Progress of NASICON-structured Li1+xAlxTi2-x(PO4)3 (0 ≤x≤ 0.5) solid electrolyte

doi:10.19799/j.cnki.2095-4239.2020.0135

Abstract

Abstract:

The widespread application of lithium-ion batteries greatly improves peoples’ quality of life. However, due to the use of flammable organic liquid electrolytes, there is a safety risk with traditional lithium-ion batteries and their energy density is limited. The development of all-solid-state batteries using solid electrolytes is expected to solve these problems. With high ionic conductivity, good environmental stability, and mild synthesis conditions, the NASICON-structured solid electrolyte Li₁₊_xAl_xTi_2-_x(PO₄)₃ (LATP, 0≤x≤0.5) is a fairly promising solid electrolyte. This paper first reviews the progress of LATP according to four aspects: Its crystal structure, ionic diffusion mechanism, synthetic methods, and methods to improve its ionic conductivity. In addition, with the electrochemical instability and high interface impedance of the LATP solid electrolyte against electrode active materials limiting its application in all-solid-state lithium batteries, the solutions to these key issues are summarized in the second part of the paper. Finally, it is emphasized that interface problems are the main challenge limiting the application of LATP solid electrolytes in all-solid-state batteries, necessitating the development of better strategies to further optimize the interface between LATP and electrode active materials.

Key words: LATP solid electrolyte, ionic diffusion mechanism, ionic conductivity, synthetic methods, electrode/solid electrolyte interface

CLC Number:

TM 911

Jie WU, Xiaobiao JIANG, Yang YANG, Yongmin WU, Lei ZHU, Weiping TANG. Progress of NASICON-structured Li₁₊_xAl_xTi₂_-_x(PO₄)₃(0 ≤x≤ 0.5) solid electrolyte[J]. Energy Storage Science and Technology, 2020, 9(5): 1472-1488.

Figures/Tables 1

References 121

1	ZHANG S G, UENO K, DOKKO K, et al. Recent advances in electrolytes for lithium-sulfur batteries[J]. Advanced Energy Materials, 2015, 5(16): 1500117-1500144.
2	TAKADA K. Progress in solid electrolytes toward realizing solid-state lithium batteries[J]. Journal of Power Sources, 2018, 394: 74-85.
3	FAN Lei, WEI Shuya, LI Siyuan, et al. Recent progress of the solid-state electrolytes for high-energy metal-based batteries[J]. Advanced Energy Materials, 2018, 8(11): 1702657-1702687.
4	ZHENG Feng, KOTOBUKI M, SONG Shufeng, et al. Review on solid electrolytes for all-solid-state lithium-ion batteries[J]. Journal of Power Sources, 2018, 389: 198-213.
5	SUN Chunwen, LIU Jin, GONG Yudong, et al. Recent advances in all-solid-state rechargeable lithium batteries[J]. Nano Energy, 2017, 33: 363-386.
6	YAO Xiayin, HUANG Bingxin, YIN Jingyun, et al. All-solid-state lithium batteries with inorganic solid electrolytes: Review of fundamental science[J]. Chinese Physics B, 2016, 25(1): doi: 10.1088/1674-1056/25/1/018802.
7	ZHANG Zhizhen, SHAO Yuanjun, LOSTCH B, et al. New horizons for inorganic solid state ion conductors[J]. Energy & Environmental Science, 2018, 11(8): 1945-1976.
8	DOKKO K, HOSHINA K, NAKANO H, et al. Preparation of LiMn₂O₄ thin-film electrode on Li₁₊_xAl_xTi_2-_x(PO₄)₃ NASICON-type solid electrolyte[J]. Journal of Power Sources, 2007, 174(2): 1100-1103.
9	CHEN Chunhua, XIE Song, SPERLING E, et al. Stable lithium-ion conducting perovskite lithium-strontium-tantalum-zirconium-oxide system[J]. Solid State Ionics, 2004, 167(3/4): 263-272.
10	RAMAKUMAR S, DEVIANNAPOORANI C, GHIVYA L, et al. Lithium garnets: Synthesis, structure, Li⁺ conductivity, Li⁺ dynamics and applications[J]. Progress in Materials Science, 2017, 88: 325-411.
11	NAGATA H, CHIKUSA Y. Activation of sulfur active material in an all-solid-state lithium-sulfur battery[J]. Journal of Power Sources, 2014, 263: 141-144.
