU M, LEI Y. Organic materials for rechargeable sodium-ion batteries[J]. Materials Today, 2018, 21(1): 60-78.
54	SONG Z P, ZHOU H S. Towards sustainable and versatile energy storage devices: An overview of organic electrode materials[J]. Energy & Environmental Science, 2013, 6(8): 2280-2301.
55	WAN F, ZHANG L L, WANG X Y, et al. An aqueous rechargeable zinc-organic battery with hybrid mechanism[J]. Advanced Functional Materials, 2018, 28(45): 1804975.
56	KIM C, AHN B Y, WEI T S, et al. High-power aqueous zinc-ion batteries for customized electronic devices[J]. ACS Nano, 2018, 12(12): 11838-11846.
57	ZHOU G Y, AN X Y, ZHOU C Y, et al. Highly porous electroactive polyimide-based nanofibrous composite anode for all-organic aqueous ammonium dual-ion batteries[J]. Composites Communications, 2020, 22: 100519.
58	GE J M, YI X H, FAN L, et al. An all-organic aqueous potassium dual-ion battery[J]. Journal of Energy Chemistry, 2021, 57: 28-33.
59	ZHANG H Z, ZHONG L F, XIE J H, et al. A COF-like N-rich conjugated microporous polytriphenylamine cathode with pseudocapacitive anion storage behavior for high-energy aqueous zinc dual-ion batteries[J]. Advanced Materials, 2021, 33(34): e2101857.
60	CAI Z J, HOU C W. Study on the electrochemical properties of zinc/polyindole secondary battery[J]. Journal of Power Sources, 2011, 196(24): 10731-10736.
61	CHEN C X, GAN Z Y, XU C, et al. Electrosynthesis of poly(aniline-co-azure B) for aqueous rechargeable zinc-conducting polymer batteries[J]. Electrochimica Acta, 2017, 252: 226-234.
62	MU S L, SHI Q F. Controllable preparation of poly(aniline-co-5-aminosalicylic acid) nanowires for rechargeable batteries[J]. Synthetic Metals, 2016, 221: 8-14.
63	CHEN C X, HONG X Z, CHEN A K, et al. Electrochemical properties of poly(aniline-co-N-methylthionine) for zinc-conducting polymer rechargeable batteries[J]. Electrochimica Acta, 2016, 190: 240-247.
64	GLATZ H, LIZUNDIA E, PACIFICO F, et al. An organic cathode based dual-ion aqueous zinc battery enabled by a cellulose membrane[J]. ACS Applied Energy Materials, 2019, 2(2): 1288-1294.
65	KOSHIKA K, SANO N, OYAIZU K, et al. An aqueous, electrolyte-type, rechargeable device utilizing a hydrophilic radical polymer-cathode[J]. Macromolecular Chemistry and Physics, 2009, 210(22): 1989-1995.
66	LUO Y W, ZHENG F P, LIU L J, et al. A high-power aqueous zinc-organic radical battery with tunable operating voltage triggered by selected anions[J]. ChemSusChem, 2020, 13(9): 2239-2244.
67	XIE J, YU F, ZHAO J W, et al. An irreversible electrolyte anion-doping strategy toward a superior aqueous Zn-organic battery[J]. Energy Storage Materials, 2020, 33: 283-289.
68	LIN Z Q, FAN G H, ZHANG T, et al. Solid-electrolyte interphase for ultra-stable aqueous dual-ion storage[J]. Advanced Energy Materials, 2023, 13(7): 2203532.
69	WANG N, GUO Z W, NI Z G, et al. Molecular tailoring of an n/p-type phenothiazine organic scaffold for zinc batteries[J]. Angewandte Chemie (International Ed in English), 2021, 60(38): 20826-20832.
70	ZHANG H, XU D X, WANG L P, et al. A polymer/graphene composite cathode with active carbonyls and secondary amine moieties for high-performance aqueous Zn-organic batteries involving dual-ion mechanism[J]. Small, 2021, 17(25): e2100902.
71	RODRÍGUEZ-PÉREZ I A, ZHANG L, LEONARD D P, et al. Aqueous anion insertion into a hydrocarbon cathode via a water-in-salt electrolyte[J]. Electrochemistry Communications, 2019, 109: 106599.
72	ZHANG C, MA W Y, HAN C Z, et al. Tailoring the linking patterns of polypyrene cathodes for high-performance aqueous Zn dual-ion batteries[J]. Energy & Environmental Science, 2021, 14(1): 462-472.
73	ZHANG F, ZHANG G W, YAO H, et al. Scalable in situ growth of self-assembled coordination supramolecular network arrays: A novel high-performance energy storage material[J]. Chemical Engineering Journal, 2018, 338: 230-239.
74	AUBREY M L, LONG J R. A dual-ion battery cathode via oxidative insertion of anions in a metal-organic framework[J]. Journal of the American Chemical Society, 2015, 137(42): 13594-13602.
