Recent development of polyanionic cathodes for second ion batteries

doi:10.19799/j.cnki.2095-4239.2021.0133

Abstract

Abstract:

Among various energy storage devices, rechargeable ion batteries (RIBs) have been commercialized in portable electronic devices, electric vehicles, etc., thanks to their advantages of excellent reversibility, long lifespan, high safety and easy-to-operate property. With the shortage of lithium and cobalt resources and the promotion of renewable energy sources, high efficient RIBs with low-cost and environmental friendly merit are urgently required, whereas their developments are limited by the lack of suitable cathode materials. Compared with other candidates, polyanionic compounds have shown virtues of diversity, structural fruitfulness, adjustable working potential and great stability, and therefore are promising cathode materials for promoting the application of next-generation RIBs. In this paper, polyanion cathode materials are systematically classified into phosphate, sulfate, single polyanion and mixed polyanion, and the crystal structure and electrochemical properties of various cathode materials are introduced in detail with LiFePO₄, Na₃V₂(PO₄)₃, NaVPO₄F, Na₂Fe₂(SO₄)₃, Li₂FeSiO₄, etc. as the representative compounds. The research progress of various kinds of polyanionic cathode materials is reviewed, and the research achievements of coating, doping and nanocrystallization of the materials are briefly summarized. Finally, the bottleneck in the development of polyanionic cathode materials, i.e., low electronic conductivity, is discussed, and the corresponding solutions are proposed.

Key words: second ion batteries, cathode, polyanionic compounds, challenges and strategies

CLC Number:

TQ 028.8

Qi YAN, Yuanqi LAN, Wenjiao YAO, Yongbing TANG. Recent development of polyanionic cathodes for second ion batteries[J]. Energy Storage Science and Technology, 2021, 10(3): 872-886.

Figures/Tables 5

References 92

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