12	ARBI K, ROJO J M, SANZ J. Lithium mobility in titanium based NASICON Li₁₊_xTi_2-_xAl_x(PO₄)₃ and LiTi_2-_xZr_x(PO₄)₃ materials followed by NMR and impedance spectroscopy[J]. Journal of the European Ceramic Society, 2007, 27(13/14/15): 4215-4218.
13	ZHAO Yusheng, DAEMEN L L. Superionic conductivity in lithium-rich anti-perovskites[J]. Journal of the American Chemical Society, 2012, 134(36): 15042-15047.
14	HAN Xiaogang, GONG Yunhui, FU Kun, et al. Negating interfacial impedance in garnet-based solid-state Li metal batteries[J]. Nature Materials, 2017, 16(5): 572-579.
15	LUO Wei, GONG Yunhui, ZHU Yizhou, et al. Transition from superlithiophobicity to superlithiophilicity of garnet solid-state electrolyte[J]. Journal of the American Chemical Society, 2016, 138(37): 12258-12262.
16	WANG Chengwei, GONG Yunhui, LIU Boyang, et al. Conformal, nanoscale ZnO surface modification of garnet-based solid-state electrolyte for lithium metal anodes[J]. Nano Letters, 2017, 17(1): 565-571.
17	BROEK J VAN DEN, AFYON S, RUPP J L M, et al. Interface-engineered all-solid-state Li-ion batteries based on garnet-type fast Li⁺ conductors[J]. Advanced Energy Materials, 2016, 6(19): doi: 10.1002/adma.201600736.
18	NAGAO M, HAYASHI A, TATSUMISAGO M, et al. Bulk-type lithium metal secondary battery with indium thin layer at interface between Li electrode and Li₂S-P₂S₅ solid electrolyte[J]. Electrochemistry, 2012, 80(10): 734-736.
19	ZHANG Zhihua, ZHAO Yanran, CHEN Shaojie, et al. An advanced construction strategy of all-solid-state lithium batteries with excellent interfacial compatibility and ultralong cycle life[J]. Journal of Materials Chemistry A, 2017, 5(32): 16984-16993.
20	SAKUDA A, HAYASHI A, TATSUMISAGO M, et al. Intefacial observation between LiCoO₂ electrode and Li₂S-P₂S₅ solid electrolytes of all-solid-state lithium secondary batteries using transmission electron microscopy[J]. Chemistry of Materials, 2010, 22(3): 949-956.
21	KATO T, HAMANAKA T, YAMAMOTO K, et al. In-situ Li₇La₃Zr₂O₁₂/LiCoO₂ interface modification for advanced all-solid-state battery[J]. Journal of Power Sources, 2014, 260: 292-298.
22	FU Kun, GONG Yunhui, LIU Boyang, et al. Toward garnet electrolyte-based Li metal batteries: An ultrathin, highly effective, artificial solid-state electrolyte/metallic Li interface[J]. Science Advances, 2017, 3(4): 1601659-1601669.
23	XU Kang. Nonaqueous liquid electrolytes for lithium-based rechargeable batteries[J]. Chemical Reviews, 2004, 104(10): 4303-4417.
24	KAMAYA N, HOMMA K, YAMAKAWA Y, et al. A lithium superionic conductor[J]. Nature Materials, 2011, 10(9): 682-686.
25	KATO Y, HORI S, SAITO T, et al. High-power all-solid-state batteries using sulfide superionic conductors[J]. Nature Energy, 2016, 1: doi: 10.1038/nenergy.2016.30.
26	MURAMATSU H, HAYASHI A, OHTOMO T, et al. Structural change of Li₂S-P₂S₅ sulfide solid electrolytes in the atmosphere[J]. Solid State Ionics, 2011, 182(1): 116-119.
27	BACHMAN J C, MUY S, GRIMAUD A, et al. Inorganic solid-state electrolytes for lithium batteries: Mechanisms and properties governing ion conduction[J]. Chemical Reviews, 2016, 116(1): 140-162.
28	LARRAZ G, ORERA A, SANJUAN M L. Cubic phases of garnet-type Li₇La₃Zr₂O₁₂: The role of hydration[J]. Journal of Materials Chemistry A, 2013, 1 (37): 11419-11428.
29	XIA Wenhao, XU Biyi, DUAN Huanan, et al. Ionic conductivity and air stability of Al-doped Li₇La₃Zr₂O₁₂ sintered in alumina and Pt crucibles[J]. ACS Applied Materials & Interfaces, 2016, 8(8): 5335-5342.