75	WANG Z H, YAO H, ZHANG F, et al. Electro-synthesized Ni coordination supermolecular-networks-coated exfoliated graphene composite materials for high-performance asymmetric supercapacitors[J]. Journal of Materials Chemistry A, 2016, 4(42): 16476-16483.
76	TAN Y M, TAO Z R, ZHU Y F, et al. Anchoring I₃ ^- via charge-transfer interaction by a coordination supramolecular network cathode for a high-performance aqueous dual-ion battery[J]. ACS Applied Materials & Interfaces, 2022, 14(42): 47716-47724.
77	TAN Y M, CHEN Z, TAO Z R, et al. A two-dimensional porphyrin coordination supramolecular network cathode for high-performance aqueous dual-ion battery[J]. Angewandte Chemie (International Ed in English), 2023, 62(12): e202217744.
78	JIANG H, WEI Z X, MA L, et al. An aqueous dual-ion battery cathode of Mn₃O₄ via reversible insertion of nitrate[J]. Angewandte Chemie International Edition, 2019, 58(16): 5286-5291.
79	JIANG H, JI X L. Counter-ion insertion of chloride in Mn₃O₄ as cathode for dual-ion batteries: A new mechanism of electrosynthesis for reversible anion storage[J]. Carbon Energy, 2020, 2(3): 437-442.
80	XU X Q, YANG H Q, WANG X L, et al. Efficient high-rate aqueous alkaline battery with dual-ion intercalation chemistry enabled by asymmetric electrode polarization[J]. Cell Reports Physical Science, 2022, 3(8): 100981.
81	CAO X X, PAN A Q, YIN B, et al. Nanoflake-constructed porous Na₃V₂(PO₄)₃/C hierarchical microspheres as a bicontinuous cathode for sodium-ion batteries applications[J]. Nano Energy, 2019, 60: 312-323.
82	SONG W X, JI X B, WU Z P, et al. First exploration of Na-ion migration pathways in the NASICON structure Na₃V₂(PO₄)₃[J]. Journal of Materials Chemistry A, 2014, 2(15): 5358-5362.
83	NI Q, GUO Q B, REN H X, et al. Realizing the multi-electron reaction in the Na₃V₂(PO₄)₃ cathode via reversible insertion of dihydrogen phosphate anions[J]. ACS Applied Materials & Interfaces, 2022, 14(1): 1233-1240.
84	NIAN Q S, LIU S, LIU J, et al. All-climate aqueous dual-ion hybrid battery with ultrahigh rate and ultralong life performance[J]. ACS Applied Energy Materials, 2019, 2(6): 4370-4378.
85	SONG F, HU X L. Exfoliation of layered double hydroxides for enhanced oxygen evolution catalysis[J]. Nature Communications, 2014, 5: 4477.
86	LEE P K, TAN T, WANG S, et al. Robust micron-sized silicon secondary particles anchored by polyimide as high-capacity, high-stability Li-ion battery anode[J]. ACS Applied Materials & Interfaces, 2018, 10(40): 34132-34139.
87	TIAN B B, ZHENG J, ZHAO C X, et al. Carbonyl-based polyimide and polyquinoneimide for potassium-ion batteries[J]. Journal of Materials Chemistry A, 2019, 7(16): 9997-10003.
88	JIANG B, KONG T Y, CAI Z H, et al. In-situ modification of polyimide anode materials in dual-ion batteries[J]. Electrochimica Acta, 2022, 435: 141402.
89	ZHANG Y D, AN Y F, YIN B, et al. A novel aqueous ammonium dual-ion battery based on organic polymers[J]. Journal of Materials Chemistry A, 2019, 7(18): 11314-11320.
90	PERTICARARI S, SAYED-AHMAD-BARAZA Y, EWELS C, et al. Dual anion-cation reversible insertion in a bipyridinium-diamide triad as the negative electrode for aqueous batteries[J]. Advanced Energy Materials, 2018, 8(8): 1701988.
91	TAO Y P, DING C X, TAN D M, et al. Aqueous dual-ion battery based on a hematite anode with exposed{1 0 4}facets[J]. ChemSusChem, 2018, 11(24): 4269-4274.
92	WU C, KOPOLD P, DING Y L, et al. Synthesizing porous NaTi₂(PO₄)₃ nanoparticles embedded in 3D graphene networks for high-rate and long cycle-life sodium electrodes[J]. ACS Nano, 2015, 9(6): 6610-6618.
93	CHEN S Q, WU C, SHEN L F, et al. Challenges and perspectives for NASICON-type electrode materials for advanced sodium-ion batteries[J]. Advanced Materials, 2017, 29(48): 1700431.
94	ZHANG Z S, HU X Q, ZHOU Y, et al. Aqueous rechargeable dual-ion battery based on fluoride ion and sodium ion electrochemistry[J]. Journal of Materials Chemistry A, 2018, 6(18): 8244-8250.
95	YU H X, DENG C C, YAN H H, et al. Cu₃(PO₄)₂: Novel anion convertor for aqueous dual-ion battery[J]. Nano-Micro Letters, 2021, 13(1): 41.

