储能科学与技术 ›› 2024, Vol. 13 ›› Issue (2): 546-567.doi: 10.19799/j.cnki.2095-4239.2023.0577
李校磊1(), 高健2(), 周伟东1,2(), 李泓3,4()
收稿日期:
2023-08-28
修回日期:
2023-09-14
出版日期:
2024-02-28
发布日期:
2024-03-01
通讯作者:
高健,周伟东,李泓
E-mail:lixiaolei@buct.edu.cn;gaojian@buct.edu.cn;zhouwd@buct.edu.cn;hli@mail.iphy.ac.cn
作者简介:
李校磊(1996—),男,博士研究生,研究方向为锂离子固态电池,E-mail:lixiaolei@buct.edu.cn;
基金资助:
Xiaolei LI1(), Jian GAO2(), Weidong ZHOU1,2(), Hong LI3,4()
Received:
2023-08-28
Revised:
2023-09-14
Online:
2024-02-28
Published:
2024-03-01
Contact:
Jian GAO, Weidong ZHOU, Hong LI
E-mail:lixiaolei@buct.edu.cn;gaojian@buct.edu.cn;zhouwd@buct.edu.cn;hli@mail.iphy.ac.cn
摘要:
作为一种具有前景的能量存储系统,锂离子电池需要进一步提高能量密度、功率密度、可靠性和循环稳定性,以满足不断增长的大型能源存储、电动汽车和便携式电子设备需求。当前对锂离子电池的实验研究仍然面临多个挑战,这些挑战包括电解液的导电性和安全性、高能量负极的沉积-剥离机制的优化、高能量正极的循环电压和容量维持、高电流条件下的界面极化和容量释放,以及在极端电流-温度-针刺条件下的热失控管理等问题。这些问题涉及到电-化-力-热等多个场的耦合作用,需要进行协同优化处理。COMSOL Multiphysics提供了一种可行的工具,通过求解多物理场耦合的连续方程,能够同时考虑载流子浓度、电流密度、电-化学势、温度、应力/应变和几何形态等综合信息的演化。本文概述了该工具在锂离子电池的电解液、负极和正极设计等方面的研究,并聚焦于多场耦合对电池性能的综合影响、多场耦合模拟方法以及理论模拟与实验表征的结合。最后,本文对理论与实验联合研究中的多场和多尺度问题进行了展望。
中图分类号:
李校磊, 高健, 周伟东, 李泓. COMSOL Multiphysics在锂离子电池中的应用[J]. 储能科学与技术, 2024, 13(2): 546-567.
Xiaolei LI, Jian GAO, Weidong ZHOU, Hong LI. Application of COMSOL multiphysics in lithium-ion batteries[J]. Energy Storage Science and Technology, 2024, 13(2): 546-567.
图4
(a) 上图为锂化过程中硅纳米颗粒断裂的尺寸相关性;中图表明,在临界粒径 Dc ≈150 nm以下,硅纳米颗粒不会在首次嵌锂时破裂或者断裂;随着粒径增大,表面厚度/粒径的比值(t/D)降低,第一次出现裂纹的时间提前;下图为半径分别为 R0 和 R0/2,裂纹长度均为0.1 R0 时,硅纳米颗粒横截面的应力[47];(b) 不同锂化时间下,锂化硅纳米线在〈100〉和〈112〉横截面上的锂化状态(左)和最大平面主应力(右)[48];(c) 在等级多孔硅纳米球壳的锂化(上)和脱锂(下)循环中,体积变化主要由向内的Li呼吸所适应,导致外部体积变化可忽略不计[49](红色表示完全锂化,蓝色表示未锂化)"
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