30	XIA Wenhao, XU Biyi, DUAN Huanan, et al. Reaction mechanisms of lithium garnet pellets in ambient air: The effect of humidity and CO₂[J]. Journal of the American Ceramic Society, 2017, 100(7): 2832-2839.
31	KOTOBUKI M, KOISHI M. Influence of precursor calcination temperature on sintering and conductivity of Li_1.5Al_0.5Ti_1.5(PO₄)₃ ceramics[J]. Journal of Asian Ceramic Societies, 2019, 7(1): 69-74.
32	MERTENS A, YU Shicheng, SCHON N, et al. Superionic bulk conductivity in Li_1.3Al_0.3Ti_1.7(PO₄)₃ solid electrolyte[J]. Solid State Ionics, 2017, 309: 180-186.
33	AONO H, SUGIMOTO E, SADAOKA Y, et al. Ionic conductivity of the lithium titanium phosphate [Li₁₊_xM_xTi_2-_x(PO₄)₃, M=Al, Sc, Y, and La] systems[J]. Journal of the Electrochemical Society, 1989, 136(2): 590-591.
34	ZHANG P, MATSUI M, TAKEDA Y, et al. Water-stable lithium ion conducting solid electrolyte of iron and aluminum doped NASICON-type LiTi₂(PO₄)₃[J]. Solid State Ionics, 2014, 263: 27-32.
35	DASHJAV E, MA Qianli, XU Qu, et al. The influence of water on the electrical conductivity of aluminum-substituted lithium titanium phosphates[J]. Solid State Ionics, 2018, 321: 83-90.
36	XIAO Wei, WANG Jingyu, FAN Linlin, et al. Recent advances in Li₁₊_xAl_xTi_2-_x(PO₄)₃ solid-state electrolyte for safe lithium batteries[J]. Energy Storage Materials, 2019, 19: 379-400.
37	ZHAI Haowei, XU Pengyu, NING Mingqiang, et al. A flexible solid composite electrolyte with vertically aligned and connected ion-conducting nanoparticles for lithium batteries[J]. Nano Letters, 2017, 17(5): 3182-3187.
38	BAN Xiaoyao, ZHANG Wenqiang, CHEN Ning, et al. A high-performance and durable poly(ethylene oxide)-based composite solid electrolyte for all solid-state lithium battery[J]. The Journal of Physical Chemistry C, 2018, 122(18): 9852-9858.
39	LI Dan, CHEN Long, WANG Tianshi, et al. 3D fiber-network-reinforced bicontinuous composite solid electrolyte for dendrite-free lithium metal batteries[J]. ACS Applied Materials & Interfaces, 2018, 10(8): 7069-7078.
40	BONIZZONI S, FERRARA, C, BERBENNI, V, et al. NASICON-type polymer-in-ceramic composite electrolytes for lithium batteries[J]. Physical Chemistry Chemical Physics, 2019, 21(11): 6142-6149.
41	LIU Lehao, CHU Lihua, JIANG Bing, et al. Li_1.4Al_0.4Ti_1.6(PO₄)₃ nanoparticle-reinforced solid polymer electrolytes for all-solid-state lithium batteries[J]. Solid State Ionics, 2019, 331: 89-95.
42	PAN Kecheng, ZHANG Lan, QIAN Weiwei, et al. A flexible ceramic/polymer hybrid solid electrolyte for solid-state lithium metal batteries[J]. Advanced Materials, 2020, 32(17): doi: 10.1002/adma.202000399.
43	余涛, 谢凯, 韩喻, 等. PEO基Li_1.5Al_0.5Ge_1.5(PO₄)₃固体复合电解质的制备[J]. 储能科学与技术, 2015, 4(3): 273-277.
	YU Tao, XIE Kai, HAN Yu, et al. Preparation and characterization of PEO based Li1_.5Al_0.5Ge1.5(PO₄)₃ solid composite electrolyte[J]. Energy Storage Science and Technology, 2015, 4(3): 273-277.
44	赵宁, 李忆秋, 郭向欣, 等. 纳米锂镧锆钽氧粉体复合聚氧化乙烯制备的固态电解质电化学性能的研究[J]. 储能科学与技术, 2016, 5(5): 754-761.
	ZHAO Ning, LI Yiqiu, GUO Xiangxin, et al. Electrochemical performance of solid state electrolytes consisting of Li_6.4La₃Zr_1.4Ta_0.6O_1.2 nanopowders dispersed in polyethylene oxides[J]. Energy Storage Science and Technology, 2016, 5(5): 754-761.