[1]	彭可, 张志成, 胡有章, 张旭辉, 周稼辉, 李彬. 基于有限元的热力耦合场匣钵运动分析与优化[J]. 储能科学与技术, 2024, 13(2): 634-642.
[2]	杜文, 王君雷, 徐运飞, 李世龙, 王昆. 火焰喷雾热解法生产锂离子电池高镍三元正极材料的技术经济分析[J]. 储能科学与技术, 2024, 13(1): 345-357.
[3]	陈珊珊, 郑翔, 王若, 原铭蔓, 彭威, 鲁博明, 张光照, 王朝阳, 王军, 邓永红. 锂离子电池硅基负极电解液添加剂研究进展：挑战与展望[J]. 储能科学与技术, 2024, 13(1): 279-292.
[4]	戴雪娇, 闫婕, 王管, 董浩天, 蒋丹枫, 魏泽威, 孟凡星, 刘松涛, 张海涛. 铌基低温电池关键材料研究进展[J]. 储能科学与技术, 2024, 13(1): 311-324.
[5]	李顺, 黄建国, 何桂金. 木质素基碳/硫纳米球复合材料作为高性能锂硫电池正极材料[J]. 储能科学与技术, 2024, 13(1): 270-278.
[6]	王盼晴, 黄彦杰, 何一芃, 陈祁恒, 尹提, 陈伟豪, 谭磊, 宁天翔, 邹康宇, 李灵均. 高镍正极材料表面锂残渣的研究进展[J]. 储能科学与技术, 2024, 13(1): 92-112.
[7]	陈淑媛, 程晨, 夏啸, 鞠焕鑫, 张亮. 高比能二次电池正极材料的X射线谱学研究进展[J]. 储能科学与技术, 2024, 13(1): 113-129.
[8]	张新新, 申晓宇, 岑官骏, 乔荣涵, 朱璟, 郝峻丰, 孙蔷馥, 田孟羽, 金周, 詹元杰, 武怿达, 闫勇, 贲留斌, 俞海龙, 刘燕燕, 黄学杰. 锂电池百篇论文点评（2023.10.1—2023.11.30）[J]. 储能科学与技术, 2024, 13(1): 252-269.
[9]	贾铭勋, 吴桐, 杨道通, 秦小茜, 刘景海, 段莉梅. 锂硫电池电解液多功能添加剂：作用机制及先进表征[J]. 储能科学与技术, 2024, 13(1): 36-47.
[10]	张永辉, 傅杰, 李先锋, 张长昆. 原位表征技术在水系有机液流电池中的研究进展[J]. 储能科学与技术, 2023, 12(9): 2971-2984.
[11]	詹世英, 李欢欢, 胡方. 水系锌离子电容器正极材料的研究进展[J]. 储能科学与技术, 2023, 12(9): 2799-2810.
[12]	周向阳, 胡颖杰, 梁家浩, 周其杰, 文康, 陈松, 杨娟, 唐晶晶. 天然鳞片石墨球化尾料的高性能负极材料制备及储锂特性研究[J]. 储能科学与技术, 2023, 12(9): 2767-2777.
[13]	江婉薇, 梁呈景, 钱历, 刘梅城, 朱孟想, 马骏. 锡基三维石墨烯泡沫调控及其锂电池负极性能[J]. 储能科学与技术, 2023, 12(9): 2746-2751.
[14]	岑官骏, 乔荣涵, 申晓宇, 朱璟, 郝峻丰, 孙蔷馥, 张新新, 田孟羽, 金周, 詹元杰, 武怿达, 闫勇, 贲留斌, 俞海龙, 刘燕燕, 黄学杰. 锂电池百篇论文点评（2023.6.1—2023.7.31）[J]. 储能科学与技术, 2023, 12(9): 3003-3018.
[15]	张鼎, 叶子贤, 刘镇铭, 易群, 史利娟, 郭慧娟, 黄毅, 王莉, 何向明. 钠离子电池黑磷基负极材料研究进展[J]. 储能科学与技术, 2023, 12(8): 2482-2490.

水系双离子电池的研究进展与展望

Research progress and perspectives of aqueous dual-ions batteries

RichHTML

PDF

可视化

摘要/Abstract

引用本文

使用本文

图/表 9

参考文献 95

相关文章 15

编辑推荐

Metrics

本文评价