45	HONG H Y P, GOODENOUGH J B. Crystal structures and crystal chemistry in the system Na₁₊_xZr₂Si_xP_3-_xO₁₂[J]. Materials Research Bulletin, 1975, 11(2): 173-182.
46	PARK H, KANG M, PARK Y C, et al. Improving ionic conductivity of NASICON (Na₃Zr₂Si₂PO₁₂) at intermediate temperatures by modifying phase transition behavior[J]. Journal of Power Sources, 2018, 399: 329-336.
47	MOUAHID F E, BETTACH M, ZAHIR M, et al. Crystal chemistry and ion conductivity of the Na₁₊_xTi_2-_xAl_x(PO₄)₃ (0≤x≤0.9) NASICON series[J]. Journal of Materials Chemistry, 2000, 10(12): 2748-2757.
48	MA Qianli, GUIN M, NAQASH S, et al. Scandium-substituted Na₃Zr₂(SiO₄)₂(PO₄) prepared by a solution-assisted solid-state reaction method as sodium-ion conductors[J]. Chemistry of Materials, 2016, 28(13): 4821-4828.
49	KAZAKEVICIUS E, KEZIONIS A, ZUKAUSKAITE L, et al. Characterization of Na_1.3Al_0.3Zr_1.7(PO₄)₃ solid electrolyte ceramics by impedance spectroscopy[J]. Solid State Ionics, 2015, 271: 128-133.
50	BRADTMULLER H, NIETO-MUNOZ A M, ORTIZ-MOSQUERA J F, et al. Glass-to-crystal transition in the NASICON glass-ceramic system Na₁₊_xAl_xM_2-_x(PO₄)₃ (M=Ge, Ti)[J]. Journal of Non-Crystalline Solids, 2018, 489: 91-101.
51	LI Yutao, LIU Meijing, LIU Kai, et al. High Li⁺ conduction in NASICON-type Li₁₊_xY_xZr_2-_x(PO₄)₃ at room temperature[J]. Journal of Power Sources, 2013, 240: 50-53.
52	WEISS M, WEBER D A, WENYSHYN A, et al. Correlating transport and structural properties in Li₁₊_xAl_xGe_2-_x(PO₄)₃(LAGP) prepared from aqueous solution[J]. ACS Applied Materials & Interfaces, 2018, 10(13): 10935-10944.
53	ZANGINA T, HASSAN J, AZIS R S, et al. Analysis of thermal and electrical conductivity properties of Al substitution LiHf₂(PO₄)₃ chemical solid electrolyte[J]. SN Applied Sciences, 2019, 1(8): doi: 10.1007/S42452-019-0901-x.
54	CHAKIR M, JAZOULI A EL, DE WAAL D. Synthesis, crystal structure and spectroscopy properties of Na₃AZr(PO₄)₃(A=Mg, Ni) and Li_2.6Na_0.4NiZr(PO₄)₃ phosphates[J]. Journal of Solid State Chemistry, 2006, 179(6): 1883-1891.
55	ARBI K, BUCHELI W, JIMENEZ R, et al. High lithium ion conducting solid electrolytes based on NASICON Li₁₊_xAl_xM_2-_x(PO₄)₃ materials (M=Ti, Ge and 0≤x≤0.5)[J]. Journal of the European Ceramic Society, 2015, 35(5): 1477-1484.
56	TAKADA K, TANSHO M, YANASE I, et al. Lithium ion conduction in LiTi₂(PO₄)₃[J]. Solid State Ionics, 2001, 139: 241-247.
57	HE Shengnan, XU Youlong, ZHANG Baofeng, et al. Unique rhombus-like precursor for synthesis of Li_1.3Al_0.3Ti_1.7(PO₄)₃ solid electrolyte with high ionic conductivity[J]. Chemical Engineering Journal, 2018, 345: 483-491.
58	FRANCISCO B E, STOLDT C R. Lithium-ion trapping from local structural distortions in sodium super ionic conductor (NASICON) electrolytes[J]. Chemistry of Materials, 2014, 26: 4741-4749.
59	MONCHAK M, HUPFER T, SENYSHYN A, et al. Lithium diffusion pathway in Li_1.3Al_0.3Ti_1.7(PO₄)₃ (LATP) superionic conductor[J]. Inorganic Chemistry, 2016, 55(6): 2941-2945.
60	REDHAMMER G J, RETTENWANDER D, PRISTAT S, et al. A single crystal X-ray and powder neutron diffraction study on NASICON-type Li₁₊_xAl_xTi_2-_x(PO₄)₃(0≤x≤0.5) crystals: Implications on ionic conductivity[J]. Solid State Sciences, 2016, 60: 99-107.
61	ARBI K, HOELZEL M, KUHN A, et al. Structural factors that enhance lithium mobility in fast-ion Li₁₊_xTi_2-_xAl_x(PO₄)₃(0≤x≤0.4) conductors investigated by neutron diffraction in the temperature range 100～500 K[J]. Inorganic Chemistry, 2013, 52(16): 9290-9296.
62	PEREZ-ESTEBANEZ M, ISASI-MARIN J, TOBBENS D M, et al. A systematic study of NASICON-type Li₁₊_xM_xTi_2-_x(PO₄)₃(M: Cr, Al, Fe) by neutron diffraction and impedance spectroscopy[J]. Solid State Ionics, 2014, 266: 1-8.
63	BUCHARSKY E C, SCHELL K G, HINTENNACH A, et al. Preparation and characterization of sol-gel derived high lithium ion conductive NZP-type ceramics Li₁₊_xAl_xTi_2-_x(PO₄)₃[J]. Solid State Ionics, 2015, 274: 77-82.
64	HUANG Lezhi, WEN Zhaoyin, WU Meifen, et al. Electrochemical properties of Li_1.4Al_0.4Ti_1.6(PO₄)₃ synthesized by a co-precipitation method[J]. Journal of Power Sources, 2011, 196(16): 6943-6946.
65	ARBI K, MANDAL S, ROJO J M, et al. Dependence of ionic conductivity on composition of fast ionic conductors Li₁₊_xTi_2-_xAl_x(PO₄)₃, 0≤x≤0.7. A parallel NMR and electric impedance study[J]. Chemistry of Materials, 2002, 14(3): 1091-1097.
66	ADACHI G Y, IMANAKA N, AONO H. Fast Li⁺ conducting ceramic electrolytes[J]. Advanced Materials, 1996, 8(2): 127-135.
67	KOSOVA N, DEVYATKINA E, OSINTSEV D. Dispersed materials for rechargeable lithium batteries: reactive and non-reactive grinding[J]. Journal of Materials Science, 2004, 39(16/17): 5031-5036.
68	LU Xia, WANG Senhao, XIAO Ruijuan, et al. First-principles insight into the structural fundamental of super ionic conducting in NASICON MTi₂(PO₄)₃ (M=Li, Na) materials for rechargeable batteries[J]. Nano Energy, 2017, 41: 626-633.
69	LANG B, ZIEBARTH B, ELSASSER C. Lithium ion conduction in LiTi₂(PO₄)₃ and related compounds based on the NASICON structure: a first-principles study[J]. Chemistry of Materials, 2015, 27(14): 5040-5048.
70	EPP V, MA Q, HAMMER E M, et al. Very fast bulk Li ion diffusivity in crystalline Li_1.5Al_0.5Ti_1.5(PO₄)₃ as seen using NMR relaxometry[J]. Physical Chemistry Chemical Physics, 2015, 17(48): 32115-32121.
71	HALLOPEAU L, BREGIROUX D, ROUSSE G, et al. Microwave-assisted reactive sintering and lithium ion conductivity of Li_1.3Al_0.3Ti_1.7(PO₄)₃ solid electrolyte[J]. Journal of Power Sources, 2018, 378: 48-52.
72	HE Xingfeng, ZHU Yizhou, MO Yifei. Origin of fast ion diffusion in super-ionic conductors[J]. Nature Communications, 2017, 8: doi: 10.1038/ncomms15893.
73	WANG Qi, WU Jianfang, LU Ziheng, et al. A new lithium-ion conductor LiTaSiO₅: Theoretical prediction, materials synthesis, and ionic conductivity[J]. Advanced Functional Materials, 2019, 29(37): doi: 10.1002/adfm.201904232.
74	ZHAO Erqing, MA Furui, JIN Yongcheng, et al. Pechini synthesis of high ionic conductivity Li_1.3Al_0.3Ti_1.7(PO₄)₃solid electrolytes: The effect of dispersant[J]. Journal of Alloys and Compounds, 2016, 680: 646-653.
75	KOTOBUKI M, KOISHI M, KATO Y. Preparation of Li_1.5Al_0.5Ti_1.5(PO₄)₃ solid electrolyte via a co-precipitation method[J]. Ionics, 2013, 19(12): 1945-1948.
76	DULUARD S, PAILLASSA A, PUECH L, et al. Lithium conducting solid electrolyte Li_1.3Al_0.3Ti_1.7(PO₄)₃ obtained via solution chemistry[J]. Journal of the European Ceramic Society, 2013, 33(6): 1145-1153.
77	SCHELL K G, BUCHARSKY E C, LEMKE F, et al. Effect of calcination conditions on lithium conductivity in Li_1.3Ti_1.7Al_0.3(PO₄)₃ prepared by sol-gel route[J]. Ionics, 2017, 23 (4): 821-827.
78	LIU Xingang, TAN Jiang, FU Ju, et al. Facile synthesis of nanosized lithium-ion-conducting solid electrolyte Li_1.4Al_0.4Ti_1.6(PO₄)₃ and its mechanical nanocomposites with LiMn₂O₄ for enhanced cyclic performance in lithium ion batteries[J]. ACS Applied Materials & Interfaces, 2017, 9 (13): 11696-11703.
79	KOTOBUKI M, KOISHI M. Preparation of Li_1.5Al_0.5Ti_1.5(PO₄)₃ solid electrolyte via a sol-gel route using various Al sources[J]. Ceramics International, 2013, 39(4): 4645-4649.
80	SOMAN S, IWAI Y, KAWAMURA J, et al. Crystalline phase content and ionic conductivity correlation in LATP glass-ceramic[J]. Journal of Solid State Electrochemistry, 2012, 16(5): 1761-1766.
81	FU Jie. Superionic conductivity of glass-ceramics in the system Li₂O-Al₂O₃-TiO₂-P₂O₅[J]. Solid State Ionics, 1997, 96(3/4): 195-200.
82	WANG Shaofei, Liubin BEN, LI Hong, et al. Identifying Li⁺ion transport properties of aluminum doped lithium titanium phosphate solid electrolyte at wide temperature range[J]. Solid State Ionics, 2014, 268: 110-116.
83	KWATEK K, NOWINSKI J L. Electrical properties of LiTi₂(PO₄)₃ and Li_1.3Al_0.3Ti_1.7(PO₄)₃ solid electrolytes containing ionic liquid[J]. Solid State Ionics, 2017, 302: 54-60.
84	ARBI K, LAZARRAGE M G, CHEHIMI D B, et al. Lithium mobility in Li_1.2Ti_1.8R_0.2(PO₄)₃ compounds (R=Al, Ga, Sc, In) as followed by NMR and impedance spectroscopy[J]. Chemistry of Materials, 2004, 16(2): 255-262.
85	KOSOVA N V, DEVYATKINA E T, STEPANOV A P, et al. Lithium conductivity and lithium diffusion in NASICON-type Li₁₊_xTi_2–_xAl_x(PO₄)₃ (x=0; 0. 3) prepared by mechanical activation[J]. Ionics, 2008, 14(4): 303-311.
86	NING Linjian, WU Yuping, FANG Shibi, et al. Materials prepared for lithium ion batteries by mechanochemical methods[J]. Journal of Power Sources, 2004, 133(2): 229-242.
87	KOSOVA N, DEVYATKINA E. On mechanochemical preparation of materials with enhanced characteristics for lithium batteries[J]. Solid State Ionics, 2004, 172(1/2/3/4): 181-184.
88	KOMIYA R, HAYASHI A, MORIMOTO H, et al. Solid state lithium secondary batteries using an amorphous solid electrolyte in the system (100-x)(0.6Li₂S·0.4SiS₂)·xLi₄SiO₄ obtained by mechanochemical synthesis[J]. Solid State Ionics, 2001, 140(1/2): 83-87.
89	MORIMOTO H, HIRUKAWA M, MATSUMOTO A, et al. Lithium ion conductivities of NASICON-type Li₁₊_xAl_xTi_2-_x(PO₄)₃ solid electrolytes prepared from amorphous powder using a mechanochemical method[J]. Electrochemistry, 2014, 82(10): 870-874.
90	MORIMOTO H, AWANO H, TERESHIMA J, et al. Preparation of lithium ion conducting solid electrolyte of NASICON-type Li₁₊_xAl_xTi_2-_x(PO₄)₃ (x=0.3) obtained by using the mechanochemical method and its application as surface modification materials of LiCoO₂ cathode for lithium cell[J]. Journal of Power Sources, 2013, 240: 636-643.
91	BUCHARSKY E C, SCHELL K G, HUPFER T, et al. Thermal properties and ionic conductivity of Li_1.3Ti_1.7Al_0.3(PO₄)₃ solid electrolytes sintered by field-assisted sintering[J]. Ionics, 2016, 22(7): 1043-1049.
92	WINAND J M, RULMONT A, TARTE E P. New solid solutions L^I(M^IV)_2-_x(N^IV)_x(PO₄)₃ (L=Li, Na M, N=Ge, Sn, Ti, Zr, Hf) synthesized and studied by X-ray diffraction and ionic conductivity[J]. Journal of Solid State Chemistry, 1991, 93(2): 341-349.
93	DELMAS C, NADIRI A, SOUBEYROUX J L. The NASICON-type titanium phosphates ATi₂(PO₄)₃ (A=Li, Na) as electrode materials[J]. Solid State Ionics, 1988, 28/29/30: 419-423.
94	AONO H, SUGIMOTO E, SADAOKA Y, et al. Electrical property and sinterability of LiTi₂(PO₄)₃mixed with lithium salt (Li₃PO₄ or Li₃BO₃)[J]. Solid State lonics, 1991, 47: 257-264.
95	KOBAYASHI Y, TAKEUCHI T, TABUCHI M, et al. Densification of LiTi₂(PO₄)₃-based solid electrolytes by spark-plasma-sintering[J]. Journal of Power Sources, 1999, 81: 853-858.
96	RETTENWANDER D, WELZL A, PRISTAT S, et al. A microcontact impedance study on NASICON-type Li₁₊_xAl_xTi_2-_x(PO₄)₃(0≤x≤0.5) single crystals[J]. Journal of Materials Chemistry A, 2016, 4(4): 1506-1513.
97	JACKMAN S D, CUTLER R A. Effect of microcracking on ionic conductivity in LATP[J]. Journal of Power Sources, 2012, 218: 65-72.
98	HUPFER T, BUCHARSKY E C, SCHELL K G, et al. Influence of the secondary phase LiTiOPO₄ on the properties of Li₁₊_xAl_xTi_2-_x(PO₄)₃ (x= 0; 0.3)[J]. Solid State Ionics, 2017, 302: 49-53.
99	HUPFER T, BUCHARSKY E C, SCHELL K G, et al. Evolution of microstructure and its relation to ionic conductivity in Li₁₊_xAl_xTi_2-_x(PO₄)₃[J]. Solid State Ionics, 2016, 288: 235-239.
100	WAETZIG K, ROST A, LANGKLOTZ U, et al. An explanation of the microcrack formation in Li_1.3Al_0.3Ti_1.7(PO₄)₃ceramics[J]. Journal of the European Ceramic Society, 2016, 36(8): 1995-2001.
101	YU Shicheng, MERTENS A, GAO X, et al. Influence of microstructure and AlPO₄ secondary-phase on the ionic conductivity of Li_1.3Al_0.3Ti_1.7(PO₄)₃ solid-state electrolyte[J]. Functional Materials Letters, 2016, 9(5): doi: 10.1142/S1793604716500661.
102	THOKCHOM J S, KUMAR B. The effects of crystallization parameters on the ionic conductivity of a lithium aluminum germanium phosphate glass-ceramic[J]. Journal of Power Sources, 2010, 195(9): 2870-2876.
103	KEY B, SCHROEDER D J, INGRAM B J, et al. Solution-based synthesis and characterization of lithium-ion conducting phosphate ceramics for lithium metal batteries[J]. Chemistry of Materials, 2012, 24(2): 287-293.
104	WENZEL S, LEICHTWEISS T, KRUGER D. Interphase formation on lithium solid electrolytes — An in situ approach to study interfacial reactions by photoelectron spectroscopy[J]. Solid State Ionics, 2015, 278: 98-105.
105	KIM H S, OH Y, KANG K H, et al. Characterization of sputter-deposited LiCoO₂ thin film grown on NASICON-type electrolyte for application in all-solid-state rechargeable lithium battery[J]. ACS Applied Materials & Interfaces, 2017, 9 (19): 16063-16070.
106	OHTA S, SEKI J, YAGI Y, et al. Co-sinterable lithium garnet-type oxide electrolyte with cathode for all-solid-state lithium ion battery[J]. Journal of Power Sources, 2014, 265: 40-44.
107	GAO Zhonghui, SUN Huabin, FU Lin, et al. Promises, challenges, and recent progress of inorganic solid-state electrolytes for all-solid-state lithium batteries[J]. Advanced Materials, 2018, 30(17): 1705702-1705728.
108	NAGATA K, NANNO T. All solid battery with phosphate compounds made through sintering process[J]. Journal of Power Sources, 2007, 174(2): 832-837.
109	HOFMANN P, WALTHER F, ROHNKE M, et al. LATP and LiCoPO₄ thin film preparation-Illustrating interfacial issues on the way to all-phosphate SSBs[J]. Solid State Ionics, 2019, 342: 115054-115063.
110	GELLERT M, DASHJAV E, GRUNER D, et al. Compatibility study of oxide and olivine cathode materials with lithium aluminum titanium phosphate[J]. Ionics, 2018, 24(4): 1001-1006.
111	KATO T, YOSHIDA R, YAMAMOTO K, et al. Effects of sintering temperature on interfacial structure and interfacial resistance for all-solid-state rechargeable lithium batteries[J]. Journal of Power Sources, 2016, 325: 584-590.
112	HOSHINA K, YOSHIMA K, KOTOBUKI M, et al. Fabrication of LiNi_0.5Mn_1.5O₄ thin film cathode by PVP sol-gel process and its app-lication of all-solid-state lithium ion batteries using Li₁₊_xAl_xTi_2-_x(PO₄)₃solid electrolyte[J]. Solid State Ionics, 2012, 209/210: 30-35.
113	YU Shicheng, SCHMOHL S, LIU Zigeng, et al. Insights into a layered hybrid solid electrolyte and its application in long lifespan high-voltage all-solid-state lithium batteries[J]. Journal of Materials Chemistry A, 2019, 7(8): 3882-3894.
114	LIANG Jiayan, ZENG Xianxiang, ZHANG Xudong, et al. Engineering Janus interfaces of ceramic electrolyte via distinct functional polymers for stable high-voltage Li-metal batteries[J]. Journal of the American Chemical Society, 2019, 141 (23): 9165-9169.
115	LIU Wei, MILCAREK R J, FALKENSTEIN-SMITH R L, et al. Interfacial impedance studies of multilayer structured electrolyte fabricated with solvent-casted PEO10-LiN(CF₃SO₂)₂ and ceramic Li_1.3Al_0.3Ti_1.7(PO₄)₃ and its application in all-solid-state lithium ion batteries[J]. Journal of Electrochemical Energy Conversion and Storage, 2016, 13(2): doi: 10.1115/1.4035294.
116	LIU Yulong, SUN Qian, ZHAO Yang, et al. Stabilizing the interface of NASICON solid electrolyte against Li metal with atomic layer deposition[J]. ACS Applied Materials & Interfaces, 2018, 10 (37): 31240-31248.
117	HARTMANN P, LEICHTWEISS T, BUSHE M R, et al. Degradation of NASICON-type materials in contact with lithium metal: Formation of mixed conducting interphases (MCI) on solid electrolytes[J]. Journal of Physical Chemistry C, 2013, 117(41): 21064-21074.
118	HAO Xiaoge, ZHAO Qiang, SU Shiming, et al. Constructing multifunctional interphase between Li_1.4Al_0.4Ti_1.6(PO₄)₃ and Li metal by magnetron sputtering for highly stable solid‐state lithium metal batteries[J]. Advanced Energy Materials, 2019, 9(34): 1901604-1901611.
119	BAI Hainan, HU Jiulin, DUAN Yusen, et al. Surface modification of Li_1.3Al_0.3Ti_1.7(PO₄)₃ ceramic electrolyte by Al₂O₃-doped ZnO coating to enable dendrites-free all-solid-state lithium-metal batteries[J]. Ceramics International, 2019, 45(12): 14663-14668.
120	CHENG Qian, LI Aijun, LI Na, et al. Stabilizing solid electrolyte-anode interface in Li-metal batteries by boron nitride-based nanocomposite coating[J]. Joule, 2019, 3(6): 1510-1522.
121	ZHOU Weidong, WANG Shaofei, LI Yutao, et al. Plating a dendrite-free lithium anode with a polymer/ceramic/polymer sandwich electrolyte[J]. Journal of the American Chemical Society, 2016, 138(30): 9385-9388.

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Progress of NASICON-structured Li₁₊_xAl_xTi₂_-_x(PO₄)₃(0 ≤x≤ 0.5) solid electrolyte

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